• Title/Summary/Keyword: water contribution

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The Exploitation of World Fishery Resources for 10 Years under the New Regime in the Sea (신해양질서 10년후 세계어업자원 이용동향)

  • 이장욱;허영희
    • The Journal of Fisheries Business Administration
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    • v.23 no.1
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    • pp.43-87
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    • 1992
  • In this paper, state of exploitation of world fishery resources after 10 years under the new regime in the sea, called the era of exclusive economic zone (EEZ) expending up to a 200 nautical miles from coastal line, was reviewed to determine effect from establishing EEZ in the world fishery production and its export/import volume based on the fishery statistics annually published by the Food and Agriculture Organization (FAO) of United Nation. The world total production from marine living resources had a trend showing a waned increase during 1970's when most of coastal states were translated into the reality of EEZ. From mid-1980's onwards, it increased rapidly, reaching about 85 million tons . Such increase in production was basically from the Pacific Ocean, accounting for more than 60% of the world total production. Fishing areas where showed increase in the production after the new regime in the sea were the southwestern Atlantic (FAO area 41) , the eastern Indian (FAO area 57) and the whole fishing areas in the Pacific except the eastern central Pacific (FAO area 77). Increase in the production from distant-water fishing countries came from the regions of the southwest Atlantic (FAO area 41) and the southwest Pacific (FAO area 81) . The production from coastal states was up from the regions of the eastern Indian (FAO area 57) , the northwest and northeast Pacific (FAO areas 61 and 67) and the southeast Pacific (FAO area 87) . It was likely that the exploitation of the fishable stocks was well monitored in the areas of the northwest Atlantic (FAO area 21) , the eastern central Atlantic (FAO area 34) and the northeast Pacific (FAO area 67) through appropriate management measures such as annual harvest level, establishment of total allowable catch etc. The marine fisheries resources that have made contribution to the world production, despite expansion of 200 EEZ by coastal states, were sardinellas, Atlantic cod, blue whiting and squids in the Atlantic Ocean : tunas which mainly include skipjack, yellowfin and bigeye tuna, croakers and pony fishes in the Indian Ocean : and sardine, Chilean pilchard, Alaska pollock, tunas (skipjack and yellowfin tuna) , blue grenadier and blue whiting including anchoveta in the Pacific Ocean. It was identified that both fishery production and its export since introduction of the new regime in the sea were dominated by such coastal states as USA, Canada, Indonesia, Thailand, Mexico, South Africa and Newzealand. But difficulties have been experienced in the European countries including Norway, Spain, Japan and Rep. of Korea. Therefore, majority of coastal states are unlikely to have yet undertaken proper utilization as well as rational management of marine living resources in their jurisdiction during the last two decades. The main target species groups which led the world fishery production to go up were Alaska pollock, cods, tunas, sardinellas, chub and jack mackerel and anchoveta. These stocks are largely expected to continue to contribute to the production. The fisheries resources which are unexploited, underexploited and/or lightly exploited at present and which will be contributed to the world production in future are identified with cephalopods, Pacific jack mackerel and Atlantic mackerel, silver hake including anchovies. These resources mainly distribute in the Pacific regions, especially FAO statistical fishing areas 67, 77 and 87. It was likely to premature to conclude that the new regime in the sea was only in favour of coastal states in fishey production.

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Visible Light Driven ZnFe2Ta2O9 Catalyzed Decomposition of H2S for Solar Hydrogen Production

  • Subramanian, Esakkiappan;Baeg, Jin-Ook;Kale, Bharat B.;Lee, Sang-Mi;Moon, Sang-Jin;Kong, Ki-Jeong
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.2089-2092
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    • 2007
  • Tantalum-containing metal oxides, well known for their efficiency in water splitting and H2 production, have never been used in visible light driven photodecomposition of H2S and H2 production. The present work is an attempt in this direction and investigates their efficiency. A mixed metal oxide, ZnFe2Ta2O9, with the inclusion of Fe2O3 to impart color, was prepared by the conventional ceramic route in single- and double-calcinations (represented as ZnFe2Ta2O9-SC and ZnFe2Ta2O9-DC respectively). The XRD characterization shows that both have identical patterns and reveals tetragonal structure to a major extent and a minor contribution of orthorhombic crystalline system. The UV-visible diffuse reflection spectra demonstrate the intense, coherent and wide absorption of visible light by both the catalysts, with absorption edge at 650 nm, giving rise to a band gap of 1.9 eV. Between the two catalysts, however, ZnFe2Ta2O9-DC has greater absorption in almost the entire wavelength region, which accounts for its strong brown coloration than ZnFe2Ta2O9-SC when viewed by the naked eye. In photocatalysis, both catalysts decompose H2S under visible light irradiation (λ ≥ 420 nm) and produce solar H2 at a much higher rate than previously reported catalysts. Nevertheless, ZnFe2Ta2O9-DC distinguishes itself from ZnFe2Ta2O9-SC by exhibiting a higher efficiency because of its greater light absorption. Altogether, the tantalum-containing mixed metal oxide proves its efficient catalytic role in H2S decomposition and H2 production process also.

Effect of Liposome Encapsulation on Intestinal Absorption of Rhodamine 123 (리포솜 봉입이 로다민 123의 소장 흡수에 미치는 영향)

  • Hong, Soon-Sun;Lee, Hae-Ree;Li, Hong;Chung, Suk-Jae;Kim, Dae-Duk;Shim, Chang-Koo
    • YAKHAK HOEJI
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    • v.49 no.2
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    • pp.185-191
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    • 2005
  • The absorption of a P-gp substrate, rhodamine 123, from a liposomal dosage form was investigated across Caco-2 cell monolayers, rat intestines and rat intestinal Peyer's patches in Ussing chamber, Rhodamine 123 was incorporated into liposomes according to the standard evaporation method, which led to a production of liposomes with a mean diameter of 71.3 nm. The permeability (Papp of rhodamine 123 from a water solution across the monolayer was $2.45{\times}10^{-6}$ cm/s for $A{\leftrightarrow}B$ (apical to basal) and $14.0{\times}10^{-6}$ cm/s for $B{\leftrightarrow}A$ (basal to apical) directions, consistent with the fact that rhodamine 123 is one of the P-gp substrates. The transport of rhodamine 123 from the liposomal dosage form was much lower for both directions compared to the solution of rhodamine 123. The transport of rhodamine 123 across the rat intestine was also significantly decreased for both directions, I.e., influx and efflux, by the liposomal incorporation of the compound. The transport of rhodamine 123 across the Peyer's patch was substantially reduced by liposomal incorporation. No difference was found in the transport between the Peyer's patch and non-Peyer's patch. These observations suggest that the contribution of transport via Peyer's patches in the uptake of liposomes may be minimal, especially for rapidly absorbed compounds like rhodamine 123. Therefore, the increased absorption of P-gp substrates does not appear to be feasible by incorporating the compounds in liposomes, due to negligible involvement of Peyer's patches in the uptake of particulate dosage forms like liposomes. Liposomes may rather represent a sustained release dosage form of incorporated compounds.

Kinetic Behavior of Immobilized Tyrosinase on Carbon in a Simulated Packed-Bed Reactor (충전층에서 탄소에 고정시킨 Tyrosinase의 반응속도에 관한 연구)

  • Shin, Sun Kyoung;Kim, Kyeo-Keun
    • Analytical Science and Technology
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    • v.10 no.1
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    • pp.66-74
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    • 1997
  • Influence of the axial dispersion on immobilized enzyme catalytic bed was investigated in order to examine the kinetic behavior of the biocatalysis. The enzyme employed in this study was the tyrosinase(EC 1.14.18.1) immobilized on carbon support : this system requires two substrates of phenol and oxygen. This enzyme has potential application for phenol degradation in waste water. A simulated reactor was a packed-bed reactor of 2.54cm in diameter and 10cm long, loaded with the immobilized carbon particle with an average diameter of $550{\mu}m$. A phenol feed in the strength of 55.5mM(5220ppm) was used to observe the behavior of the immobilized enzyme column at three different dissolved oxygen levels of 0.08445mM(2.7ppm), 0.1689mM(5.4ppm) and 0.3378mM(9.5ppm) with the flow rates in the range of 60(1mL/s) to 180mL/min(3mL/s). Examination of the Biot number and Damkolher numbers of the immobilized system enables us to eliminate the contribution of external mass transfer to set of differential equations derived from the dispersion model. Solution of the equation was finally obtained numerically with the application of the Danckwert boundary conditions and the assumed zero-and first order rates on the non-linear two substrate enzyme kinetics. Higher conversion of phenol was observed at the low flow rates and at the higher oxygen concentration. Comparison of axial dispersion and plug flow model showed that no detectable difference was observed in the column outlet conversion between the axial and the plug flow models which was in complete agreement with the previous studies.

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Improvement Plan of Fire-Related Laws of Disaster Prevention Facilities of Road Tunnels (도로터널 방재시설의 소방관계법령 개선방안)

  • Seo, Hyo-Seon;Whang, Young-Kwon;Lee, Seung-Chul
    • Fire Science and Engineering
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    • v.33 no.2
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    • pp.124-131
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    • 2019
  • When a fire occurs in a road tunnel, it is likely to develop into a major disaster because of its sealed structural characteristics. Because of this, a range of disaster prevention facilities should be installed, and they should show their appropriate functions in fire prevention and response. In addition, the installation of essential disaster prevention facilities is missing due to the lack of considering an extension of continuous tunnels and soundproof tunnels. For these reasons, it was judged that an amendment to the law would be necessary. Therefore, this paper reviewed the changes in domestic laws related to the disaster prevention facilities of road tunnels, and the results of the study on the parts that need to be revised in the fire-related laws through a comparative analysis between laws are as follows. First, consecutive tunnels should consider the sum of the extensions of the individual tunnels and ensure that the soundproof tunnels are included in the category of tunnels in the law. In this way, the necessary disaster prevention facilities should be installed. Second, it is necessary to secure a legal justification for installing disaster prevention facilities in tunnels. Therefore, it is essential that water mist fire extinguishing system facilities, emergency broadcasting facilities, and leading lights, which are excluded from installation in tunnels, are specified in the Fire-related laws. Third, to specify in the law that air respirators must be provided in the tunnel is necessary from the viewpoint of the field response. Accordingly, it will make a great contribution to the fire-fighting activities and the life-saving efforts by fire-fighters.

Comparison of Sea Surface Temperature from Oceanic Buoys and Satellite Microwave Measurements in the Western Coastal Region of Korean Peninsula (한반도 서해 연안 해역에서의 해양 부이 관측 수온과 위성 마이크로파 관측 해수면온도의 비교)

  • Kim, Hee-Young;Park, Kyung-Ae
    • Journal of the Korean earth science society
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    • v.39 no.6
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    • pp.555-567
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    • 2018
  • In order to identify the characteristics of sea surface temperature (SST) differences between microwave SST from GCOM-W1/AMSR2 and in-situ measurements in the western coast of Korea, a total of 6,457 collocated matchup data were produced using the in-situ temperature measurements from marine buoy stations (Deokjeokdo, Chilbaldo, and Oeyeondo) from July 2012 to December 2017. The accuracy of satellite microwave SSTs was presented by comparing the ocean buoy data of Deokjeokdo, Chilbaldo, and Oeyeondo stations with the AMSR2 SST data more than five years. The SST differences between the microwave SST and the in-situ temperature measurements showed some dependence on environmental factors, such as wind speed and water temperature. The AMSR2 SSTs were tended to be higher than the in-situ temperature measurements during the daytime when the wind speed was low ($<6ms^{-1}$). On the other hand, they showed positive deviation increasingly as the wind speed increased for nighttime. In addition, increasing tendency of SST differences was related to decreasing sensitivity of microwave sensors at low temperatures and data contamination by land. A monthly analysis of the SST difference showed that unlike the previous trend, which was known to be the largest in winter when strong winds were blowing, the SST difference was largest in summer in Deokjeokdo and Chilbaldo buoy stations. This seemed to be induced by differential tidal mixing at the collocated matchup points. This study presented problems and limitations of the use of microwave SSTs with high contribution to the SST composites in the western coastal region off the Korean peninsula.

Quantifying Climate Change Regulating Service of Forest Ecosystem - Focus on Quantifying Carbon Storage and Sequestration - (산림생태계 기후변화 조절서비스 계량화 방법 - 탄소 저장 및 흡수기능 계량화 방법을 중심으로 -)

  • Choi, Hyun-Ah;Lee, Woo-Kyun;Jeon, Seong Woo;Kim, Joon Sun;Kwak, Hanbin;Kim, Moonil;Kim, Jaeuk;Kim, Jung Teak
    • Journal of Climate Change Research
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    • v.5 no.1
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    • pp.21-36
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    • 2014
  • Forest ecosystem provides variety goods and services for human being. Unlike goods, forest ecosystem services could not be easily priced by market mechanism. This uncertainty has been caused to conflict in decision-making related forest ecosystem services. Quantification of forest ecosystem services is required to understand the importance of ecosystem services and their contribution to decision-making. As a growing concern of climate change, it is necessary to quantify and calculate carbon storage and sequestration in forest. In this study, for quantifying carbon storage and sequestration, we compared scale, output, input data availability of the models and analyzed the applicability of the models to Korea. The results of this study show that most models are applicable for quantifying carbon storage and sequestration. However, relatively few models are applicable for other regulating services (air quality regulation, flood mitigation, erosion control, water quality, etc.) of forest. This study would be helpful for quantifying regulating services of forest ecosystem research.

A Business Model for Offshore Integrated Drilling Commissioning in Korea and Related Economic Analysis (우리나라 해양시추설비 통합시운전 사업 모델의 개발 및 경제성 분석에 관한 연구)

  • Lee, Chang-Woo;Cheon, Young-Wook;Shin, Sang-Hoon;Shin, Yong-John
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.1
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    • pp.102-110
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    • 2019
  • The shipbuilding and offshore plant industry of Korea is important and leads Korea's economic growth, designated as the 1st to 4th export items in Korea in terms of export contribution over the period from 2011 to 2015. This study proposes ways to improve the national competitiveness of Korean shipyards in the global offshore drilling market by reviewing a business model for providing an integrated offshore drilling commissioning service in Korea. This commissioning service model, which was attempted in 2014, was reviewed, and a new proposed business model for overcoming the limitations of the previous model and activating further business was evaluated. As a result of an economic evaluation, it was found that a 150-meter water depth model is economically more effective. As the number of integrated commissions increased from 2 to 5 times per year, NPV, IRR and B/C ratios increased and the fee per use decreased. Therefore, for offshore drilling facilities constructed and delivered in Korea, it will be necessary to encourage integrated offshore commissioning.

Accelerating Effects of Ultrasonic Irradiation on Reaction Rates for the Asymmetric Ring Opening Reaction of Epoxides (초음파 조사에 의한 에폭사이드 비대칭 고리열림 반응의 속도 증진 효과)

  • Lee, Yae Won;Park, Geun Woo;Kim, Geon Joong
    • Applied Chemistry for Engineering
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    • v.30 no.3
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    • pp.365-370
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    • 2019
  • In this study, effects of the ultrasonic irradiation during the reaction process were investigated for the enantioselective kinetic resolution (EKR) reaction of racemic epoxides in the presence of chiral cobalt salen catalysts, as compared to that of using the conventional mechanical stirring. In order to compare catalytic activities, the chiral cobalt salen complexes having $AlCl_3-$, $BF_3-$ and nitrobenzenesulfonic acid (NBSA) were synthesized and used as catalysts, and then three kinds of the racemic epoxides such as ephichlorohydrine (ECH), epoxy phenoxypropane (EPP) and propylene oxide (PO) were used as reactants. In addition, EKR reactions have been performed using the water and methanol as nucleophiles, respectively. The unique contribution of ultrasonic irradiation as a powerful mixing medium was evaluated in this study to improve the kinetics in comparison to the conventional mechanical agitation during EKR reactions. The reaction time to obtain the highest 99 ee% became shorten more than that of above 60%, when the ultrasonic irradiation was used. This result may be interpreted by the cavitation effect of ultrasound in the solution, generating a powerful shear force for the very violent mixing.

Contribution of Two-Stage Mixing Approach on Compressive Strength of Mortar Made of Recycled Fine Aggregate (2단계 배합방법이 순환잔골재 혼입 모르타르의 압축강도에 미치는 영향)

  • Kim, Yu-Jin;Kim, Gyu-Won;Chung, Chul-Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.490-497
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    • 2020
  • This work has been initiated to find possibility whether recycled fine aggregate can be used as a source of aggregate for structural concrete or not. Two-stage mixing approach was chosen in order to maximize strength potential from recycled fine aggregate. Moisture content of the recycled fine aggregate was changed, and two different types of two-stage mixing approaches were applied to produce cement mortar. The strength of mortar made of 100% recycled fine aggregate by two-stage mixing approaches was compared to that of mortar made of 100% washed sea sand. According to the results, the effect of moisture content on compressive strength was observed from low water cement mortar(W/C 0.3). In case of W/C 0.5 cement mortar, no clear relationship was observed between moisture content and strength development. It was found that two-stage mixing approach has a potential to increase the strength of mortar made of 100% recycled fine aggregate. In case of modified version of two-stage mixing approach which first prepares cement paste and pours recycled fine aggregate into the cement paste, was more effective to increase the strength of mortar made of 100% recycled fine aggregate.