• Nuclear Engineering and Technology
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• v.52 no.3
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• pp.597-609
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• 2020

Accident Tolerant Fuels have been widely studied since the Fukushima-Daiichi accident in 2011 as one of the options on how to further enhance the safety of nuclear power plants. Deposition of protective coatings on nuclear fuel claddings has been considered as a near-term concept that will reduce the high-temperature oxidation rate and enhance accidental tolerance of the cladding while providing additional benefits during normal operation and transients. This study focuses on experimental testing of Zr-based alloys coated with Cr-based coatings using Physical Vapour Deposition. The results of long-term corrosion tests, as well as tests simulating postulated accidents, are presented. Zr-1%Nb alloy used as nuclear fuel cladding serves as a substrate and Cr, CrN, Cr_xN_y layers are deposited by unbalanced magnetron sputtering and reactive magnetron sputtering. The deposition procedures are optimized in order to improve coating properties. Coated as well as reference uncoated samples were experimentally tested. The presented results include standard long-term corrosion tests at 360℃ in WWER water chemistry, burst (creep) tests and mainly single and double-sided high-temperature steam oxidation tests between 1000 and 1400℃ related to postulated Loss-of-coolant accident and Design extension conditions. Coated and reference samples were characterized pre- and post-testing using mechanical testing (microhardness, ring compression test), Thermal Evolved Gas Analysis analysis (hydrogen, oxygen concentration), optical microscopy, scanning electron microscopy (EDS, WDS, EBSD) and X-ray diffraction.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.773-776
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• 2008

The corrosion of steel in concrete is significant in marine environment. Marine bridges are readily deteriorated due to the exposure to marine environment. Salt damage is one of the most detrimental causes to concrete bridges and port structures. Especially, the splash and tidal zones around water line are comparatively important in terms of safety and life-time point of view. During the last several decades, cathodic protection (cp) has been commonly accepted as an effective technique for corrosion control in concrete structures. Zn-mesh sacrificial anode has been recently developed and started to apply to the bridge column cp in marine condition. The detailed parameters regarding Zn-mesh cp technique, however, have not well understood. This study is to investigate how much Zn-mesh cp influences along the concrete column at elevated temperature. About 100cm column specimens with eight of 10cm segment rebars have been used to measure the variation of cp potential with the distance from Zn-mesh anode at both 10$^{\circ}$C and 40$^{\circ}$C in natural seawater. The cp potential change and current diminishment along the column specimens have been discussed for the optimum design of cp by Zn-mesh sacrificial anode

• Advances in concrete construction
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• v.9 no.2
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• pp.207-215
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• 2020

This paper describes the experimental studies carried out to determine the properties of fresh and hardened concrete with Recycled Plastic Waste (RPW) as a partial replacement material for fine aggregates. In the experimental study, RPW was used for replacing river sand and manufactured sand (M sand) aggregates in concrete. The replacement level of fine aggregates was ranging from 5% to 20% by volume with an increment of 5%. M40 grade of concrete with water cement ratio of 0.40 was used in this study. Two different types of RPW were used, and they are (i) un-activated RPW and (ii) activated RPW. The activated RPW was obtained by alkali activation of un-activated RPW using NaOH solution. The hardened properties of the concrete determined were dry density, compressive strength, split tensile strength, flexural strength and ultrasonic pulse velocity (UPV). The properties of the concrete with river sand, M sand, activated RPW and un-activated RPW were compared and inferences were drawn. The effect of activation using NaOH solution was investigated using FT-IR study. The micro structural examination of hardened concrete was carried out using Scanning Electron Microscopy (SEM). The test results show that the strength of concrete with activated RPW was more than that of un-activated RPW. From the results, it is evident that it is feasible to use 5% un-activated RPW and 15% activated RPW as fine aggregates for making concrete without affecting the strength properties.

• Journal of Technologic Dentistry
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• v.27 no.1
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• pp.79-88
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• 2005

This study was performed to investigate the surface properties of electrochemically oxidized pure niobium by anodic oxide and hydrothermal treatment technique. Niobium specimens of $10\times10mm$ in dimension were polished sequentially from #600, #800, #1000 emery paper. The surface pure niobium specimens were anodized in an electrolytic solution that was dissolved calcium and phosphate in water. The electrolytic voltage was set in the range of 250 V and the current density was 10 $mA/cm^2$. The specimen was hydrothermal treated in high-pressure steam at 300$^{\circ}C$ for 2 hours using an autoclave. Then, specimens were immersed in the Hanks' solution with pH 7.4 at 37$^{\circ}C$ for 30 days. The surface of specimen was characterized by scanning electron microscope(SEM), energy dispersive X-ray microanalysis(EDX), potentiostat/galvanostat test, and cytotoxicity test. The results obtained was summarized as follows; According to the result of measuring corrosion behavior at 0.9% NaCl, corrosion resistance was improved more specimens treated with anodic oxide than in hydrothermal treated ones. The multi-porous oxide layer on surface treated through anodic oxidation showed a structure that fine pores overlap one another, and the early precipitation of apatite was observed on the surface of hydrothermal treated samples. According to the result of EDX after 30 days deposition in Hanks' solution, Ca/P was 1.69 in hydrothermal treated specimens. In MTT test, specimens treated through anodic oxidation and hydrothermal treated ones showed spectrophotometer similar to that of the control group. Thus no significant difference in cytotoxicity was observed (P>0.05).

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.4
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• pp.65-71
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• 2014

As an important component of a fuel cell, the bipolar plate comprises a large proportion in the fuel cell's volume, weight and price. The bipolar plate is the most widely used; however, graphite bipolar plate is large in volume, brittle and therefore easily broken during assembling. In addition, due to its poor machinability, production costs a lot, unless mass production. Compared with the graphite bipolar plate, the metal bipolar plate has good machinability, high electric conductivity and strong mechanical strength; however, it corrodes easily and has a high contact resistance, so in order to prevent corrosion and reduce the contact resistance, the basic metal needs to be processed by use of electro polishing and coating. The water which is produced by electrochemical reactions in the fuel cell must be discharged smoothly. In this study, in order to prevent corrosion the processes of electro polishing and CrN coating were used. According to the presence or absence of these processes, the contact angles can be measured and different metal bipolar plates can be made, these plates can be used for comparing and analyzing the performance of the fuel cell.

• Proceedings of the KWS Conference
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• 2009.11a
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• pp.16-16
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• 2009

Alloy 82/182로 용접된 원자력 발전소 주기기의 이종 금속 용접부는 장기간 운전 후 응력부식균열(SCC : Stress Corrosion Cracking)에 의한 결함이 나타나게 된다. 2000년대 이후로 원자력 주기기 Alloy 82/182 용접부에서 PWSCC(Primary Water Stress Corrosion Cracking)에 의한 Degradation이 급격히 증가하는 추세를 보이고 있으며, 국내에서도 이와 관련하여 원자력 발전소의 안전성에 대한 Issue 및 대비책에 대한 관심이 고조되고 있다. 이러한 Alloy 600 용접부에 대한 결함을 예방하기 위한 대표적인 기술로써 수명연장 오버레이 기술이 있다. 원자력 주기기 노즐부는 저탄소강으로 제작되어 있으며, 저탄소강에는 제작 시 용접후열처리가 적용된다. 후열처리를 하는 주된 이유는 Tempering을 통해 열영향부의 인성 및 연성의 회복과 강도를 감소시켜 모재와 동등 또는 이 이상의 물성을 갖도록 하는 데 그 목적이 있다. 그러나 수명연장 오버레이의 경우 현장 작업 시에 후열처리가 어렵기 때문에, 이를 대체하기 위한 기술로 템퍼비드 용접을 적용할 경우 후열처리를 면제해 주고 있다. 본 연구에서는 수명연장 오버레이 기술 개발의 일환으로써 저 탄소강에 대한 템퍼비드 용접 기술을 확립하였다. 실험에 사용된 모재는 원자력 주기기의 노즐에 사용되는 SA508 Gr.3 Cl.1을 사용하였으며, 용가재는 Alloy 52 및 52M을 사용하였다. 최적 조건 도출을 위해서 실험 매트릭스를 이용하여 기본 실험을 수행하였으며, 실험에는 자동 GTAW 용접을 적용하였다. 기본 실험을 통해 얻은 최적 조건을 사용하여 PQ 시험을 수행하여 WPS를 확보하였다. 분석은 용접 후 조직 및 경도 시험, 물리시험(인장시험, 굽힘시험 및 충격시험)을 수행하였다.

• Transactions of the Korean Society of Mechanical Engineers
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• v.17 no.6
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• pp.1404-1411
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• 1993

This study was undertaken to investigate the corrosive wear charateristics upon various transformation condition of austempered low-alloy ductile cast iron in corrosive environments against mating specimen made of the hardened SM45C. The corrosive wear test was carried out by rubbing the annular surface of two test pieces in distilled water and aqueous solution at constant sliding speed of 0.5m/s. In severe wear region, the corrosive wear rate Wc increased hastily with NaCl concentration owing to intermetallic adhesion but Wc went down slowly in mild wear region due to lubricating effect of the corrosion product. The critical sliding distance decreased with increasing NaCl concentration due to increased generation rate of the corrosion product and the specific corrosive wear rate has maximum in 1% NaCl aqueous solution at mild wear region. With the variation of matrix, the corrosive wear resistance of the fine acicular bainite was higher than that of coarse upper bainite because of reducing the local cell reaction by carbides. A growth in volume fraction of retained austenite in matrix increased the Wc due to soften surface, but has a declining tendency of Wc in mild wear region.

• Journal of the Korea institute for structural maintenance and inspection
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• v.9 no.1
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• pp.251-258
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• 2005

Up until now, most protection design has been concerned primarily with concrete's exterior protection from corrosion, its waterproof ability and its reparability. However, there are many cases in which service life of the concrete is shortened because suitability of the type of concrete surface has not been thoroughly investigated in the development process. According1y, this paper presents the development and test of the material for its reparability and its protection against corrosion in the case of wet surfaces (i.e. water supply facilities, sewage systems, and port facilities) in this country. From the test, both A type and B type are excellent for durability in watertightness, chemical resistance and abrasion. Test results of adhesive strength over $15kgf/cm^2$ under both wet and dry conditions, curing conditions and various temperatures conditions were also achieved in field tests.

• Journal of Ocean Engineering and Technology
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• v.22 no.3
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• pp.76-81
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• 2008

There are two cases when the life of a sacrificial anode is shortened from the designed life: one case results from self-corrosion of the anode due to contamination by sea water in the other case, however, electrical current to protect some given steel piles overflows to protect other, adjacent non-protected steel piles. In this study, the variation of polarization potential of nine steel piles, being protected cathodically and with anode-producing current between anode and steel piles, was investigated. Parameters were varied, such as the eighth and ninth steel piles either connected electrically or not, and whether the ninth steel pile was protected by another sacrificial anode or not. The current produced by the sacrificial anode decreased when the ninth steel pile was cathodically protected by the anode of another pile. However, produced current increased when the ninth steel pile was not connected to another anode. The study concludes that the life of a sacrificial anode can be prolonged or shortened depending on whether adjacent steel piles are cathodically protected or not.

• Corrosion Science and Technology
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• v.19 no.1
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• pp.16-22
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• 2020

It is important to realize that benzoate was intercalated into hydrotalcite (HTC-Bz) by the co-precipitation method. In this case, acrylic coating with 0.5 wt% HTC-Bz was deposited on carbon steel using the spin coating method. Next, the HTC-Bz structure was characterized by Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). In fact, an ultraviolet vision spectroscopy (UV-Vis) was used to determine the benzoate content in HTC-Bz, and the UV absorption ability of HTC-Bz. Using electrochemical techniques, water contact angle measurement, and thermal-gravimetric analysis, we compared the protective properties before and after QUV test, hydrophobicity and the thermal stability of acrylic coating containing HTC-Bz. The obtained results showed that HTC-Bz with a plate-like structure was successfully synthesized; benzoate was intercalated into the interlayer of hydrotalcite with a concentration of 28 wt%. Additionally, it was noted that HTC-Bz has an UV absorption peak at 225 nm. In conclusion, the addition of HTC-Bz enhanced the UV stability, hydrophobicity and the thermal stability of acrylic coating.