• Title/Summary/Keyword: water chemical characteristics

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Hydrogeological Characteristics and Groundwater Table Fluctuation of Dongrae Hot Spring (동래온천의 수리지질학적 특성과 수위변화)

  • Lee, Dong Young;Lim, Jeong Ung
    • Economic and Environmental Geology
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    • v.28 no.2
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    • pp.165-176
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    • 1995
  • Dongrae is one of the most famous hot spring resort area in the Republic of Korea. The water temperature ranges $50^{\circ}C{\sim}66$. The chemical composition of the thermal water is quite different from normal groundwater. $Na^+$ and $Cl^-$ are the main components, measured more than 75%, $Ca^{+{+}}$ is contained about 22% and the other ions such as $SO_4$ or $HCO_3$ are the minor components. The heat source is uprising along the fracture zone of granite which is indicated as a subsurface high temperature belt. During the research period of 1991~1992, the groundwater table was lowered down to the depth of about 100 m according to continuous increase of daily use of thermal water. The groundwater table was fluctuated with an amplitude of day, weak or seasion. The groundwater table was the lowest at 18:00 h in a day and also lowest at the weekend for the week period. There was a relavent relationship between drawdown and the amount of thermal water use on a long term base. To protect such a rapid drawdown of groundwater table, Dongrae resort area is now asked to take strong municipal control for the daily use of thermal water.

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Production and Properties of Ag Metallic Nanoparticle Fluid by Electrical Explosion of Wire in Liquid (유체 내 전기선폭발법에 의한 은 나노입자 유체의 제조 및 특성)

  • Park, E.J.;Bac, L.H.;Kim, J.S.;Kwon, Y.S.;Kim, J.C.;Choi, H.S.;Chung, Y.H.
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.217-222
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    • 2009
  • This paper presents a novel single-step method to prepare the Ag nanometallic particle dispersed fluid (nanofluid) by electrical explosion of wire in liquid, deionized water (DI water). X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) and transmission electron microscope (TEM) were used to investigate the characteristics of the Ag nanofluids. Zeta potential was also used to measure the dispersion properties of the as-prepared Ag nanofluid. Pure Ag phase was detected in the nanofluids using water. FE-SEM analysis shows that the size of the particles formed in DI water was about 88 nm and Zeta potential value was about -43.68 without any physical and chemical treatments. Thermal conductivity of the as-prepared Ag particle dispersed nanofluid shows much higher value than that of pure DI water.

Assessment of Water Pollution and the Ecological Characteristics of the Singu Reservoir

  • Lim, Dohun;Lee, Yoonjin
    • Journal of Environmental Science International
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    • v.27 no.11
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    • pp.1117-1127
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    • 2018
  • This study was carried out to gather basic data for the purpose of proposing a plan to improve the water quality and conserve the aquatic ecosystem of the Singu Agricultural Reservoir in Korea. The water quality, sediment composition, benthic macroinvertebrate distribution, and fish distribution in the Singu Reservoir were analyzed; the reservoir is located close to farmlands, forests, villages, and livestock breeding areas. The results of the water quality analysis are as follows: 5.8~7.8 mg/L for dissolved oxygen, 13.1~20.7 mg/L for chemical oxygen demand, 14.4~18.8 mg/L for suspended solid, 0.96~1.70 mg/L for total nitrogen, 0.07~0.11 mg/L for total phosphorous, and $41.9{\sim}49.8{\mu}g/L$ for $chlorophyll-{\alpha}$. In total, 75 benthic macroinvertebrate specimens belonging to 4 classes, 7 orders, 14 families, and 17 species were recorded. The ecological scores of the benthic macroinvertebrate communities ranged from 11 to 23. Fish specimens recorded belonged to two families and four species. The dominant fish species were Carassius auratus and Pseudorasbora parva, both of which are water-pollutant tolerant species.

Transparent Black Phosphorus Nanosheet Film for Photoelectrochemical Water Oxidation

  • Choi, Chang-Ho
    • Clean Technology
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    • v.27 no.3
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    • pp.217-222
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    • 2021
  • Although monolayer black phosphorus (BP) and few-layer BP nanosheets (NSs) have been extensively studied as promising alternatives to graphene, research has focused primarily on atomically thin-layered BP in an isolated form. In order to realize the practical applications of BP-related devices, a BP film based on continuous networking of few-layer BP NSs should be developed. In this study, a transparent BP film with high quality was fabricated via a vacuum filtration method. An oxygen-free water solvent was used as an exfoliation medium to avoid significant oxidation of the few-layer BP NSs in liquid-phase exfoliation. The exfoliation efficiency from bulk BP to the few-layer BP NSs was estimated at 22%, which is highly efficient for the production of continuous BP film. The characteristics of the high-quality BP film were determined as 98% transparency, minimum oxidation of 18%, structural stability, and an appropriate bandgap of about 1.8 eV as a semiconductor layer. In order to demonstrate the potential of the BP film for photocatalytic activity, we performed photoelectrochemical water oxidation of the transparent BP film. Although its performance should be improved for practical applications, the BP film could function as a photoanode, which offers a new potential semiconductor in water oxidation. We believe that if the BP film is adequately engineered with other catalysts the photocatalytic activity of the BP film will be improved.

Physico-Chemical Characteristics of Water and Distribution of Vascular Hydrophytes in the West Nakdong River, South Korea (서낙동강 수질의 이화학적 특성과 수생관속식물의 분포)

  • 윤해순;김구연;김승환;이원화;이기철
    • The Korean Journal of Ecology
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    • v.25 no.5
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    • pp.305-313
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    • 2002
  • The physico-chemical characteristics of water and sediment, and structures of vegetation of the vascular hydrophytes were investigated in the West Nakdong River. Water quality was eutrophic according to the mean values and the ranges of water properties such as pH, DO, BOD, chlorophyll a, total nitrogen and phosphate, and other nutrients. A few cases were hypereutrophic for chlorophyll a level in summer. Soil reaction was weak acid. Composition of sediment was mainly sand except in SI(Sinan chideung) of which was mainly clay, and SU(Suan chideung) of which was mainly silt. Flora of vascular hydrophyte had 26 species and 1 variety comprising 16 families. Trapa japonica was dominant species in the sites of DU(Dunchido), GA(Garak chideung) and SU. Nymphoides peltata and Hydrocharis dubia dominated in DA and SI, respectively. Species diversity and evenness were relatively high in SI and SU but dominance was high in DA. After June, water lettuce(Pistia stratiotes) and water hyacinth(Eichhornia crassipes) were flowed from tributary to the river. Standing crop of macrohydrophytes was high in DA from April to August, but it showed maximum standing crop (445g·dw/㎡) in DU after disturbance by explosive growth of exotic plants in October. In comparison with those in 1985, total productivities in DU and GA decreased to 33.5%, and the reduction ratio of dominant species, Trapa japonica was 56.7%. Najas marina, N. minor, Myriophyllum spicatum and Nymphoides indica have disappeared ever since the Nakdong barrage was constructed in the Nakdong river. They were divided into three groups (GA-SU-DU, DA, SI) by cluster analysis. Introduction of the exotic species in this river caused decreasing of endemic plants including endangered species Euryale ferox and rare species Hydocharis dubia, and food plants for waterfowl such as Trapa japonica, Vallisneria asiatica and Potamogeton crispus.

Structural and Chemical Characterization of Aquatic Humic Substances in Conventional Water Treatment Processes (재래식 정수처리 공정에서 수질계 휴믹물질의 구조 및 화학적 특성분석)

  • Kim, Hyun-Chul;Yu, Myong-Jin
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.11-16
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    • 2005
  • Humic substances(HS) from raw and process waters at a conventional water treatment plant were isolated and extracted by physicochemical fractionation methods to investigate their characteristics. They are characterized for their functionality, chemical composition, and spectroscopic characteristics using FT-IR(Fourier transform infrared) and $^1H-NMR$(proton nuclear magnetic resonance) spectroscopy. Humic fraction gradually decreased from 47.2% to 26.4%(from 0.97 to 0.54 mgC/L) through conventional water treatment processes. Concentration of phenolic groups in the HS fraction gradually decreased from 60.5% to 21.8%(from 12.2 to $6.0\;{\mu}M/L$ as phenolic-OH) through water treatment. In the case of carboxylic groups, the concentration increased from 39.5% to 46.9%(from 7.9 to $10.6\;{\mu}M/L$ as COOH) by pre-chlorination, but gradually decreased to 34.2%($9.4\;{\mu}M/L$ as COOH) through sedimentation and sand filtration. From the results of the FT-IR and $^1H-NMR$ spectra of HS, the content of carboxylic groups increased and ratio of aliphatic protons to aromatic protons($P_{Al}/P_{Ar}$) also increased through water treatment, which indicated the increase of aliphatic compounds.

Effects of Pig Slurry Application on the Characteristics of Runoff Water in Volcanic Ash Soil in Jeju (제주 화산회토양에서 돈분액비 시용이 유거수의 특성에 미치는 영향)

  • Park, Nam-Geon;Hwang, Kyung-Jun;Park, Hyung-Soo;Song, Sang-Teak;Kim, Moon-Cheol
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.27 no.3
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    • pp.189-196
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    • 2007
  • This study was conducted to determine the effects of application levels of pig slurry on the characteristics of runoff water in volcanic ash soil in Jeju, Korea. This study was arranged in randomized complete block design. The data represent the means of the three experiments. Experimental plots were consisted of five treatments such as no fertilizer, chemical fertilizer at 200kg N/ha/year and pig slurry levels at 200, 400 and 600kg N/ha/year. The concentrations of BOD and COD in 600kg N/ha pig slurry were significantly higher (p<0.05) than those of the other treatments at initial sampling at 12 days after application. The total nitrogen concentration in runoff water increased with increasing pig slurry. The total phosphorous concentration in runoff water was hardly influenced by application levels of pig slurry since there were no significant difference among the treatments. The concentrations of $NO_3-N\;and\;NH_4-N$ were raised (p<0.05) in proportion to application levels of pig slurry. In conclusion, pig slurry usage at 200kg N/ha to the volcanic ash soil in Jeju area can replace the chemical fertilizer. However, more than 200kg N/ha of pig slurry may not be appropriate, because it may contaminate the water environment.

Characteristics of chemical water quality and the empirical model analysis before and after the construction of Baekje Weir (금강수계 백제보 건설 전·후의 화학적 수질특성 및 경험적 모델 분석)

  • Kim, Yu-Jin;Lee, Sang-Jae;An, Kwang-Guk
    • Korean Journal of Environmental Biology
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    • v.37 no.1
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    • pp.48-59
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    • 2019
  • This study analyzed the water quality characteristics and developed empirical models prior to and after the construction of Baekje Weir, in the Geum River watershed between 2004-2017. The comparative evaluation of the surface water chemistry before and after the four major river projects on the weirs indicated that total phosphorus (TP), based on annual data, rapidly decrease after the construction of the weir while the total nitrogen(TN) decreased. Conversely, chlorophyll-a (CHL) concentration, which is a good indicator of primary productivity, increased after the construction of the weir together with an increase in specific conductivity. Simply put, the construction of the weir led to the decrease in concentrations of N and P due to the increased water residence time (WRT), whereas the CHL :TP ratio greatly increased in magnitude. The regression analysis of the empirical model indicated that CHL had no significant relation (r=0.068, p=0.6102, n=58) with TP before the weir construction, but had a relation with TP after the weir construction (r=0.286, p<0.05, n=56). Therefore, such conditions resulted in an increase in primary productivity on a given unit of phosphorus, resulting in frequent algal blooms. In contrast, seasonal suspended solids (SS) and TP increased during the monsoon period, compared to the pre-monsoon, thereby showing positive correlations (r>0.40, p<0.01, n=163) with precipitation. If the government consistently discharges water from the weir, the phosphorus concentration will be increased due to its reversion to a lotic waterbody from a lentic waterbody hereby reducing algal blooms in the future.

Seasonal Variations of Physico-Chemical Characteristics and Phytoplanktonic Pigments in Coastal Sea Water from Ullungdo and Dokdo Islands (울릉도와 독도 근해해역의 이ㆍ화학적 특성과 광합성색소의 계절적 변화)

  • 정지안;조은영;차재훈;김미경;김기태
    • Korean Journal of Environmental Biology
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    • v.18 no.4
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    • pp.425-440
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    • 2000
  • The physico-chemical characteristics and the concentrations of chlorophylls of coastal seawater were investigated to know the seasonal variations of biological oceanographic environments in the Islands of Ullungdo(U) and Dokdo(D). The samplings of sea water according to different depths were performed four seasons (May, June, August and November) in five stations along the coast of Ullungdo Island and 3 times (June, August and November) in three stations around the coast of Dokdo Island. The seasonal variations of sea water temperature showed that the formation of thermocline in August was distinct in comparison to the other seasons. The sea water in the surface was influenced by low temperature-high salinity in May and with high temperature-low salinity in the investigated area. The amount of seston was high in May (5.3-15.0mg/l) and was low in August (1.4-4.9mg/l) in ullungdo island. for the nutrients or sea water in Ullungdo Island, the concentrations of nitrate and ammonium were higher than Dokdo Island (nitrate-max. of U in August : 0.10-11.50$\mu\textrm{g}$/1, max. of D in August : 2.92-8.10$\mu\textrm{g}$/l : ammonium-max. of U in November : 14.18-20.69$\mu\textrm{g}$/l, max. of D in June : 0-1.78 $\mu\textrm{g}$/l). The high concen-tration of chlorophylls showed on the deeper layer from 30 m to 50 m in August (U 30 m : 0.85$\mu\textrm{g}$/l ; D 50m : 1.02 $\mu\textrm{g}$/l), while the concentrations of chlorophylls were even in May, June and November in the deeper layer of surface layer. In conclusion, the establishment of thermocline in deeper area of the euphotic layer in August was a trigger far the development of phytoplankton, while the complex physico-chemical system by diverse currents and vertical mixing of sea water in the area induced the even distribution of phytoplankton in both epilimnion and hypolimnion in May, June and November.

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Characterization of Water Hyacinth (Eichhornia crassipes) Biomass and Evaluation of Applicability as an Organic Filler to Papermaking (부레옥잠 바이오매스의 특성분석과 제지적용성 평가)

  • Kim, Dong Sung;Heo, Yoon Sung;Sung, Yong Joo;Han, Seung-Won;Seo, Cheol Mo
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.5
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    • pp.79-87
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    • 2014
  • The enrichment with nutrients in rivers and lakes becomes serious problems in Korea. As the environmental friendly solution, the phytoremediation are getting more attention and the water hyacinth could be a strong candidate plant for this. Water hyacinth is a free floating freshwater plant proven to be a effective plant used for a purification of a polluted lakes, sewage wastewater, and livestock wastewater. The biggest obstacles for application of water hyacinth in Korea could be the disposal of the water hyacinth before winter, because there is no feasible use for the water hyacinth until now. In this study, the characteristics of water hyacinth were deeply investigated for providing background data to develop appropriate application of the water hyacinth. The water hyacinth was fractioned three parts, leaf, air blader, root of which morphological properties were evaluated with microscope and field emission scanning electron microscope (FE-SEM). The water contents of each parts of the water hyacinth were 87% for leaf, 96.5% for air bladder, 94.6% for root. The chemical compositions of each parts were also measured and showed around 29% of hot water extract in leaf and air bladder, 42% holocellulose for leaf, 47% holocellulose for air bladder. The application of water hyacinth biomass without root parts to papermaking provided bulkier structure, but the tensile strength was decreased.