• Title/Summary/Keyword: water corrosion

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Analysis of Pipe Wall-thinning Caused by Water Chemistry Change in Secondary System of Nuclear Power Plant (원전 2차계통의 수화학 변화가 배관감육에 미치는 영향 분석)

  • Yun, Hun;Hwang, Kyeongmo;Moon, Seung-Jae
    • Corrosion Science and Technology
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    • v.14 no.6
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    • pp.325-330
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    • 2015
  • Pipe wall-thinning by flow-accelerated corrosion (FAC) is a significant and costly damage of secondary system piping in nuclear power plants (NPPs). All NPPs have their management programs to ensure pipe integrity from wall-thinning. This study analyzed the pipe wall-thinning caused by changing the amine, which is used for adjusting the water chemistry in the secondary system of NPPs. The pH change was analyzed according to the addition of amine. Then, the wear rate calculated in two different amines was compared at the steam cycle in NPPs. As a result, increasing the pH at operating temperature (Hot pH) can reduce the rate of FAC damage significantly. Wall-thinning is affected by amine characteristics depending on temperature and quality of water.

A Study on the Test Methods of Bond Strength in Waterproofing and Anti-corrosion Materials by Reversed Pressure (역수압 작용을 고려한 방수·방식재의 부착강도 시험방법에 관한 연구)

  • Kim, Meong-Ji;Choi, Su-Young;Choi, Sung-Min;Oh, Sung-Keun
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.232-233
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    • 2014
  • Recently, water treatment facility is usually eastablished in underground, and waterproofing and anti-corrosion materials for concrete structures applied water treatment tank is developing in various ways. However, as the limit of research focused on durability improvement of top coating material, it is insufficient to study on the adhesion strength between the concrete surface and primer. Therefore, there is to confirm the adhesion of between concrete surface and the three primers used as anti-corrosion waterproofing materials, and to investigate the properties of adhesion strength according to the condition such as wet codition and water pressure condition of the concrete surface in this study.

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Failure Investigation of Fire-Side Water-Wall Tube Boiler

  • Fatah, M.C.;Agustiadi, D.;Pramono, A.W.
    • Corrosion Science and Technology
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    • v.20 no.5
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    • pp.242-248
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    • 2021
  • Unforeseen failures of boilers in power plants may affect the continuation of electricity generation. Main failures in boilers are influenced by the tube material, tube position, boiler service temperature and pressure, and chemical composition of the feed water and coal. This investigation was intended to find answers on the causes and mechanism of failure of the fire-side boiler water-wall tubes, due to perforation and corrosion. The tube conformed to the material requirements in terms of its chemical composition and hardness. Microscopic examination showed ferrite and pearlite indicating no changes in its microstructure due to the temperature variation. SEM test showed a single layer and homogenous film density particularly on the area far from perforation. However, layers of corrosion product were formed on the nearby perforation area. EDX showed that there were Na, Ca, S, and O elements on the failed surface. XRD indicated the presence of Fe2O3 oxide. The failure mechanism was identified as a result of significant localized wall thinning of the boiler water wall-tube due to oxidation.

Study on the Characteristics of Cavitation Erosion-Corrosion for Mild Steel ( 1 ) - Damage Behaviour of Vibration Cavitation Erosion-Corrosion - (연강의 캐비테이션 침식-부식 특성에 관한 연구 ( 1 ) - 진동 캐비네이션 침식-부식 손상 거동 -)

  • Lim, Un-Joh;Hwang, Jae-Ho
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.31 no.4
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    • pp.413-422
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    • 1995
  • Cavitation erosion-corrosion implies damage to materials due to the shock pressure or shock wave that results when bubbles form and collapse at a metal surface within a liquid. If the liquid is corrosive to the material, a condition typically encountered in industry, the component materials may suffer serious damage by a combination of mechanical and electrochemical attack. In this study, the mild steel(SS41) was tested by using the piezoelectric vibrator with 20kHz, 24$\mu$m to cavity generation apparatus. The damage behaviour of vibration cavitation erosion-corrosion and the environment characteristics were investigated in various solutions which are seawater, tap water and distilled water. The main results obtained are as follows; 1) The cavitation erosion-corrosion damage behaviour in the seawater increases to occur at the equal degree on the middle portion and the outside portion of specimen. The distilled water specimen, on other hand, occurs beginning on the outside portion across to the middle portion of specimen. 2) The cavitation erosion-corrosion damage in the tap water of low specific resistance more increases than that in the distilled water of high specific resistance at the initial testing time and more decreases than that in it by the CaCO sub(3) film with testing time. 3) Cavitation erosion-corrosion damage characteristic divides into four regions; incubation region, acceleration region, deceleration region and steady state region.

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Study of Drinking water pipeline Corrosion Mechanism by using Scale Analysis (부식 생성물 분석법을 이용한 상수도 금속관의 부식거동에 관한 연구)

  • 황상용;송호봉
    • Journal of environmental and Sanitary engineering
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    • v.17 no.1
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    • pp.57-62
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    • 2002
  • Carbon cast iron and Zinc coated steel were the most widely used portable water of supply and distribution Pipeline system. The leaching of red water in portable water could produce sericus environmental sanitary problems. Due to the red water was the most alternative to inner scale of metal pipeline. So this study was conducted the impact of red water on scale products, and was evaluated by the corrosive metal contaminants of 20 fears over. Surface tests, metal surface composition measurements of samples XRF, XRD, and SEM(EDS), analysis were used to investigate the corrosion characteristies of carbon cast iron and Zinc coated steel. As the contaminants of Fe increased the red water of carbon castiron pipe increased due to the scale products amount of $Fe_2O_3$ (Hemite).

New test method for real-time measurement of SCC initiation of thin disk specimen in high-temperature primary water environment

  • Geon Woo Jeon;Sung Woo Kim;Dong Jin Kim;Chang Yeol Jeong
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4481-4490
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    • 2022
  • In this study, a new rupture disk corrosion test (RDCT) method was developed for real-time detection of stress corrosion cracking (SCC) initiation of Alloy 600 in a primary water environment of pressurized water reactors. In the RDCT method, one side of a disk specimen was exposed to a simulated primary water at high temperature and pressure while the other side was maintained at ambient pressure, inducing a dome-shaped deformation and tensile stress on the specimen. When SCC occurs in the primary water environment, it leads to the specimen rupture or water leakage through the specimen, which can be detected in real-time using a pressure gauge. The tensile stress applied to the disk specimen was calculated using a finite element analysis. The tensile stress was calculated to increase as the specimen thickness decreased. The SCC initiation time of the specimen was evaluated by the RDCT method, from which result it was found that the crack initiation time decreased with the decrease of specimen thickness owing to the increase of applied stress. After the SCC initiation test, many cracks were observed on the specimen surface in an intergranular fracture mode, which is a typical characteristic of SCC in the primary water environment.

Experimental Study on the Penetration Depth and Concentration of Corrosion Inhibitor Using Press-in Method Into the Inside of Concrete (콘크리트 내부로의 압입공법을 사용한 방청제의 침투깊이 및 농도에 관한 실험적 연구)

  • Cho, Hyeong-Kyu;Yoo, Jo-Hyeong;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.13 no.5 s.57
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    • pp.160-168
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    • 2009
  • After steel bar was corroded it removes concrete contaminated, it does steel bar corrosion protection, repairing method and corrosion inhibitor spreading method are difficult to secure corrosion protection performance. Accordingly, in this research before Research and Development to penetrate corrosion inhibitor to high pressure by steel bar position, it measures penetration depth through corrosion inhibitor high pressure penetration experiment and amount of nitrite by position and then it predicts penetration depth in accordance with water-cement ratio, pressure, pressure time and it computed water-cement ratio, pressure, pressure time to be more than 0.6 mol ratio of chloride ion and nitrite to have outstanding corrosion protection performance. As a result of experiment, water-cement ratio gives the biggest influence to penetration of corrosion inhibitor and also the more depth of specimen becomes deep, concentration of penetrated corrosion inhibitor does not equal and becomes low.

Investigation of Pitting Corrosion of Copper Heat-Return Pipe in District Heating (지역난방 구리난방환수관의 공식 원인 분석)

  • Keun Hyung Lee;Min Ji Song;Tae Uk Kang;Woo Cheol Kim;Heesan Kim;Soo Yeol Lee
    • Corrosion Science and Technology
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    • v.23 no.4
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    • pp.315-323
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    • 2024
  • This work examined pitting corrosion failure of a copper heat-return pipe used in a district heating system. The copper pipe was corroded with a 48% reduction in thickness due to localized corrosion on the inner surface exposed to heating water of 20 ~ 40 ℃. Fe and Si elements as corrosion products were found around pits. Cl element was also observed, which accelerated oxidation of copper inside pits. Cu2O deposits on the pit's bottom surface decreased the pH inside the pit. X-ray diffraction analysis revealed hematite, cuprite, malachite and brochantite as corrosion products. Chemical analysis demonstrated that Fe and Si elements did not exist in the copper, supply water, or heating water, indicating that Fe and Si species might have entered into the pipe from the exterior. These results indicated that pits were initiated due to ion concentration gradient near Fe and Si species. Moreover, the interior of pits had lower pH due to Cl- concentration and Cu2O reactions, which accelerated the pit's growth and led to formation of pinholes. Additionally, we confirmed that the type of pitting corrosion was a complex combination of types I and II based on the HCO3-/SO42- ratio, pH, temperature, and corrosion products.

The Capacity of Applying Electrical Resistance Probe in Natural Corrosion Tests of Vietnam

  • Pham, Thy San;Le, Thi Hong Lien;Le, Quoc Hung
    • Corrosion Science and Technology
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    • v.2 no.2
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    • pp.98-101
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    • 2003
  • The Electrical Resistance Probe of carbon steel and weight loss coupons were exposed in atmosphere and in the lake water of Hanoi. The comparison of data received by two methods after one year exposure was presented. The correspondence of the data of these methods on the exposure time in both environments showed a capacity of using Electrical Resistance Probe in Vietnamese natural corrosion testing of Carbon steel.

A Study on the Crevice Corrosion Behavior of Chromium Plating (크롬도금의 틈부식 거동에 관한 연구)

  • 곽남인;임우조
    • Journal of the Korean institute of surface engineering
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    • v.36 no.4
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    • pp.324-328
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    • 2003
  • This study was made on the crevice corrosion behavior of chromium plating in fresh water. Under the various crevice, the electrochemical polarization test of chromium plating was carried out. Results are discussed In terms of corrosion potential, polarization resistance, corrosion current density and cathodic control of chromium plating.