• Title/Summary/Keyword: water corrosion

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Environmental Exposure Performance of a Panel-Type Glass-Fiber-Reinforced Polymer Composite Clamping Plate for an Improved Moveable Weir (개량형 가동보에 적용하기 위한 패널형 유리섬유보강 폴리머 복합재료 클램핑 플레이트의 환경노출 성능)

  • Yoo, Seong-Yeoul;Jeon, Jong-Chan;Shin, Hyung-Jin;Park, Chan-Gi
    • Journal of The Korean Society of Agricultural Engineers
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    • v.59 no.5
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    • pp.73-81
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    • 2017
  • The improved movable weir supplements the advantages and disadvantages of the rubber weir and the conduction gate. It consists of a stainless steel gate, air bags, and a steel clamping plate. The stainless steel gate is the main body of the weir, and the inflatable rubber sheet serves to support the steel gate. The steel clamping plate is typically in direct continuous contact with water, but this leads to corrosion issues that can reduce the life of the entire movable weir. In this study, a panel-type glass-fiber-reinforced polymer (GFRP) clamping plate was designed and fabricated. The test results showed that the flexural load of the panel-type GFRP composite clamping plate was over twice that of the wings type GFRP clamping plate. The lowest moisture absorption value was obtained upon exposure to tap water, and exposure to other solutions showed similar values. Additionally, flexural load testing after exposure to an accelerated environment found the lowest residual loads of 80.51 % and 78.50 % at 50 and 100 days, respectively, for exposure to a $CaCl_2$ solution, while exposure to other environments showed residual failure loads of over 80 % at both 50 and 100 days.

Validation Study on Processing Grip Part of Tensile Specimen Acquired from Corroded Pipeline (부식이 존재하는 기존 노후 관로에서 인장 시편 가공 시 그립 가공 타당성에 대한 연구)

  • Nam, Young Jun;Kim, Jeong Hyun;Bae, Cheol Ho;Lim, Yun Mook
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.40 no.2
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    • pp.191-195
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    • 2020
  • In this work, tensile tests, one of the most common test method to assess the condition of a corroded pipe, were conducted. According to ASTM E8 method, the use of flat or curved uni-axial tension test is allowed under the recommendation with the usage of grips corresponding to a curvature of the pipe. However, this method is not for corroded specimen. Furthermore, in the case of performing the multiple tensile tests with various curvatures, it is desirable not to produce zigs that fit each curvatures, if merely processing the specimen grip with curvature into the flat grip can show almost identical tensile behavior. Therefore, various tension simulations were conducted first to check if there exist any differences. Also, experiments on corroded tensile specimen were conducted and compared with the FEM simulation that reflects the actual geometry acquired from the 3D scanner.

An Effects of Radiation Dose Assessment for Radiation Workers and the Member of Public from Main Radionuclides at Nuclear Power Plants (원전에서 발생하는 주요 방사성핵종들이 방사선작업종사자와 원전 주변주민의 피폭방사선량 평가에 미치는 영향)

  • Kim, Hee-Geun;Kong, Tae-Young;Jeong, Woo-Tae;Kim, Seok-Tae
    • Journal of Radiation Protection and Research
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    • v.35 no.1
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    • pp.12-20
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    • 2010
  • In a primary system at nuclear power plants (NPPs), various radionuclides including fission products and corrosion products are generated due to the complex water conditions. Particularly, $^3H,\;^{14}C,\;^{58}Co,\;^{60}Co,\;^{137}Cs,\;and^{131}I$ are important radionuclides in respect of dose assessment for radiation workers and management of radioactive effluents. In this paper, the dominant contributors of radiation exposure for radiation workers and the member of public adjacent to NPPs were reviewed and the process of dose assessment attributable to those contributors were introduced. Furthermore, the analysis for some examples of radiation exposure to radiation workers and the public during the NPP operation was carried out. This analysis included the notable precedents of internal radiation exposure and contamination of demineralized water occurred in Korean NPPs. Particularly, the potential issue about the dose assessment of tritium and carbon-14 was also reviewed in this paper.

A fundamental study on the sulphate-resistant mortar using waste glass fine powder and meta-kaolin according to various fine aggregates (잔골재 종류에 따른 폐유리 미분말 및 메타카올린을 사용한 내황산염 모르타르에 관한 기초적 연구)

  • Jeong, Dongwhan;Park, Junhui;Ahn, Taeho;Park, Yeongsik;Sho, Kwangho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.3
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    • pp.115-121
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    • 2017
  • The degradation of the concrete due to deterioration factors, such as corrosion of steel bars, cracks and structural strength of reinforced concrete structures, is a social problem. Especially, concrete structures constructed in seawater, underground water, waste water treatment facilities and sewerage are subject to chemical attack by acid and sulphate. Therefore, this study was conducted to compare sulfated glass and fine aggregate of slag using waste glass fine powder and meta kaolin. The results showed that the slag fine aggregate showed better sulfate resistance than the river sand, and the fine powder of waste glass showed the best performance at 3 % displacement.

Prediction of the Flow Coefficient of a PFA Lined Ball Valve Using the CFD Simulation Method (CFD 해석방법을 이용한 PFA 라이닝 볼밸브의 유량계수 예측)

  • Jeon, Hong-Pil;Lee, Won-Seob;Kim, Chul-Soo;Lee, Jong-Chul
    • The KSFM Journal of Fluid Machinery
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    • v.19 no.4
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    • pp.35-38
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    • 2016
  • A PFA lined ball valve, which is machined with fluorinated resin PFA to its inner part for improving corrosion resistance, non-stickness, heat-resistance, has been widely used in semiconductor/LCD manufacturing processes with the high purity chemicals as working fluid. Due to the safety concerns, the experiments for measuring the flow coefficient of a PFA lined ball valve should be conducted with water at room temperature according to IEC standards. However, it is required to know the real flow coefficient with the real working fluid, because the flow coefficient is critical to correctly design valves in piping system. In this study, we calculated the flow coefficient of a PFA lined ball valve 40A with hydrochloric acid ($40^{\circ}C$ 36% HCl) as the working fluid using a commercial CFD package, ANSYS CFX v15. The computational results had a good agreement with the measured data and showed a little difference between water and hydrochloric acid as the working fluid of a PFA lined ball valve.

A Study I on the Sizing Accuracy of the Characterized Defects of the Reactor Vessel Head Penetrations (원자로헤드 관통관 결함의 검출 정확성 연구)

  • Chung Tae-hoon;Kim Han-Jong
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 2005.05a
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    • pp.216-227
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    • 2005
  • The head penetrations for control rod drive mechanism and instrumentation systems are installed at the reactor pressure vessel head of PWRs. Primary coolant water and the operating conditions of PWR plants can cause cracking of these nickel-based alloy through a process called primary water stress corrosion cracking (PWSCC). Inspection of the head penetrations to ensure the integrity of the head penetrations has been interested since reactor coolant leakages were found at U. S. reactors in 2000 and 2001. The complex geometry of the head penetrations and the very low echo amplitude from the fine, multiple flaws due to the nature of the see made it difficult to detect and size the flaws using conventional pulse-echo UT methods. Time-of-flight-diffraction technique, which utilizes the time difference between the flaw tips while pulse-echo does the flaw response amplitude from the flaw, has been selected for this inspection for it's best performance of the detection and sizing of the head penetration see flaws. This study defines the limits of the detectable and accurately sizable minimum flaw size which can be detected by the General TOFD and the Delta TOFD techniques for circumferentially and axially oriented flaws respectively. These results assures the reliability of the inspection techniques to detect and accurately size for various kind of flaws, and will also be utilized for the future development and qualifications of the TOFD techniques to enhance the detecting sensitivity and sizing accuracy of the flaws of the reactor head penetrations in nuclear power plants.

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고온 물에서 304 와 600 합금의 입계응력부식균열(IGSCC)의 상이성과 유사성

  • 권혁상;김수정
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 1998.05a
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    • pp.22-22
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    • 1998
  • 304 는 BWR(boiling water reactor)의 reactor 구조용 재료로 사용되고 있고, 합금 600 은 PWR(pressurized water reator) 의 증기 발생기 세관으로 쓰이고 있으며 모두 약 $280{\;}^{\circ}C$ 이상 의 원자로 냉각수에 노출되어 있다. 원자로 냉각수 분위기에서 두 합금의 공통적인 특정은 입계응력부식균열(IGSCC)에 민감한것과 IGSCC가 예민화(sensitization)와 관련이 있는 것이 다. 두 합금에서 일어나는 IGSCC는 원자력발전소의 부식피해중 가장 빈도가 높고 발생시 방사능 누출로 인하여 원전의 신뢰성을 저하시키고, 가동중단으로 인한 경제적 손실을 초 래하여 지난 20 년 동안 가장 심도있게 연구된 주제다. 304 은 크롬 탄화물의 업계 석출로 언하여 예민화된경우 IGSCC 에 민감한 반면 600 은 예민화된 경우 뿐만 아니라 용체화처리된 상태에서도 IGSCC에 민감하다. 오히려 600은 용 체화처리 후 700 C에서 15~20시간 시효처리를 하여 크롬탄화물을 업계에 석출 시커었을 때 IGSCC 저항성이 향상된다. 두 합금의 IGSCC 특정 중 큰 차이는 304는 임계균열전위 ( (critical cracking potential) 이 존재하여 부식전위(corrosion potential) 가 엄계균열전위보다 낮 은 경우 IGSCC 가 일어나지 않지만 그 반대인 경우 IGSCC 에 민감하게된다. 반면에 600 은 뚜렷한 임계균열전위가 존재하지 않고 양극 분극(anodic polarization) 뿐만 아니라 음극분극 시에도 IGSCC 가 일어난다. 이련 이유로 600의 IGSCC 가구로 피막파괴-양극용해(film rupture-anodic dissolution)외에 수소취성(hydrogen embrittlement)기구도 제안되고 었다. 원전의 냉각수는 고 순도의 물이지만 수 처리 과정과 웅축기 배관의 누수로 인한 산소, $Cu^{2+},{\;}S_xO_6{\;}^{2-}(x=3~6)$ 등이 유입되어 오염되는데 이려한 오염물질들이 수 ppm정도 소량 포함된 경우 응 력부식민감도는 상당히 증가된다. 산성분위기 흑은 산소, $Cu^{2+}$, 등이 소량 포합된 산화성 분위기 그리고 sufur oxyanion 에 오염된 고온의 물에서 600 의 IGSCC 민감도는 예민화도가 증가할 수록 민감하여 304 의 IGSCC 와 매우 유사한 거동을 보인다. 본 강연에서는 304 와 600 의 고온 물에서 일어나는 IGSCC 민감도에 미치는 환경, 예민화처리, 합금원소의 영향을 고찰하고 이에 대한 최근의 연구 동향과 방식 방법을 다룬다.

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Optimal Remediation of TCE-contaminated Groundwater using Direct Current and Fe$^0$ (직류전원과 0가 철을 이용한 지하수내 TCE정화효율의 최적화 연구)

  • Moon, Ji-Won;Moon, Hi-Soo;Roh, Yul;Kim, Heon-Ki;Song, Yun-Goo
    • Economic and Environmental Geology
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    • v.35 no.3
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    • pp.229-239
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    • 2002
  • The objective of this study was to design an optimal electro-remediation system for TCE contaminated water using zero talent iron (ZVI) and direct current (DC). A series of column experiments were conducted to evaluate the effects of electrode arrangement and the location of permeable iron barrier in the column on the TCE removal efficiency and iron corrosion process. In twelve different combinations of ZVI and/or DC application in the test columns, the rate of reductive degradation of TCE was improved with simultaneous application of both ZVI and DC compared to that used ZVI only. The moot effective arrangement of electrode and ZVI for TCE removal from water was a column set with ZVI and cathode installed at the down gradient, respectively.

A Study on the Polarization Potential Distrbution of a Steel Disc in the Water by Specific Resistance of Corrosion Circumstances (환경의 비저항을 고려한 수중 원강판의 분극전위분포에 관한 연구)

  • 김귀식
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.17 no.2
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    • pp.105-108
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    • 1981
  • The oceanic effect on the climate of the southern coast of Korea was analysed based on the sea surface temperature and in order to study relationships between the fluctuation of the sea surface temperature and that of climatic elements. Meteolorogical data from 1960 to 1979 were used. In the year when difference between the air and water temperature was maximum, the air temperature in southern coast was higher than normal year. A fluctuation of the sea surface temperature plays an important influence to determine the variation of the air temperature in the coastal area. Humidity of the coastal climate depends upon the oceanic effect in summer, but not in winter. This results may be due to prevailing wind effect. The oceanic effect on the precipitation in the coastal area is not found.

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Electrical resistivity and capillarity of self-compacting concrete with incorporation of fly ash and limestone filler

  • Silva, Pedro;de Brito, Jorge
    • Advances in concrete construction
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    • v.1 no.1
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    • pp.65-84
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    • 2013
  • Electrical resistivity is a property associated with both the physical and chemical characteristics of concrete. It allows the evaluation of the greater or lesser difficulty with which aggressive substances penetrate the concrete's core before the dissolution of the passive film process and the consequent reinforcement's corrosion begin. This work addresses the capillary absorption of self-compacting concrete (SCC) with various types and contents of additions, correlating it with its electrical resistivity. To that effect, binary and ternary mixes of SCC were produced using fly ashes (FA) and limestone filler (LF). A total of 11 self-compactable mixes were produced: one with cement (C) only; three with C + FA in 30%, 60% and 70% substitution ratios; three with C + LF in 30%, 60% and 70% substitution ratios; four with C + FA + LF in combinations of 10-20%, 20-10%, 20-40% and 40-20% substitution ratios, respectively; and four reference mixes according to the LNEC E 464 specification, which refers to the NP EN 206-1 norm. The evaluation of the capillarity of the mixes produced was made through the determination of the water absorption by capillarity coefficient according to the LNEC E 393 specification. The electrical resistivity was evaluated using the European norm proposal presented by the EU-Project CHLORTEST (EU funded research Project under 5FP GROWTH programme) and based on the RILEM TC-154 EMC technical recommendation. The results indicate that SCC's capillarity is strongly conditioned by the type and quantity of the additions used. It was found that FA addition significantly improves some of the properties studied especially at older ages.