• 제목/요약/키워드: water corrosion

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원·정수의 부식특성에 따른 상수관망에서의 부식성 수질 모니터링 (The Monitoring of Corrosive Water Quality in Water Distribution System by Corrosion Characteristics of Raw and Tap water)

  • 배석문;김도환;손희종;최동훈;김익성;김경아
    • 한국환경과학회지
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    • 제24권7호
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    • pp.907-915
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    • 2015
  • The tap water is generally known to be corrosive in the pH range at 6.5 ~ 7.5. And the degree of corrosion varies depending on the types of raw water such as river surface water or lake water of the dam. Although several corrosion index represents the corrosivity of tap water, the typical corrosion indexes such as Langelier saturation index (LI) and calcium carbonate precipitation potential (CCPP) were calculated to monitoring the corrosive water quality about raw and tap water in water distribution system. To control the corrosive water quality, the correlation between corrosion index and water quality factors were examined. In this study, corrosion index (LI, CCPP) and the pH was found to be most highly correlated.

유연운전에 따른 석탄화력보일러 수계통 튜브에서의 이상 유동가속부식(Two-Phase Flow Accelerated Corrosion) 고찰 (A Two-Phase Flow Accelerated Corrosion Study on Water Wall Tube of Coal-Fired Boiler According to Flexible Operation)

  • 김상호;이승민;이재홍
    • Corrosion Science and Technology
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    • 제23권3호
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    • pp.246-254
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    • 2024
  • Recently, coal-fired power plants are experiencing many problems that they have never experienced before due to an increase in flexible operation. In particular, a two-phase flow accelerated corrosion on water wall tubes in a boiler has not been detected overseas or domestically. There is no response plan to deal with such corrosion problem either. However, oxide film damage and tube material corrosion due to a two-phase flow accelerated corrosion are being discovered on water wall boiler tubes of domestic coal-fired power plants recently. If this situation is severe, it can cause enormous damage such as tube rupture. Therefore, in this paper, in order to prepare a response plan for a two-phase flow accelerated corrosion on water wall tubes in the future, differences between a two-phase flow accelerated corrosion and a single-phase flow accelerated corrosion were investigated and an example of discovery of a two-phase flow accelerated corrosion on water wall tubes was presented.

수돗물의 pH가 동관의 부식에 미치는 영향 (The Influence of pH on Corrosion Behavior of Copper Tubes in Tap Water)

  • 민성기;나승찬;황운석
    • Corrosion Science and Technology
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    • 제8권6호
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    • pp.232-237
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    • 2009
  • Copper tubes are widely used in the distribution systems of drinking water throughout the world because of their excellent corrosion resistance, high thermal conductivity, and ease of fabrication. However, corrosion problems from copper tubes as blue water phenomenon and leakage have been reported appreciably. The effect of pH on the corrosion behavior of copper tube for tap water was investigated by electrochemical voltammetric techniques in synthetic tap water. And the copper corrosion cases were discussed from the viewpoint of factors affecting the corrosion rate such as pH, alkalinity, LSI(Langelier Saturation Index), and concentration of bicarbonate and dissolved carbon dioxide.

해수와 청수환경에서 선박용 원심펌프 임펠러 재료의 캐비테이션 특성 (Cavitation Characteristics on Impeller Materials of Centrifugal Pump for Ship in Sea Water and Fresh Water)

  • 임명환
    • Corrosion Science and Technology
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    • 제10권6호
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    • pp.218-224
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    • 2011
  • The fresh water and sea water in present ships is used as cooling water for marine engine. Therefore, corrosion damage in seawater system is frequently occurred. In particular, in the impeller of pump, the performance and material span due to the corrosion and cavitation erosion has adverse effects. Most of the pump impellers in vessels are used Cu-Al alloy. Cu-Al alloy which having the excellent mechanical properties and corrosion resistance is widely used in marine environments. However, despite the excellent characteristics, the periodic replacement parts due to the cavitation damage in seawater is vulnerable to economic viewpoint. In this study, Cu-Al alloy used with impeller for centrifugal pump were conducted various experiments to evaluate its characteristics in seawater and fresh water solutions. As an electrochemical result, the dynamic conditions that exposed to the cavitation environment presented high corrosion current density with collapse of the cavity compared with the static conditions. Cavitation test results, the weightloss and weightloss rate in fresh water are observed more than those of seawater.

탄소강 볼트 체결된 GECM(Graphite Epoxy Composite Material)/Al 판재의 구성 부재의 부식 거동 (Corrosion Behavior of the parts of Carbon Steel Bolted GECM(Graphite Epoxy Composite Material)/Al plates)

  • 김영식;박수진;유영란
    • Corrosion Science and Technology
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    • 제11권6호
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    • pp.232-241
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    • 2012
  • This work focused on corrosion of carbon steel bolted GECM/Al parts in tap water and NaCl solutions. In tap water and NaCl solutions, open circuit potential of GECM and its potentials in a series of carbon steel bolt>Ti>Al became active. Regardless of test materials, open circuit potentials in tap water were noble, and increasing NaCl concentration, its potentials became active. Immersion test of single specimen showed that no corrosion occur in Ti and GECM. In tap water, carbon steel bolt didn't show red corrosion product and in chloride solutions, corrosion rate in 1% NaCl solution was greater than its rate in 3.5% NaCl solution and red corrosion product in 1% NaCl solution was earlier observed than that in 3.5% NaCl solution. It seems that this behavior would be related to zinc-coatings on the surface of carbon stee l bolt. On the other hand, aluminium was corroded in tap water and chloride solutions. Corrosion of aluminium in tap water was due to the presence of chloride ion in tap water by sterilizing process.

수돗물 부식성 제어를 통한 수도관 부식방지기술: 석회수 분산화장치를 이용한 미네랄 공급 효과와 영향 분석 (Corrosion control technology in water pipes by adjusting the corrosivity of drinking water : effect and impact of the lime dispersion system)

  • 한금석;박영복;김성재;김현돈;최영준;박주현;우달식;홍성호
    • 상하수도학회지
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    • 제32권3호
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    • pp.235-242
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    • 2018
  • Corrosion inhibitors including calcium hydroxide have been used to prevent corrosion in the pipes for tap water supply. The corrosion index (i.e., Langelier Index) differs by area and water quality. The corrosion indices of the areas studied differed by more than 2.0. The 'homogenized' calcium hydroxide was added to the treated water at the K water treatment plant, in order to increase the value of the corrosion index and the concentration of calcium. As the result, the concentration of calcium was increased while the turbidity and pH changed little. The corrosion rate of the tap water with the 'homogenized' calcium hydroxide could be slowed down pretty much. The results suggested that the technology of 'homogenization' of calcium hydroxide can applied to tap water and desalinated water to prevent corrosion in water pipes even in corrosive pipes.

수질제어를 통한 관 내부 부식방지 기술의 정수처리공정 적용방안 (Approaches to Internal Corrosion Control Technologies by Controlling Water Quality in Water Treatment Systems)

  • 서대근;왕창근
    • 상하수도학회지
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    • 제20권4호
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    • pp.509-518
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    • 2006
  • Although final water of domestic water treatment plants almost contains highly corrosive characteristics, the countermeasures for eliminating internal corrosion of pipeline system have not been conducted yet by controlling water quality in plants. The technologies of internal corrosion control are to control water quality parameters(pH, Alkalinity, and Calcium Hardness etc.) and to use corrosion inhibitor. Under the conditions of domestic water treatment, first of all, the technologies of adjusting water quality parameters has to be considered. Otherwise, The technology of using corrosion inhibitor is favorably thought to be applied with the technology of adjusting water quality parameters in accordance with the result of availability for water treatment process. Since the technology of adjusting water quality parameter influences on other water treatment processes, the guideline of water quality management to be apt for water quality characteristic is required to be estabilished. While the selection of proper chemicals and technologies is dependent upon the raw water characteristics and water treatment process, typically, the technology of $Ca(OH)_2$ & $CO_2$ additions is considered more effective than other technologies in order to adjust pH and Alkalinity, increase $Ca^{2+}$ and form $CaCO_3$ film

수도관 부식에 대한 잔류염소 농도 영향 및 부식제어 방안 (Effect of Residual Chlorine Concentration on Water Pipe Corrosion and Corrosion Control Plan)

  • 한금석;박주현;박영복;김성재;김현돈;최영준;최인철;홍성호
    • Corrosion Science and Technology
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    • 제17권1호
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    • pp.12-19
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    • 2018
  • Langelier Index (LI) is used as a tap water corrosiveness index. Residual chlorine in tap water induces corrosion inside water pipes. This study takes a deeper look into the effect of residual chlorine in water pipes. Comparison between tap waters of Y and K water treatment plant (WTP) shows that the LI index of K WTP is lower than that of Y. However, the corrosion rate of Y WTP is higher than that of K WTP. This means that the higher the concentration of residual chlorine in tap water, the higher the corrosion rate of pipe materials. When calcium hydroxide was added to tap water, the corrosiveness index was improved and thus the corrosion rate reduced. It is possible to increase the disinfection efficiency by increasing the duration of residual chlorine and suppressing the rust generation of water pipes and to supply minerals. A guideline for corrosion control with residual chlorine should be set up. The effects of residual chlorine should be included in the corrosiveness index of tap water.

ANALYSIS ON MICROBIOLOGICALLY INFLUENCED CORROSION FAILURE CASE OF SUS316L STAINLESS STEEL WELDS

  • Miyano, Yasuyuki;Yamamoto, Michiyoshi;Watanabe, Kazuya;Kikuchi, Yasushi
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.133-138
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    • 2002
  • Microbiologically Influenced Corrosion (MIC) was suspected in a corrosion failure of cooling system of stainless piping welded joint, carrying marine water. Marine water which is used for cooling water in a plant was transferred to the laboratory and used for experiment. In the first experiment, weld metal samples were exposed to the test solution for 56 days (marine water and sterilized marine water (control)). Surface condition of experimental coupons was observed using a Scanning Electron Microscope (SEM). In another experiment, free corrosion potential of these material was monitored for 56 days. Pitting corrosion was found in the coupons exposed to marine water. Free corrosion potential ennoblement was found to be significant compared to control. It was suspected that this corrosion case was MIC. In the second experiment, coupons were exposed to diluted nutrient medium containing single culture of microbes isolated from the MIC causing marine water sample used for the first experiment. After exposure test, surface condition of experimental coupon was observed using SEM. Pitting corrosion was found in coupons exposed to some of the isolates. The results indicate that they contribute to the corrosive effect of the SUS316L welds.

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Atmospheric Corrosion Process for Weathering Steel

  • Nagano, Hiroo;Yamashita, Masato
    • Corrosion Science and Technology
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    • 제7권2호
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    • pp.119-124
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    • 2008
  • Steel is generally not corrosion resistant to water with formation of non protective rusts on its surface. Rusts are composed of iron oxides such as $Fe_3O_4$, $\alpha-$, $\beta-$, $\gamma-$and ${\delta}-FeOOH$. However, steel, particularly weathering steel containing small amounts of Cu, Ni and Cr etc., shows good corrosion resistance against rural, industrial or marine environment. Its corrosion rate is exceedingly small as compared with that of carbon steel. According to the exposure test results undertaken in outdoor environments, the atmospheric corrosion rate for weathering steel is only 1 mm for a century. Atmospheric corrosion for steels proceeds under alternate dry and wet conditions. Dry condition is encountered on steel surface on fine or cloudy days, and wet condition is on rainy or snowy days. The reason why weathering steel shows superior atmospheric corrosion resistance is due to formation of corrosion protective rusts on its surface under very thin water layer. The protective rusts are usually composed of two layer rusts; the upper layer is ${\gamma}-FeOOH$ termed as lepidocrocite, and inner layer is nano-particle ${\alpha}-FeOOH$ termed as goethite. This paper is aimed at elucidating the atmospheric corrosion mechanism for steel in comparison with corrosion in bulky water environment by use of empirical data.The summary is as follows: 1. No corrosion protective rusts are formed on steel in bulky water. 2. Atmospheric corrosion for steel is the corrosion under wetting and drying conditions. Corrosion and passivation occur alternately on steel surface. Steel, particularly weathering steel with small amounts of alloying elements such as Cu, Ni and Cr etc. enhances forming corrosion protective rusts by passivation.