• Membrane Journal
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• v.27 no.4
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• pp.358-366
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• 2017

The most important factor in the performances of polymer electrolyte membranes for fuel cells is how fast hydrogen ions can be transported along the water channel formed inside the electrolyte membrane. Since the morphology of the water channel and the diffusivity of the protons are very important factors for the proton transport behavior, various molecular dynamics simulation studies are being carried out to clarify this. The force-field is an important variable parameterizing the movement and interaction of each atom in molecular dynamics simulation. In this study, proton diffusivities of the 3D models of polymer electrolyte membranes were calculated in order to analyze the effects of various types of force-fields on the molecular simulation. It has been found that the charge value determining the non-bonding interaction plays a very important role in the formation of the water channel morphology, and the COMPASS force-field can calculate the accurate proton diffusion behavior. Accordingly, for molecular dynamics simulation of polymer electrolyte membranes, the proper selection of the force-field is very important due to its great effect on the proton diffusion as well as the final molecular structure.

• Corrosion Science and Technology
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• v.8 no.3
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• pp.103-109
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• 2009

An epoxy coating was designed to give a hydrophobic property on its surface by modifying it with three types of Amino Terminated Polydimethylsiloxane (ATP), and then effects of the modification on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protectiveness of the modified epoxy coating were examined using FT-IR spectroscopy, hydrothermal cyclic test, and impedance test. The surface of epoxy coating was changed from hydrophilic to hydrophobic property due primarily to a phase separation tendency between epoxy and modifier by the modification. The phase separation tendency is more appreciable when modified by ATP with higher molecular weight ATP at higher content. Water transport behavior of the modified epoxy coating decreased more in that with higher hydrophobic surface property. The resistance to localized corrosion of the modified epoxy coated carbon steel was well agreed with its water transport behavior and hydrophobic tendency.

• Clean Technology
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• v.22 no.1
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• pp.45-52
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• 2016

This study reports on the modeling and simulation of heat transfer in packaging boxes used for vaccine shipping. Both water and n-tetradecane are used as primary insulation materials inside a multi-slab system. The one-dimensional model, which is a spherical model using a radius equivalent to the rectangular geometry of container, is applied in this study. N-tetradecane with low thermal diffusivity and proper phase transition temperature exhibits higher heat transfer resistance during both heating and cooling processes compared to water. Thus, n-tetradecane is a better candidate as an insulating material for packaging containers for vaccine shipping. Furthermore, the developed method can also become a rapid and economic tool for screening appropriate phase change materials used as insulation materials with suitable properties in logistics applications.

• Clean Technology
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• v.7 no.3
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• pp.195-202
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• 2001

In this study the trace of chlorinated organic compound in aqueous solution was separated by pervaporation process using crosslinked PDMS (polydimethylsiloxane) membrane. The flux of trichloroethylene(TCE) increased linearly with feed composition but the flux of water was slightly increased. The partial flux of TCE was greater than that of tetrachloroethylene(PCE). The partial flux of TCE was not changed with operating temperature, but increased rapidly with feed flow rates. High crosslinking density causes the reduction of solubility and diffusivity for target component. The reduction of flux and selectivity for TCE is due to the chain immobilization and reduction of diffusivity with crosslinking density.

• Advanced Composite Materials
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• v.17 no.4
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• pp.359-372
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• 2008

The moisture absorption behavior of carbon fiber-reinforced plastic (CFRP) and its effect on dimensional stability were examined. Moisture diffusivity in CFRP was determined by measuring a specimen's weight during the moisture absorption test. Three types of CFRP specimens were prepared: a unidirectionally reinforced laminate, a quasi-isotropic laminate and woven fabric. Each CFRP was processed into two geometries - a thin plate for determination of diffusivity and a rod with a square cross-section for the discussion of two-dimensional diffusion behavior. By solving Fick's law expanded to 3 dimensions, the diffusivities in the three orthogonal directions were obtained and analyzed in terms of the anisotropy of CFRP moisture diffusion. Coefficients of moisture expansion (CMEs) were also obtained from specimen deformation caused by moisture absorption. During moisture absorption, the specimen surfaces showed larger deformation near the edges due to the distribution of moisture contents. This deformation was reasonably predicted by the finite element analysis using experimentally determined diffusivities and CMEs. For unidirectional CFRP, the effect of the fiber alignment on CME was analyzed by micromechanical finite element analysis (FEA) and discussed.

• Journal of the Korean Society for Industrial and Applied Mathematics
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• v.4 no.1
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• pp.11-22
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• 2000

Nonhysteretic infiltration in nonswelling soil is modelled by the Burgers equation under appropriate physical conditions. For this nonlinear partial differential equation the modal approximation scheme is used for estimating parameters such as soil water diffusivity and hydraulic conductivity. The parameter estimation convergence is proved, and numerical experiments are performed.

• Proceedings of the Korea Concrete Institute Conference
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• 1992.04a
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• pp.13-18
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• 1992

Moisture movement which is controlled by water potential and permeability of concrete is a very important phenomenon which affects the shrinkage of concrete. Thermocouple psychrometer were used to measure the moisture potentials in concrete. Based on the measured moisture potentials, three method have been proposed to calculate hycraulic conductivity and diffusivity. And also the hystresis of sorption isotherm due to drying and wetting cycle has been crawn.

• Corrosion Science and Technology
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• v.15 no.2
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• pp.69-77
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• 2016

In the present study, polyester-melamine coating systems with natural wood fiber (NWF) were prepared and the effects of NWF on the corrosion protectiveness of the polyester-melamine coating were examined using EIS analysis. From the results, higher average surface roughness was observed with increase of NWF content. Water diffusivity and water uptake into the polyester-melamine coatings with NWF were much higher than that into the pure polyester-melamine coating. The decrease in the impedance modulus |Z| was associated with the localized corrosion on carbon steel, confirming that corrosion protection of the polyester-melamine coatings with NWF well agrees with its water transport behavior.

• Corrosion Science and Technology
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• v.7 no.6
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• pp.344-349
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• 2008

Epoxy coatings were prepared to give a different corrosion protection by reacting it with two different kinds of curing agent, and then effects of the curing agents on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protection of epoxy coatings were examined using hygrothermal cyclic test, and impedance analysis. In the results of EIS, the corrosion protection of epoxy coating cured by polyamide shows better than epoxy coating cured by polyamide epoxy adduct. It was well agreed with its water transport behavior and hydrophobic tendency.

• Journal of Korean Society on Water Environment
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• v.24 no.3
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• pp.311-316
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• 2008

This study aimed to obtain equilibrium concentration on adsorption removal of ammonia nitrogen by activated carbon, to express the adsorption characteristics following Freundlich isotherm and also, based on the value obtained, to investigate the relationship between physical characteristics of activated carbon and dynamics of ammonia nitrogen removal by obtaining rate constant and effective pore diffusivity. The results summarized from this study are as follows. It was noted that powdered activated carbon showed better adsorption ability than granular activated carbon. The value of constant (f) of Freundlich isotherm of powered activated carbon was $4.6{\times}10^{-8}$ which is bigger than that of granular activated carbon. The adsorption rate constant on ammonia nitrogen of powered activated carbon with high porosity and low effective diameter was highest as 0.416 hr-1 and the effective pore diffusivity ($D_e$) was lowest as $1.17{\times}10^{-6}cm^2/hr$, and the value of ammonia nitrogen adsorption rate constant of granular activated carbon was $0.149{\sim}0.195hr^{-1}$. It was revealed that, with the same amount of dosage, the adsorptive power of activated carbon with lower effective diameter and bigger porosity was better and its rate constant was also high. With a little adsorbent dosage of 2 g, there was no difference removal ability of ammonia nitrogen as change of adsorption properties.