• Title/Summary/Keyword: water diffusivity

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Prediction of solute rejection and modelling of steady-state concentration polarisation effects in pressure-driven membrane filtration using computational fluid dynamics

  • Keir, Greg;Jegatheesan, Veeriah
    • Membrane and Water Treatment
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    • v.3 no.2
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    • pp.77-98
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    • 2012
  • A two-dimensional (2D) steady state numerical model of concentration polarisation (CP) phenomena in a membrane channel has been developed using the commercially available computational fluid dynamics (CFD) package CFX (Ansys, Inc., USA). The model incorporates the transmembrane pressure (TMP), axially variable permeate flux, variable diffusivity and viscosity, and osmotic pressure effects. The model has been verified against several benchmark analytical and empirical solutions from the membrane literature. Additionally, the model is able to predict the rejection of an arbitrary solute by the membrane using a pore model, given some basic knowledge of the geometry of the solute molecule or particle, and the membrane pore geometry. This allows for predictive design of membrane systems without experimental determination of the membrane rejection for the specified operating conditions. A demonstration of the model is presented against experimental results for two uncharged test compounds (sucrose and PEG1000) from the literature. The model will be extended to incorporate charge effects, transient simulations, three-dimensional (3D) geometry and turbulent effects in future work.

Effect of Temperature and Water Content of Soil on Creeping Bentgrass(Agrostis palustris Huds) Growth (토양의 온도와 수분이 크리핑 벤트그래스(Agrostis palustris Huds) 생육에 미치는 영향)

  • Lim, Seung-Hyun;Jeong, Jun-Ki;Kim, Ki-Dong;Joo, Young-Kyoo
    • Asian Journal of Turfgrass Science
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    • v.23 no.2
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    • pp.229-240
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    • 2009
  • The high temperature and water content in soil profile probably affect the physiological disorder especially on cool-season turfgrasses in warm and humid weather of Korean summer. The purpose of this research was to analyze the effect of soil temperature and water content on the growth and stress response of creeping bentgrass(Agrostis palustris Huds.) under a humid and warm temperature. USGA(United State of Golf Association) green profile in laboratory test, Daily temperature changes were tested under a dried sand, 70% water content of field capacity, and saturated condition at $34^{\circ}C$ of the USGA green in lab. In this test, the dried sand reached to $80^{\circ}C$, however, the surface temperature decrease of $10^{\circ}C$ on the saturated condition. In the thermal properties test in field, thermal conductivity, thermal diffusivity, and soil temperature were increased followed by irrigation practise. In the water-deficient condition, the highest soil temperature was reached temporally right after irrigation, however, the excessive soil water content higher than field water holding capacity showed the highest soil temperature after a while. This result indicated that a heat damage to root system was caused from the thermal conductivity of a high surface soil temperature. The excessive irrigation when a high turf surface temperature should occur a negative result on tufgrass growth, moreover, it would be fatal to root growth of creeping bentgrass, especially when associated with a poor draining system on USGA sand green. Overall, this study shows that high soil temperature with water-excessive condition negatively affects on cool-season grass during the summer season, suggesting that excessive irrigation, over 70% field capacity of soil condition, does not help to reduce soil temperature for summer season in Korea. In the study that cool-season grass were treated with different water content of soil, The soil had higher temperature and more water holding capacity when treatment rate of soil conditioner was increased. The best growth at the normal water condition and the worst state of growth at thee water-excessive condition were observed.

A study on the characteristic of the anodic dead-end mode PEM fuelcell and performance improvement by pulsation effect (수소 데드 앤드 연료전지의 특성 및 맥동을 이용한 성능 향상에 관한 실험적 연구)

  • Choi, Jong-Won;Hwang, Yong-Sheen;Kim, Sung-Il;Ha, Jeong-Hoon;Park, Joon-Ho;Cha, Suk-Won;Kim, Min-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.336-340
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    • 2009
  • This paper presents experimental results carried out on the purge characteristic of the anodic dead-end mode fuelcell and how to improve the cell performance by pulsation effects. The dead-end mode fuelcell has some merits that a fuel supplying device is not needed and the cell power is higher than that in the open mode fuelcell. However, the purge is necessary for preventing the porous media from being flooded by liquid water formed in the channel. At this time, the un-reacted fuel is discharged with the liquid water together in purge process. The discharged fuel can make the fuel efficiency lower. Therefore, the number of purge times should be decreased for the better fuel efficiency. In this study, the outlet of the anode channel was equipped with a purge solenoid valve and a pulsation generator. The purge times was decreased when the current density decreased and operation pressure increased without the pulsation effects. In addition, when the pulsation effects such as various frequencies or amplitudes were applied, purge times was alleviated up to 40%.

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A Numerical Analysis of Thermal Discharge using $\kappa-\imath$ Turbulence Closure ($\kappa-\imath$ 난류모델을 이용한 온배수 수치해석)

  • 최흥식
    • Water for future
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    • v.29 no.2
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    • pp.199-207
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    • 1996
  • To evaluate the usage of $\kappa-\imath$ turbulence closure for the analysis of thermal discharge behavior, a two-dimensional depth-integrated numerical model is developed. The developed model is applied to a steady flow in an open channel with simle geometry and the numerical results agree well with existing experimental data. The adequate simulation of recirculation, reattachment, and excess temperature rise at downstream of the outlet in the channel attributes to the correct calculation of turbulent eddy viscosity and diffusivity by $\kappa-\imath$ turbulence model. For an accurate prediction of thermal discharge behavior, the introduction of buoyancy production term, the modification of source/sink, and the correct input of turbulence constants of the $\kappa-\imath$ turbulence model are required.

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DEVELOPMENT OF THE MULTI-DIMENSIONAL HYDRAULIC COMPONENT FOR THE BEST ESTIMATE SYSTEM ANALYSIS CODE MARS

  • Bae, Sung-Won;Chung, Bub-Dong
    • Nuclear Engineering and Technology
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    • v.41 no.10
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    • pp.1347-1360
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    • 2009
  • A multi-dimensional component for the thermal-hydraulic system analysis code, MARS, was developed for a more realistic three-dimensional analysis of nuclear systems. A three-dimensional and two-fluid model for a two-phase flow in Cartesian and cylindrical coordinates was employed. The governing equations and physical constitutive relationships were extended from those of a one-dimensional version. The numerical solution method adopted a semi-implicit and finite-difference method based on a staggered-grid mesh and a donor-cell scheme. The relevant length scale was very coarse compared to commercial computational fluid dynamics tools. Thus a simple Prandtl's mixing length turbulence model was applied to interpret the turbulent induced momentum and energy diffusivity. Non drag interfacial forces were not considered as in the general nuclear system codes. Several conceptual cases with analytic solutions were chosen and analyzed to assess the fundamental terms. RPI air-water and UPTF 7 tests were simulated and compared to the experimental data. The simulation results for the RPI air-water two-phase flow experiment showed good agreement with the measured void fraction. The simulation results for the UPTF downcomer test 7 were compared to the experiment data and the results from other multi-dimensional system codes for the ECC delivery flow.

Cake Reduction Mechanism in Coagulation-Crossflow Microfiltration Process (Crossflow 방식 응집-정밀여과 공정의 케이크층 저감 메커니즘)

  • Kim, Suhan;Park, Heekyung
    • Journal of Korean Society of Water and Wastewater
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    • v.17 no.4
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    • pp.519-527
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    • 2003
  • Cake layer in crossflow microfiltration(CFMF) can be reduced by coagulation, enhancing membrane flux. This is because enlarging particle size by coagulation increases shear-induced diffusivity and the back-transport of rejected particles. However it is known that the enlarged particles are disaggregated by the shear force of the pump while passing through it. This study is to look at the disaggregation in relation with cake layer reducation. Kaolin and polysulfon hollow fiber microfilter are used for experiment. The reduction of cake resistance by coagulation is observed in a range of 17% to 53% at the various coagulation conditions. The particle size analysis results of the experiments show that aggregated particles in feed are completely disaggregated by pump but re-aggregation of particles occurs in membrane. This suggestes that the re-aggregation of particles is critical to cake reduction and flux enhancement, since the aggregated particles are completely broken. The mechanisms for re-aggregation in membrane are the same with those for coagulation in feed tank. Charge neutralization is better for CCFMF than sweep flocculation although it has two drawbacks in operation.

Temperature Dependence of Self-Diffusion of THO in Copolymer Hydrogel Membrane as a Function of Gel Compositions

  • Soon Hong Yuk;Sang Il Jeon;Mu Shik Jhon
    • Bulletin of the Korean Chemical Society
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    • v.5 no.3
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    • pp.104-108
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    • 1984
  • The self-diffusion experiment of THO was performed across a series of copolymer hydrogel membranes at different temperatures. Copolymer hydrogel membranes were prepared by copolymerizing 2-hydroxyethyl methacrylate (HEMA) and 2-aminoethyl methacrylate (AEMA) in the presence of the solvent and the crosslinker, ethylene glycol dimethacrylate (EGDMA). By changing the crosslinker content and the ratio of HEMA and AEMA monomer, two series of copolymer hydrogel membranes were synthesized. The tagging material was THO and efflux of THO was counted on a Liquid Sc-intillation Counter. The experimental data show that the permeability decreases as the amount of EGDMA and the mole fraction of HEMA increase, and the permeability is proportional to the temperature. The partition coefficient shows a parallel trend with permeability. Using the relationship between viscosity and diffusivity, the viscosity of water within the membrane was obtained. According to the result, the viscosity of watler within the membrane has the same value with those of supercooling water. And we obtained the activation energy of THO for transport in the membrane by using Arrhenius plotting.

Drying Characteristics and Physicochemical Properties of Semi-Dried Restructured Sausage Depend on Initial Moisture Content

  • Kim, Dong-Hyun;Kim, Yea Ji;Shin, Dong-Min;Lee, Jung Hoon;Han, Sung Gu
    • Food Science of Animal Resources
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    • v.42 no.3
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    • pp.411-425
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    • 2022
  • Semi-dried restructured sausages are restructured meat products with a high nutritional and economic value. However, excessively long drying times can have negative effects on the energy consumption, texture, and sensory properties of semi-dried restructured sausages. The objective of this study was to investigate the effects of different water contents on the drying and physicochemical characteristics of semi-dried restructured sausages. Sausages were prepared with different initial moisture contents (0%-50%) and drying time (0-580 min). The drying characteristics, including the drying rate, effective moisture diffusivity, and water activity of sausage were significantly improved as the initial moisture content was increased. When the initial moisture content of the sausage was 50%, physicochemical properties, such as color, porosity, shear force, and volatile basic nitrogen, were improved the most along with the decreased drying time. Scanning electron microscopy data showed greater porosity and pore size in sausages with the increase of initial moisture content. Collectively, our data suggest that an increase in the initial moisture content of semi-dried restructured sausages improves their drying characteristics and physicochemical properties.

A Comparative Study on Strength Development, Chloride Diffusivity and Adiabatic Temperature Rise of Marine Concrete Depending on Binder Type (결합재 종류에 따른 해양 콘크리트의 강도 발현, 염화물 확산 및 단열온도 상승 특성에 대한 비교 연구)

  • Bae, Jun-Young;Cho, Sung-Hyun;Shin, Kyung-Joon;Kim, Yun-Yong
    • Journal of the Korea Concrete Institute
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    • v.25 no.4
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    • pp.411-418
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    • 2013
  • Recently, in order to reduce a damage of chloride attack and hydration heat in marine concrete structures, blended cement in mixing the marine concrete is widely used. Long term strength development is distinct in concrete with blended cement and it also has excellent resistance to chloride attack and reduction of hydration heat. However, blended cement has a characteristic of relatively low compressive strength in early age of 28 days. On the other hand, a high level of compressive strength is required in the Standard Specification for marine concrete mix design. Such concrete mix design satisfying Standard Specification is effective to chloride attack but disadvantageous for hydration heat reduction due to large quantity of binder. In this study, the material properties of marine concrete considering water-binder ratio and binder type are experimentally investigated. Through the research results, compressive strength in blended cement at the age of 56 days is similar although it has smaller compressive strength at the age of 28 days compared with result of OPC (ordinary portland cement). Even though blended cement has a large water-binder ratio and small unit of binder content, chloride ion diffusion coefficient is still small and hydration heat is also found to be reduced. For meeting the required compressive strength in Standard Specification for marine concrete at 28 days, the increased unit content of binder is needed but the increased hydration heat is also expected.

Numerical Modeling of Water Transfer among Precipitation, Surface Water, Soil Moisture and Groundwater

  • Chen, Xi;Zhang, Zhicai;Chen, Yongqin
    • Proceedings of the Korea Water Resources Association Conference
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    • 2006.05a
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    • pp.2-11
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    • 2006
  • In the processes of hydrological cycle, when precipitation reaches the ground surface, water may become surface runoff or infiltrate into soil and then possibly further percolate into groundwater aquifer. A part of the water is returned to the atmosphere through evaporation and transpiration. Soil moisture dynamics driven climate fluctuations plays a key role in the simulation of water transfer among ground surface, unsaturated zone and aquifer. In this study, a one-layer canopy and a four-layer soil representation is used for a coupled soil-vegetation modeling scheme. A non-zero hydraulic diffusivity between the deepest soil layer modeled and groundwater table is used to couple the numerical equations of soil moisture and groundwater dynamics. Simulation of runoff generation is based on the mechanism of both infiltration excess overland flow and saturation overland flow nested in a numerical model of soil moisture dynamics. Thus, a comprehensive hydrological model integrating canopy, soil zone and aquifer has been developed to evaluate water resources in the plain region of Huaihe River basin in East China and simulate water transfer among precipitation, surface water, soil moisture and groundwater. The newly developed model is capable of calculating hydrological components of surface runoff, evapotranpiration from soil and aquifer, and groundwater recharge from precipitation and discharge into rivers. Regional parameterization is made by using two approaches. One is to determine most parameters representing specific physical values on the basis of characterization of soil properties in unsaturated zone and aquifer, and vegetations. The other is to calibrate the remaining few parameters on the basis of comparison between measured and simulated streamflow and groundwater tables. The integrated modeling system was successfully used in the Linhuanji catchment of Huaihe plain region. Study results demonstrate that (1) on the average 14.2% of precipitation becomes surface runoff and baseflow during a ten-year period from 1986 to 1995 and this figure fluctuates between only 3.0% in drought years of 1986, 1988, 1993 and 1994 to 24.0% in wet year of 1991; (2) groundwater directly deriving from precipitation recharge is about 15.0% t of the precipitation amount, and (3) about half of the groundwater recharge flows into rivers and loses through evaporation.

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