• Korean Journal of Materials Research
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• 제34권4호
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• pp.202-207
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• 2024

In this study, we undertook detailed experiments to increase hydrogen production efficiency by optimizing the thickness of titanium dioxide (TiO₂) thin films. TiO₂ films were deposited on p-type silicon (Si) wafers using atomic layer deposition (ALD) technology. The main goal was to identify the optimal thickness of TiO₂ film that would maximize hydrogen production efficiency while maintaining stable operating conditions. The photoelectrochemical (PEC) properties of the TiO₂ films of different thicknesses were evaluated using open circuit potential (OCP) and linear sweep voltammetry (LSV) analysis. These techniques play a pivotal role in evaluating the electrochemical behavior and photoactivity of semiconductor materials in PEC systems. Our results showed photovoltage tended to improve with increasing thickness of TiO₂ deposition. However, this improvement was observed to plateau and eventually decline when the thickness exceeded 1.5 nm, showing a correlation between charge transfer efficiency and tunneling. On the other hand, LSV analysis showed bare Si had the greatest efficiency, and that the deposition of TiO₂ caused a positive change in the formation of photovoltage, but was not optimal. We show that oxide tunneling-capable TiO₂ film thicknesses of 1~2 nm have the potential to improve the efficiency of PEC hydrogen production systems. This study not only reveals the complex relationship between film thickness and PEC performance, but also enabled greater efficiency and set a benchmark for future research aimed at developing sustainable hydrogen production technologies.

• Proceedings of the KIPE Conference
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• 전력전자학회 2008년도 하계학술대회 논문집
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• pp.643-645
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• 2008

Stainless steel 304 and 316 plates were deposited with the multi-layered coatings of titanium film (0.1um) and gold film (1-2um) by an electron beam evaporation method. The XRD patterns of the stainless steel plates modified with the multi-layered coatings showed the crystalline phases of the external gold film and the stainless steel substrate. Surface microstructural morphologies of the stainless steel bipolar plates modified with multi-layered coatings were observed by AFM and FE-SEM images. The external gold films formed on the stainless steel plates showed microstructure of grains of about 100nm diameter. The grain size of the external surface of the stainless steel plates increased with the gold film thickness. The electrical resistance and water contact angle of the stainless steel bipolar plates covered with multi-layered coatings were examined with the thickness of the external gold film.

• Transactions of the Korean Society of Mechanical Engineers
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• 제10권6호
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• pp.947-958
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• 1986

물-증기 역류 성층이상유동에서의 평균 액체층 두께가 여러가지 경사각과 종횡비에 따라 측정되었다. 난류유동에 있어서 전단응력분포의 선형화와 von Karman의 혼합길이 이론을 근거로 평균 액체층의 두께에 대한 관계식이 제시되었으며 실험결과와 잘 일치하였음을 보였다. 접촉면에서의 조파저항이 고려되지 않은 해석결과는, 수평 성층유동의 경우에, 평균 액체층 두께보다는 오히려 파곡까지의 액체층 두께를 예측하고 있는 것으로 나타났다. 또한 평균 액체층 두께에 대한 실험 상관관계식이 계산시 편의를 위해 쉽게 인지할 수 있는 매개변수들의 항들롤 제시되었다.

• 한국태양에너지학회:학술대회논문집
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• 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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• pp.68-73
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• 2011

This study was performed numerical analysis in order to analyze liquid film flow of heat exchanger tube arrangement and configuration of evaporative multi effect distillation system using medium-temperature. Simulation was accomplished the two-dimensional calculations using commercial analyses program FLUENT based on the FVM(finite volume method). Fresh water generator of this study used Shell & Tubes heat exchanger with Cu_Ni tube, configuration of tube used bare tube and corrugated tube, and arrangement of tube used in-line array and staggered array. Performance of heat exchanger through the formation of liquid film was compared and analyzed. Liquid film flow occurred that falling on heat exchanger tube wall. Result of simulation showed that liquid film thickness of in-line arrangement was found 0.57mm with bare tube and 0.67mm with corrugated tube, respectively. And liquid film thickness of staggered arrangement was found 0.39mm with bare tubes and 0.62mm with corrugated tubes, respectively. Liquid film thickness of corrugated tube showed thicker than bare tube, but heat transfer rates of corrugated tube showed higher than bare tube. The reason was considered that surface area of corrugated tube was wider than bare tube. And liquid film thickness of staggered arrangement showed thinner than in-line arrangement, so thermal performance of staggered arrangement showed higher than in-line arrangement.

• Nuclear Engineering and Technology
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• 제17권1호
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• pp.25-33
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• 1985

The main purpose of this work is to investigate the effects of the wall thickness, the ultrasonic frequency, and the acoustic impedance of wall material on the liquid-film thickness measurement by an ultrasonic pulse echo method. A series of liquid-film thickness measurements in a horizontal air-water stratified system was performed employing a plate-type and a tube-type test sections. Measurements were repeated changing (1) the wall thickness of the test section and (2) the transducer frequency. Also, in an effort to improve the accuracy of the measurement and to exam me the effect of acoustic impedance of wall material on the measurement by an ultrasonic technique, two different stand-off rods, one made of stainless steel and the other polyacrylate, were used in the liquid-film thickness measurement. These experimental results are discussed and compared with the actual film thicknesses.

• Tribology and Lubricants
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• 제19권3호
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• pp.133-138
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• 2003

The characteristics for bimorph PZT cantilever of laboratory-fabricated have been evaluated experimentally. The deflections of cantilever with PZT are result from a capillary force between a water drop and a tip of cantilever. The output voltage due to deflect cantilever are depend on the tip shape and thickness of cantilever. We applied a bimorph PZT cantilever to oil thickness measurement. This reasonable concept is that the output voltage be caused by different defected characteristics between oil and surface. Experimental results demonstrated that the high measurement accuracy of the oil film thickness is obtained from the probe.

• Journal of the Korean Crystal Growth and Crystal Technology
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• 제25권6호
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• pp.280-284
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• 2015

Au doped $TiO_2$ nanoparticles have been synthesized using a reverse micelle technique combined with metal alkoxide hydrolysis and condensation. Au doped $TiO_2$ was coated with glass substrate. The size of the particles and thickness of the coating can be controlled by manipulating the relative rates of the hydrolysis and condensation reaction of TTIP within the micro-emulsion. The average size of synthesized Au doped $TiO_2$ nanoparticle was about in the size range of 15 to 25 nm and the Au particles formed mainly the range of 2 to 10 nm in diameter. The effect of synthesis parameters, such as the molar ratio of water to TTIP and the molar ratio of water to surfactant, are discussed. The synthesized nanopaticles were coated on glass substrate by a spin coating process. The thickness of thin film was about 80 nm. The degradation of MB on a $TiO_2$ thin film was enhanced over 20 % efficiency by the incorporation of Au.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• 제9권2호
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• pp.144-152
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• 1997

Film absorption involves simultaneous heat and mass transfer in the vapor-liquid system. In the present work, the absorption process of water vapor by an aqueous soluton of LiBr flowing inside of the vertical tube was investigated. The continuity, momentum, energy and diffusion equations for the solution film and vapor were formulated in integral forms and solved numerically. The model could predict the film thickness, the pressure gradient, and the heat and mass transfer rate. Particularly the effects of vapor flow conditions on the absorption process were investigated in terms of the vapor Reynolds number. As the vapor Reynolds number increased, the shear stress at the vapor-solution interface also increased. Consequently solution film became thinner at higher vapor flowrate under the co-currentflow condition. Thinner film was capable of higher heat transfer to the wall and leaded to higher absorption rate of the water vapor into the solution film.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• 제12권7호
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• pp.642-648
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• 2000

Falling film heat transfer analyses with aqueous lithium bromide solution were peformed to investigate the transfer characteristics of the copper tubes. Finned(knurled) tube and a smooth tube were selected as test specimens. Averaged generation fluxes of water and the heat transfer performances(heat flux, heat transfer coefficient) were obtained. The results of this work were compared with the data reported previously. As the film flow rate of the solution increased, the generation fluxes of water decreased for both tubes. The reason is estimated by the fact that the heat transfer resistance with the film thickness increased as the film flow rate increased. The effect of the enlarged surface area at the knurled tube was supposed to be dominant at a small flow rate. The generation fluxes of water increased with the increasing degree of tube wall superheat. Nucleate boiling is supposed to occur at a wall superheat of 20 K for a smooth tube, and at 10 K for a knurled tube. The heat transfer performance of the falling film was superior to pool boiling at a low wall superheat below 10 K for both tubes tested. The knurled tube geometry showed good performance than the smooth tube, and the increased performance was mainly came from the effect of the increased heating surface area.

• Journal of the Korean Applied Science and Technology
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• 제15권3호
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• pp.47-53
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• 1998

The polyimide film surface was modified with KOH aqueous solutions or sulfuric acid. The film thickness was increased by about 10% through the modification of film surface. Hydrolysis of amide bonds and hydration of water induced the increase. The polarity of the film surface increased and identified by contact angle measurement. The depth and roughness of modified was increased. After treatment of surface with water, alkyl and 4-pentyloxyaniline were introduced on the film surface by complex formation between anionic species formed on the imide surface and ammonium ion. The newly introduced alkyl group was identified by FT-IR spectroscopy. Surface polarity reduced dramatically and the roughness was increased after introduction of ammonium salt.