• Title/Summary/Keyword: water chemical characteristics

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The Recent Tendency of Environmentally-friendly Tackifiers

  • Sakurai, Yoshihiro
    • Journal of Adhesion and Interface
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    • v.8 no.1
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    • pp.28-33
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    • 2007
  • It is a main trend not to use organic solvents in the adhesive industry from the recent environmental and safe points of view. For example, water-based, hot-melt, or UV curable adhesives are being investigated. Several different kinds of tackifiers that are formulated in the adhesives in order to give them more functional properties like initial tack and higher adhesion, etc., have been proposed to meet the recent trend. Firstly, the characteristics and fundamental properties of the respective materials are presented. In Japan, the trend to develop the water-based adhesives is most remarkable. While the environmental regulations are getting harder, Arakawa Chemical has been spending a lot of energy for the research, and developed toluene-free and solvent free tackifier dispersions that are presented precisely.

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An Experimental Study on the Compressive Strength for the Cement Mortar Contained Phosphogypsum and Kaolin as a Binder (인산부산석고와 카올린을 활용한 시멘트용 결합재의 콘크리트 모르터 압축강도 평가에 대한 실험적 연구)

  • Oh, Hong-Seob;Park, Jong-Tak;Lee, Ju-Won;Nam, Ki-Wook
    • Proceedings of the Korea Concrete Institute Conference
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    • 2010.05a
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    • pp.263-264
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    • 2010
  • In this study, respectively and furnaced kaolin at $900^{\circ}C$ was also manufactured into meta kaolin by air cooling and water cooling method. The chemical characteristic and mechanical properties of various type of blended cements contained above mentioned gypsum and meta kaolin materials analyzed and compared with those characteristics of cement matrix with silica fume. From the test, the cement mixed meta kaolin made in water cooling has more excellent quality than other material.

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A Study on Analysis of the Hydrogen-Oxygen Gas Generator (수산화가스 발생기의 모델링 및 특성해석)

  • Kang, B.H.;Lee, J.M.;Mok, H.S.;Choe, G.H.
    • Proceedings of the KIEE Conference
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    • 2001.04a
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    • pp.198-201
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    • 2001
  • The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electrical for the high efficiency of water electrolysis equipment. First, chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated. For basic experiment, unit electrode of singular electrolysis electrode is manufactured and experimented, results are compared and analyzed with simulation, and the electrolysis is electrically equivalent.

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Review of Management Methods and Criteria for Environmentally-Sound Soil (친환경 토양 관리 방법과 기준에 대한 평가)

  • Ryu, Jin-Hee;Lee, Kyo-S.;Chung, Doug-Y.
    • Korean Journal of Agricultural Science
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    • v.35 no.1
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    • pp.53-67
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    • 2008
  • The principle goal of environmentally-friendly agriculture is to maintain and conserve water and agriculture environment including drinking water resources by properly using agricultural materials such as agricultural chemicals, chemical fertilizers, and other agricultural materials according to act 19 of foster law of environmentally-friendly agriculture. To achieve these goals, we have to establish Integrated Nutrient Management(INM) and Integrated Pesticide Management(IPM) which are most important core technologies for environmentally-friendly rice cultivation. However, there are lack of criteria and technology for evaluation category according to soil management and its soil classes to practice an environmentally-friendly agriculture. Therefore, we should eatablish the standards to produce the safe agricultural products based on the soil physical and chemical characteristics which are basic properties of soil to accomplish the principle aims of environmentally-friendly agriculture.

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Characteristics of Sludge Bulking Caused by Low Dissolved Oxygen in Aeration Tank for Paper Mill Wastewater Treatment (포기조의 낮은 용존산소로 인한 제지폐수의 슬러지 팽화특성)

  • Kwak, Dong-Heui;Yoo, Seung-Joon;Park, Jong-Chun
    • Journal of Korean Society on Water Environment
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    • v.24 no.4
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    • pp.458-464
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    • 2008
  • Bulking phenomena and scum formation are common problem in suspended growth system like the activated sludge plants for wastewater treatment. Apart from wastewater composition, operating conditions, such as mechanical stress by insufficient oxygen supply, are often decisive for the occurrence of a bulking or scumming problem. There were the comparative aeration tanks in terms of sludge bulking caused by the difference of mechanical aeration facilities in the wastewater treatment plant of N paper mill company. In this study the cause of bulking was investigated through not only the biological isolation and identification but also a series of operational data consideration. On the basis of the investigation results for bulking cause, the operational criteria on dissolved oxygen concentration was derived to decrease the bulking problem.

Studies on the Characteristics of Humic Acid and its Utilizations. (Ⅲ) Utilizations of Humic Acid (Nitrohumates) (土炭흄酸의 性狀및 應用에 關한 硏究 흄酸(니트로흄酸鹽)의 應用 (第3報))

  • Won Taik Kim
    • Journal of the Korean Chemical Society
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    • v.13 no.1
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    • pp.62-67
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    • 1969
  • The adaptabilities of various nitrohumates (-K, -Na and $-NH_4$ salt) as a soil conditioner and a raw material for soluble phosphatic fertilizer were studied. 1. Nitrohumates (especially $-NH_4$ salt) protect the soil from fissures and control the phosphoric acid adsorptive functions of soils considerably. 2. Most effective nitrohumic acids as a soil conditioner were prepared with 15% $HNO_3$ solution composed of five times of original humic acids (by weight) at $80^{\circ}C$ for 2 hrs under continuous stirring. 3. When 50% (by weight) of $NH_4$-nitrohumate were added to apatites in water and boiled for 2 hrs, maximum 26% of $P_2O_5$(apatite contains 37% of $P_2O_5$) were changed into water soluble forms.

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Characterization of Black Carbon Collected from Candle Light and Automobile Exhaust Pipe

  • Cho, Seo-Rin;Cho, Han-Gook
    • Journal of the Korean Chemical Society
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    • v.57 no.6
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    • pp.691-696
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    • 2013
  • Black carbon contributes to global warming and melting of polar ice as well as causing respiratory diseases. However, it is also an inexpensive, easily available carbon nano material for elementary chemistry experiments. In this study, black carbon samples collected from candle light and automobile exhaust pipes have been investigated to examine their compositions and surface characteristics. The observed broad G and D bands and amorphous $sp^3$ band in their Raman spectra as well as the high intensity of the D (defect) band reveal that black carbon is principally made of amorphous graphite. The black carbon deposits in automobile exhaust pipes are apparently more amorphous, probably due to the shorter time allowed for formation of the carbonaceous matter. An exceptionally large water contact angle ($159.7^{\circ}$) is observed on black carbon, confirming its superhydrophobicity. The surface roughness evidently plays an important role for the contact angle much larger than that of crystalline graphite ($98.3^{\circ}$). According to the Sassie-Baxter equation, less than 1% the area actually in contact with the water drop.

Adsorption and Molecular Sieve Properties on the Natural Zeolite with Chemical Surface treatment (화학적 표면처리에 의한 천연 제올라이트의 흡착 및 분자체 특성)

  • 조승래;심미자;김상욱
    • Journal of the Korean institute of surface engineering
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    • v.25 no.3
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    • pp.144-149
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    • 1992
  • The adsorption and molecular sieve characteristics of water, methanol, ethanol, butanol and benzene on acid-alkali treated natural zeolite from Kampo area were investigated by the Diamond·Kinter method, and it was compared with synthetic zeolite A. Adsorption amount of water increased with the treatment of acid rather than the treatment of alkali. Similar tendency was observedd in adsorption of alcohols such as methanol, ethanol and butanol, but the amount of adsorption decreased. From the views of the molecular size, adsorption amount of benzene decreased because of surface activity according to the cations species rather than chemical treatment. And it was almost same value that the amount of adsorption was compared acid treated natural zeolite with synthetic zeolite A.

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Spectral and Photophysical Behaviors of Curcumin and Curcuminoids

  • Bong, Pil Hun
    • Bulletin of the Korean Chemical Society
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    • v.21 no.1
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    • pp.81-86
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    • 2000
  • In order to obtain detailed information on ground and excited states of curcumin and curcuminoids, as well as to understand the photobiological characteristics of them, their spectral and photophysical behaviors are investigated in various conditions. Various curcuminoids were obtained and their structures were determined by spectroscopic methods. In n-hexane, the absorption and fluorescence spectra of these compounds contain some structure, which disappear in more polar solvent such as methanol. The fluorescence intensities of curcumin and dimethylated curcumin decrease as the concentration of water increases. The intensities also decrease as the solvent varies from neutral to extremely acidic (lower than pH 1.5) or to basic (higher than pH 8.0) condition. These results indicate that the spectral and photophysical properties of both of curcumin and curcuminoids are strongly influenced by solvent, water, and pH.

The Importance of Thermodynamic Quantities for the Determination of the Unknown Conformation: Ab initio Studies of$ K^+(H_2O)_3$

  • 이한명;Son, Hyeon S.;민병진
    • Bulletin of the Korean Chemical Society
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    • v.20 no.3
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    • pp.345-351
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    • 1999
  • The structures, the energetics, and the spectra of K+(H2O)3 have been studied at HF and MP2 levels with the basis set of triple-zeta plus two sets of polarization functions (TZ2P) for water molecules. Two structures considered are 3+0 (D3), and 2+1 (C2v). The 2+1 (C2v) has two hydrogen bonds between the primary hydration and the secondary hydration shell water molecules. They have similar binding energy and enthalpy. The most stable conformation of K+(H2O)3 is entropy driven as shown in Na+(H2O)5 and in Na+(H2O)6 cases. The 3+0 (D3) conformation is the most stable at 298 K and at 1 atm, based on Gibbs free energy changes (ΔGr). The thermal contributions to the enthalpy and the Gibbs free energy are corrected for the low frequency modes. The corrected ΔGr is in good agreement with the experimental value. Vibrational frequencies of two conformations are revealed as their characteristics.