• 제목/요약/키워드: water chemical characteristics

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하천 생물서식처의 물리.화학적 특성에 관한 연구 (A study on the Physical and Chemical Characteristics of Fluvial Habitat)

  • 안태웅;최이송;오종민
    • 한국수자원학회:학술대회논문집
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    • 한국수자원학회 2009년도 학술발표회 초록집
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    • pp.437-441
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    • 2009
  • 1990년대 이후 하천환경에 대한 관심은 치수적 과점에서 이수적 관점, 환경적 관점으로 확대되어 가고 있으며, 이에 부응하여 하천환경을 개선하기 위한 노력이 1990년대 말부터 자연형 하천개발이라는 이름으로 확산되어 우리나라의 하천환경을 크게 변모시켜 나가고 있다. 실제로 자연형 하천은 우리 주변의 하천경관 및 수질을 많이 개선하는 효과를 거두어 왔으나, 하천의 보전 및 복원에 대한 구체적인 기술개발이 없는 상태에서 경쟁적으로 시행되어 비효율성, 비생태성, 비안전성의 문제를 노출시키고 있다. 특히 하천의 다양한 물리적 인자와 복합되어 형성되는 하도서식처 환경들에 대한 이해의 부족은 하천에 서식하는 다양한 생태계의 순환과정 및 연계성을 단절시키고 근본적인 하천환경복원을 어렵게 한다. 최근에 하천환경 복원사업의 근본 목표는 그 하천 고유의 하천경관이나 생태계 등의 특성을 회복(Rehabilitation)시키거나 복원(Restoration)시키는 것으로, 평여울, 급여울, 폐쇄형 하도습지, 웅덩이 등과 같은 하도서식처로서의 물리적 자연환경을 인위적으로 조성하여 원활한 생태환경이 자생될 수 있도록 하기 위한 노력의 일환이다. 그러나 하천 생태계는 물리적 환경에 의해서만 지배되는 것은 아니며, 하천생태계가 원활하게 조성되기 위해서는 그에 따른 적정한 수질이 유지되는 것 또한 중요하다. 물론 자연생태계의 순환과정이 원활해진다면, 하천의 자정능력 향상을 가져오게 되고 그로 인하여 수질도 생태환경에 적합하게 유지되는 것은 자연스러운 이치이다. 결국 자연적으로 조성된 하천에서의 물리적 서식처 환경이 수질에 어떠한 영향을 미치는지 파악하는 것은 앞으로 하천환경 복원사업에 있어서 매우 중요한 요소 중의 하나이다. 따라서 본 연구에서는 물리적 환경인 하도서식처 환경을 조사하고 그에 따른 화학적 특성을 평가해 보았다. 본 연구의 결과는 앞으로 하천복원에 있어서 물리적 서식처 조성과 수질의 상호 연계성 및 복원기술의 타당성을 평가하는데 중요한 지표가 될 수 있을 것으로 판단된다.

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재첩의 지질에 관한 연구 (Lipids of Fresh-Water Cockle, Corbicula elatior)

  • 조용계;박수진;안철우
    • 한국수산과학회지
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    • 제15권1호
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    • pp.94-98
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    • 1982
  • 낙동강 하류산 재첩 (Corbicula elatior)에 함유되어 있는 지질의 이화학적 성질, 조성 그리고 이 지질의 지방산과 sterol 조성을 밝히기 위하여 실험한 결과는 다음과 같다. (1) 조지질과 불연화물 함양은 각각 $2.17\%,\;16.6\%$였으며 요-드가는 119였다. (2) 조지질의 조성은 린지질이 약 $43\%$로 가장 많았고 triglyceride (약$40\%$), 유리 sterol ($11\%$)의 순이었다. (3) 지방기조성은 $C_{16:0}$$48.4\%$로 가장 많았고, C_{14:0}\;(10.0\%, C_{14:1}\;5.4\%,\;C_18:1 (5.3\%)의 순이였으며 $C_{19:0}$으로 생각되는 지방산이 $6.4\%$였다. (4) 6종의 sterol 이 검출되었는데 24-nlethylene-cholesterol이 $41\%$로 가장 많았고 $\beta-sitosterol(22.5\%)$, fucosterol이 $14.9\%$였으며 isofucosterol과 과 $\Delta^7-avenasterol (?)(5.2\%)$로 생각되는 것이 각각 $14.0\%$, $5.2\%$ 였고 cholesterol은 $2.3\%$로 가장 적었다.

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하수종말처리장 방류수를 논 관개용수로 처리시 벼 생육 및 토양환경 영향 조사 - 라이시미터 재배실험 - (Rice Growth Response and Soil Quality by Domestic Wastewater Irrigation on Rice Paddy Field - Lysimeter experiment -)

  • 조재영;박승우;손재권;박봉주;이용근
    • 농촌계획
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    • 제12권2호
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    • pp.49-56
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    • 2006
  • The application of domestic wastewater on rice paddies results in the accumulation of sodium(Na$^+$) to the soil. Excessive concentration of sodium may cause the deterioration of the physical characteristics of the soil, change in the osmosis of the soil, destruction of soil aggregates as well as ion toxicity due to sodium accumulation. Using domestic wastewater as irrigation water should be preceded by measures to prevent or control the soil salinization caused by sodium. Agricultural reuse of domestic wastewater were found not to cause serious problems with food safety due to heavy metals. However, pre-treatment using ultraviolet or ozone is recommended to reduce the number of bacteria and gem and for public health reasons. Using domestic wastewater has shown that reducing the standard application of chemical fertilizers by as much as 50% reduced the harvesting index by only 10%. This study has shown that it is feasible to reuse domestic wastewater on rice paddies. In order to facilitate the application, it is deemed necessary to establish wastewater treatment technologies in the future, to review criteria for recycling domestic wastewater for agricultural purposes such as conditions of soil and cropping system and to resolve conflicts with farmers and public health issues.

용매증발법에 의한 부피바카인 microsphere의 제조 및 평가 (Preparation and Evaluation of Bupivacaine Microspheres by a Solvent Evaporation Method)

  • 곽손혁;황성주;이병철
    • 약학회지
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    • 제44권6호
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    • pp.511-520
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    • 2000
  • Various bupivacaine-loaded microspheres were prepared from poly (d,l-lactide) (PLA) or poly (d,l-lactic-co-glycolide) (PLGA) by a solvent evaporation method for the sustained release of drug. PLA and PLGA microspheres were prepared by w/o/w and w/o/o multiple emulsion solvent evaporation, respectively. The effects of process conditions such as emulsification speed, emulsifier type, emulsifier concentration and internal/external phase ratio on the characteristics of microspheres were investigated. The prepared microspheres were characterized for their drug loading, size distribution, surface morphology and release kinetics. Drug loading efficiency was higher in the microspheres prepared by w/o/o multiple emulsion than that by w/o/w multiple emulsion method, because the solubility of bupivacaine HCI was decreased in oil phase compared with water phase. The prepared microspheres had an average diameter between 1 and $2\;{\mu}M$ in all conditions of two methods. In morphology studies the PLA microspheres showed an irregular shape and smooth surface, but PLGA microspheres had a spherical shape and smooth surface. The release pattern of the drug from microspheres was evaluated on the basis of the burst effect and the extent of the release after 24h. The in vitro release of bupivacaine HCl from microspheres showed a large initial burst release and $60{\sim}80%$ release within one day in all conditions of two methods. The extents of the burst release against PLA and PLGA microspheres were $30{\sim}50%$ and $50{\sim}80%$ within 20min, respectively. This burst release seems to be due to the smaller size of microspheres and the solubility of drug in water.

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방사성 폐기물 저장을 위한 불연속 암반의 특성 및 고온하에서의 암반의 수리열역학적 상호작용에 관한 연구 (A Study on Characteristics of Jointed Rock Masses and Thermo-hydro-mechanical Behavior of Rock Mass under High Temperature)

  • 이희근;김영근;이희석
    • 터널과지하공간
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    • 제8권3호
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    • pp.184-193
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    • 1998
  • 방사성 폐기물의 안전한 처분을 위해서는 암반의 역학적, 열적, 유체 거동 뿐 아니라 암반과 물 사이의 물리 화학적 상호작용을 이해할 필요가 있다. 또한 지질구조, 지하현지응력, 습곡, 열수작용, 마그마의 관입, 판구조 등과 같은 많은 조건을 모델링하고 예측하기 위해서는 암석의 역학적, 수리적 특성을 알아야 한다. 이 연구는 심부 암반에 폐기물 처분과 관련된 암석역학적인 사항들에 대해 연구들에 기초하고 있다. 이 논문은 변하는 온도 상태에서 암반의 역학적 수리적 거동, 암반의 열-수리-역학적 상호작용 해석과 불연속 암석의 거동 특성 등을 포함한다. 역학적 특성은 Interaken 암석역학 시험 시스템으로 측정되었으며, 수리적 특성에는 순간 증압 투수계수 측정 시스템이 사용되었다. 모든 결과에서 암석 특성은 온도 변화에 민감함을 보였다.

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하수고도처리에서 층상이중수화물을 이용한 인산 이온교환 특성 (Characteristics of Ion Exchange of Phosphate using Layered Double Hydroxides in Advanced Wastewater Treatment)

  • 송지현;신승규;이상협;박기영
    • 한국물환경학회지
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    • 제22권6호
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    • pp.991-995
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    • 2006
  • The layered double hydroxide with the insertion of chloride ions (LDH-Cl), which was synthesized by the co-precipitation method, was applied to investigate the fundamental aspects of the absorptive agent for phosphate removal from wastewater. The adsorption capacity was best described by the Langmuir-FreundIich isotherm, and the estimated isotherm parameters indicate that the LDH-CI capacity for the phosphate removal is much higher than that observed using a natural adsorbent material such iron oxide tailing. The kinetic experiment also showed that the LDH-Cl adsorption reaction rapidly at the adsorptive rate of 0.55 mg-P/g-LDH/min, implying that this adsorbent can be of use in the full-scale applications. The pH had a minimal effect on the LDH adsorption capacity in the range of 5 to 11, although the capacity dropped at the low pHs because of the change in LDH surface properties. Furthermore, other anions such as $Cl^-$ and $NO_3{^-}$ commonly found in the wastewater streams insignificantly affected the phosphate removal efficiencies, while $HCO_3{^-}$ ions had a negative effect on the LDH adsorption capacity due to its high selectivity. The phosphate removal experiment using the actual secondary effluent from a wastewater treatment plant showed the similar decrease in adsorption capacity, indicating that the bicarbonate ions in the wastewater were competing with phosphate for the adsorptive site in the surface of the LDH-Cl. Overall, the synthetic adsorbent material, LDH-Cl, can be a feasible alternative over other conventional chemical agents, since the LDH-Cl exhibits the high phosphate removal capacity with the low sensitivity to other environmental conditions.

천연 다당류 먼지포집제를 이용한 지하철 터널 내 PM10 제어에 대한 연구 (A Study on PM10 Control in Subway Tunnels Using Natural Polysaccharide Dust Collecting Agent)

  • 이한섭;황수진;황현석
    • 한국환경보건학회지
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    • 제43권2호
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    • pp.122-129
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    • 2017
  • Objectives: Most of the $PM_{10}$ in subway stations is spread by the train-induced wind from the tunnels. Therefore, in order to improve air quality in subway stations, it is important to remove the $PM_{10}$ from the tunnels. After the installation of PSD (platform screen doors), the influence of train-induced wind and $PM_{10}$ at the platform has decreased, but is estimated to have increased in subway tunnels. This study was conducted to investigate the control of $PM_{10}$ in subway tunnels by applying a 500-fold diluted solution mixed with a humectant using a natural polymer. Methods: For this purpose, we tested the dust reduction effect in a laboratory and corrosion test and water pollution using fish and aquatic plants for the natural dust collecting agent. In the tunnel of a subway station, we used the natural dust collecting agent over 15 days. The study was carried out on $PM_{10}$ control during operation, which accounts for more than 70% of subway dust. Results: As results, the natural dust collecting agent exhibited an excellent dust control effect, and it was safe for water quality and soil. It showed the effect of controlling $PM_{10}$ in the subway tunnel by 49.5- 64.7% over 15 days. The use of the dust collecting agent for the control of $PM_{10}$ could be confirmed in the subway. Conclusion: It is necessary to clearly explain the major portions of chemical components contained in $PM_{10}$ to figure out the characteristics of $PM_{10}$ and to develop effective reduction measures to decrease the adverse effects of $PM_{10}$ in the subway.

낙동강 상류 수계인 내성천의 부착돌말 군집과 부착돌말지수를 이용한 생물학적 수질평가 (The Epilithic Diatom Community and Biological Water Quality Assessment of Naeseongcheon Located at the Upper Region of Nakdong River)

  • 최재신;이재학;김한순
    • 생태와환경
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    • 제50권4호
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    • pp.470-477
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    • 2017
  • 본 연구는 낙동강 상류에 위치한 내성천과 지류들을 대상으로 총 15개의 지점에서 2016년 5월, 8월 및 10월의 총 3회에 걸쳐 이화학적 환경요인들과 부착돌말 군집의 특성을 분석하고, 생물학적 방법인 DAIpo와 TDI를 이용하여 수질을 평가하였다. 내성천 수계에서 출현한 부착돌말류는 2목 3아목 9과 35속 145종 16변종 2품종으로 구성된 총 163종이 출현하였다. Cocconeis placentula var. lineata는 모든 지점에서 출현하였으며, Achnanthes lanceolata, Nitzschia fonticola, Nitzschia inconspicua와 Reimeria sinuate는 내성천의 보편적인 분류군들로 조사되었다. Nitzschia inconspicua와 Achnanthes minutissima가 주요 우점종으로 출현하였다. CCA 분석 결과, 부착돌말 종조성은 전기전도도와 총질소에 가장 많이 영향을 받는 것으로 나타났다. DAIpo를 이용한 생물학적 수질평가 결과, 내성천의 DAIpo는 평균 62.38로 B등급이나, TDI로 평가한 결과, 내성천의 TDI는 평균 66.12로 C등급으로 나타났다.

UV/TiO2 광촉매반응에 의한 페놀의 분해 특성 (Characteristics of Phenol Degradation by using UV/TiO2 Photocatalysis)

  • 신인수;최봉종;이승목
    • 한국물환경학회지
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    • 제20권5호
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    • pp.488-493
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    • 2004
  • The effects were examined from several conditions of $TiO_2$ photocatalysis reaction to phenols degradation by changing it's reacting conditions such as phenol concentration, pH, $TiO_2$ concentration, $H_2O_2$ concentration, flow rate, and intensity of ultraviolet rays. Phenol degradation was more efficient in low concentration of phenol, neutral pH. Phenol degradation appeared to increase as concentration of $TiO_2$ photocatalyst, that of $H_2O_2$ and intensity of ultraviolet rays increased. As $TiO_2$ dosage increased, initial rate constant k linearly increased. When $H_2O_2$ was injected more than optimum, phenol removal rate didn't increase in proportional to the change of $H_2O_2$ concentration as OH radicals was being consumed. When flow rate is less than $4.75m^3/m^2$ day, phenol removal efficiency appeared to decrease as ultraviolet rays transmission rate becomes low by $TiO_2$ suspension coated in photo reaction column. Meanwhile, initial rate constant according to light intensity change in less than $25mW/cm^2$ appeared to be in proportion to light intensity ($mW/cm^2$) Removal efficiency decreased about 12% after 180 minutes of reaction time while showed stable removal efficiency of 100% after 300 minutes when using regenerated $TiO_2$.

충전재 종류에 따른 포장용 포러스 폴리머 콘크리트의 강도 및 투수 특성 (Strengths and Permeability Properties of Porous Polymer Concrete for Pavement with Different Fillers)

  • 김영익;성찬용
    • 한국농공학회논문집
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    • 제49권4호
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    • pp.51-59
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    • 2007
  • Recently, concrete has been made porous and used for sound absorption, water permeation, vegetation and water purification according to void characteristics. Many studies are carried out on the utilization of sewage sludge, fly ash and waste concrete to reduce the environmental load. This study was performed to evaluate the void, strength, relationship between void and strength, permeability and chemical resistance properties of porous polymer concrete for pavement with different fillers. An unsaturated polyester resin was used as a binder, crushed stone and natural sand were used as an aggregate and bottom ash, fly ash and blast furnace slag were used as fillers. The mix proportions were determined to satisfy the requirement for the permeability coefficient, $1{\times}10^{-2}$ cm/s for general permeable cement concrete pavement in Korea. The void ratios of porous polymer concrete with fillers were in the range of $18{\sim}23%$. The compressive strength and flexural load of porous polymer concrete with fillers were in the range of $19{\sim}22$ MPa and $18{\sim}24$ KN, respectively. The permeability coefficients of porous polymer concrete with fillers were in the range of $5.5{\times}10^{-1}{\sim}9.7{\times}10^{-2}$ cm/s. At the sulfuric acid resistance, the weight reduction ratios of porous polymer concrete immersed during 8-week in 5% $H_{2}SO_{4}$ were in the range of $1.08{\sim}3.56%$.