• Title/Summary/Keyword: water chemical characteristics

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Evaluation of Disinfection Characteristics for Mixed Oxidants Produced by Electro-chemical Method (전기분해 방식에 의한 혼합산화제 소독 특성 평가)

  • Lee, Kyung-Hyuk;Lim, Jae-Lim;Lee, Doo-Jin;Kim, Seong-Su;Ahn, Hyo-Won
    • Journal of Korean Society of Water and Wastewater
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    • v.19 no.5
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    • pp.625-631
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    • 2005
  • Disinfection characteristics of mixed oxidants produced by mean of electro-chemical method were evaluated. Inactivation rate of B. subtilis spore on the mixed oxidants were similar with that of chlorine. Based on the experimental results, activation energy of mixed oxidants and chlorine with B. subtilis spore at pH 8.3 were calculated as 30.8, $34.7kJ{\cdot}mol^{-1}$ respectively. UV absorption spectrum of both chlorine and mixed oxidants present similar. Molar extinction coefficients of chlorine and mixed oxidants at 292nm, which is maximum absorption wavelength of $OCl^-$ were 357, $377M^{-1}cm^{-1}$, respectively. Disinfectant decay rate and formation rate of THM in the S WTP filtrate also shows insignificant difference for both mixed oxidants and chlorine. In consequent, it was confirmed that high portion of chlorine presents in the mixed oxidants.

A Study on Characteristics of Coated Films on Wood Surface by Nitrocellulose Lacquer, Aminoalkyd, Polyester, and Polyurethan (니트로셀룰로오스락카, 아미노알키드, 폴리에스테르 및 폴리우레탄 도료(塗料)의 도막성능(塗膜性能)에 관(關)한 고찰(考察))

  • Lee, Phil-Woo;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.17 no.1
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    • pp.12-21
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    • 1989
  • This experiment was executed to investigate the characteristics of gloss and color difference in coated films by N.C. Lacquer, Aminoalkyd, Polyester. and Polyurethan coating after chemical (distilled water, ethyl alcohol. acetic acid, and sodium hydroxide) and heating ($120^{\circ}C$) treatments, cold-check test, and U.V. radiation. The results obtained were summarized as follows 1. The gloss decreasing rate by water resistance test was the least among chemicals treated on coated films. 2. The color difference of coated films chemical treatments highly and similarly increased, except the alkali treatment showing a little increase. 3. In the color difference by U.V. radiation, the polyester coated film showed generally large difference compared with the other coated films.

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Characteristics of Polyaniline Anti-Corrosive Coatings with Primer and Top Coating Resins (하도 및 상도 수지에 따른 폴리아닐린 방청도료의 특성)

  • Kim, Tae-Ok;Kong, Seung-Dae;Park, Jin-U
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.4
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    • pp.399-409
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    • 2007
  • Characteristics of polyaniline anti-corrosive coatings with various primer coating resins(epoxy resin, urethane resin, and others) and top coating resins(epoxy and acrylic urethane resins) were investigated through adhesion, acid resistance, alkaline resistance, water resistance, and anti-corrosion tests. As a result, the anti-corrosive properties of the prepared coatings using polyaniline varied with the types of primer and top coating resins. In this condition, the properties of adhesion, chemical resistance, and water resistance were found to be very satisfactory when using emeraldine base (EB) of polyaniline blended with single-packaged urethane and acrylic urethane resins as the primer coatings, and using acrylic urethane resin as the top coatings. Also, the anti-corrosive function of these anti-corrosive coatings was well preserved for 1000 hr in the salt spray experiment.

Studies on the Characteristics of Humic Acid and its Utilizations (I) (土炭 흄酸의 性狀 및 應用에 關한 硏究 (I) 흄酸의 溶出 및 그 條件에 따른 흄酸性狀의 變異)

  • Kim, Won-Taik
    • Journal of the Korean Chemical Society
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    • v.12 no.4
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    • pp.155-159
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    • 1968
  • On the extraction of humic acid from peat, the optimum conditions were studied and the effects of them on the characteristics of humic acid were also examined by means of infrared spectroscopy. 1. Pretreatment of peat with diluted 6-8% HCl solution for 5 hrs. prior to extraction with alcohol-benzol azeotropic mixture have resulted the better yield of humic acid. The water soluble Na-humates were obtained by the subsequent extraction with one hundred times quantity of caustic soda solutieon for 1hr. at 90 $^{\circ}C$. Thus the pure humic acids have been yielded approximately 40% (by wt.) from the raw peat. 2. In characteristics of humic acid, the chemical structure, mainly the contents of such functional groups as -COOH, -OH (phenol type), $-CH_2CO-$, $-CH_2{\cdot}O{\cdot}CH_2-$ and aromatic rings were varied according to the concentration of alkaline solution, temperature and time when the humic acids were extracted with alkali.

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A Sensitivity Analysis on Numerical Grid Size of a Three-Dimensional Hydrodynamic and Water Quality Model (EFDC) for the Saemangeum Reservoir (새만금호 3차원 수리.수질모델(EFDC)의 수치격자 민감도 분석)

  • Jeon, Ji Hye;Chung, Se Woong
    • Journal of Korean Society on Water Environment
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    • v.28 no.1
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    • pp.26-37
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    • 2012
  • Multi-dimensional hydrodynamic and water quality models are widely used to simulate the physical and biogeochemical processes in the surface water systems such as reservoirs and estuaries. Most of the models have adopted the Eulerian grid modeling framework, mainly because it can reasonably simulate physical dynamics and chemical species concentrations throughout the entire model domain. Determining the optimum grid cell size is important when using the Eulerian grid-based three-dimensional water quality models because the characteristics of species are assumed uniform in each of the grid cells and chemical species are represented by concentration (mass per volume). The objective of this study was to examine the effect of grid-size of a three dimensional hydrodynamic and water quality model (EFDC) on hydrodynamics and mass transport in the Saemangeum Reservoir. Three grid resolutions, respectively representing coarse (CG), medium (MG), and fine (FG) grid cell sizes, were used for a sensitivity analysis. The simulation results of numerical tracer showed that the grid resolution affects on the flow path, mass transport, and mixing zone of upstream inflow, and results in a bias of temporal and spatial distribution of the tracer. With the CG, in particular, the model overestimates diffusion in the mixing zone, and fails to identify the gradient of concentrations between the inflow and the ambient water.

Comparative Analysis on Resources Characteristics of Deep Ocean Water and Brine Groundwater (해양심층수와 지하염수 자원의 특성)

  • Moon D.S.;Jung D.H.;Kim H.J.;Shin P.K.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.7 no.1
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    • pp.42-46
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    • 2004
  • Deep Ocean Water (DOW) is formed within restricted area including polar sea (high latitude) by cooling of surface seawater and globally circulating in the state of isolation from surface seawater. Although it is not as obvious as estuaries mixing, brine ground water is mixture of recirculated seawater and ground water. Seawater having high osmotic pressure infiltrates into an aquifer which is connected to the sea. In order to clarify the characteristics of deep ocean water and brine ground water, we investigated their origins, chemical compositions, water qualities and resources stabilities. While concentrations of stable isotopes (/sup 18/O and ²H) in seawater is 0‰, those in brine ground water is on meteoric water line or shifted toward oxygen line. It means that origin of brine ground water is different than that of deep ocean water. The ions dissolved in seawater (Na, Ca, Mg, K) are present in constant proportions to each other and to the total salt content of seawater. However deviations in ion proportions have been observed in some brine ground water. Some causes of these exception to the rule of constant proportions are due to many chemical reactions between periphery soil and ground water. While DOW has a large quantity of functional trace metals and biological affinity relative to brine ground water, DOW has relatively small amount of harmful bacteria and artificial pollutants.

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Rheological characteristics of non-spherical graphite suspensions

  • Mustafa, Hiromoto Usui;Ishizuki, Masanari;Shinge, Ibuki;Suzuki, Hiroshi
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.19-25
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    • 2003
  • Since the microstructure of functional thin films depends on the dispersion characteristics of dense slurry, it is important to control the agglomerative nature of slurries under processing. The present authors have been discussing the model prediction of agglomerative nature and local rate of agglomeration in dense suspensions. The experiments have been peformed under shear flow using the nearly spherical and oblate type graphite particles. In this study, the experiment has been conducted using water and glycerol as dispersion media. Stress control type rheometer was used to measure the slurry rheology. Local agglomeration of graphite particles has been predicted by using Usui's model. The experimental results show that both the shape and slurry processing method affect on the local dispersion condition. The agglomeration formed by oblate type graphite particles seems to be more difficult to break up than that of spherical particles.

Pervaporation Separation of Water/Ethanol Mixtures through PBMA/anionic PAA IPN Membrane

  • Jin, Young-Sub;Kim, Sung-Chul
    • Proceedings of the Membrane Society of Korea Conference
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    • 1996.10a
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    • pp.86-87
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    • 1996
  • IPN (Interpenetrating Polymer Network) is a mixture of two or more crosslinked polymers with physically interlocked network structures between the component polymers. IPN can be classified as an alloy of thermosets and has the characteristics of thermosets such as the thermal resistance and chemical resistance and also has the characteristics of polymer alloys with enhanced impact resistance and amphoteric properties. The physical interlocking during the synthesis restricts the phase separation of the component polymer with chemical pinning process, thus the control of morphology is possible through variations of the reaction temperature and pressure, catalyst concentration and crosslinking agent concentration. Finely dispersed domain structure can be obtained through IPN synthesis of polymer components with gross immiscibility. In membrane applications, particularly for the separation of liquid mixtures, crosslinked polymer component with specific affinity to the permeate is needed. With the presence of the permeant-inert polymer component, the mechanical strength and the selectivity of the membranes are enhanced by restricting the swelling of the transporting polymer component networks.

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Hydrophobic Modification of Fiber Surface by Plasma Polymerizafon of Perfluoropropene (Perfluoropropene의 플리즈마중합에 의한 섬유의 소수성 표면개질)

  • Seo, Eun-Deock;Kang, Young-Reep;Lim, Hak-Sang
    • Textile Coloration and Finishing
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    • v.3 no.4
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    • pp.22-28
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    • 1991
  • Perfluoropropene was plasma polymerized in the form of thin film on PET fabrics to give hydrophobic and barrier properties without affecting air permeability. Changes in surface characteristics were detected by application of ESCA, IR, SEM and contact anglemeter. The surface properties was changed markedly to be water and stain repellent although the effect was not much sensitive to the differences of chemical components of the thin films formed at different experimental conditions. The protective barrier characteristics of the thin film was also applicable to suppress the amounts of dyes extracted from fabrics in laundering.

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Adsorption Kinetic Constants for Basic Odorant on Pellet-type Adsorbents Recycled from Water-treatment Sludge (정수 슬러지를 재활용한 펠렛형 흡착제 상에서 염기성 악취 물질의 흡착속도상수)

  • Kim, Goun;Park, Nayoung;Bae, Junghyun;Jeon, Jong-Ki;Lee, Choul Ho
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.167-173
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    • 2014
  • The adsorption characteristics of the pellet-type adsorbent prepared from water treatment sludge for trimethylamine and ammonia were studied. The surface area and pore volume of the pellet-type adsorbent increased during calcination at $500^{\circ}C$. It was confirmed that the adsorbent prepared from water treatment sludge contained Br$\ddot{o}$nsted and Lewis acid sites. The breakthrough time of the adsorbent for both trimethylamine and ammonia was measured at different adsorbent weights and linear velocities while maintaining constant amounts of trimethylamine and ammonia. The kinetic saturation capacity and the adsorption rate constant for trimethylamine and ammonia were determined at different linear velocities by using the Wheeler equation. It was found that the kinetic saturation capacity and the adsorption rate constant were dependent on the linear velocity. An experimental equation could be derived to predict the breakthrough time of the adsorbent prepared from water treatment sludge for trimethylamine and ammonia at different adsorption conditions.