Rheological characteristics of non-spherical graphite suspensions

  • Mustafa, Hiromoto Usui (Department of Chemical Science and Engineering, Kobe University) ;
  • Ishizuki, Masanari (Department of Chemical Science and Engineering, Kobe University) ;
  • Shinge, Ibuki (Department of Chemical Science and Engineering, Kobe University) ;
  • Suzuki, Hiroshi (Department of Chemical Science and Engineering, Kobe University)
  • Published : 2003.03.01

Abstract

Since the microstructure of functional thin films depends on the dispersion characteristics of dense slurry, it is important to control the agglomerative nature of slurries under processing. The present authors have been discussing the model prediction of agglomerative nature and local rate of agglomeration in dense suspensions. The experiments have been peformed under shear flow using the nearly spherical and oblate type graphite particles. In this study, the experiment has been conducted using water and glycerol as dispersion media. Stress control type rheometer was used to measure the slurry rheology. Local agglomeration of graphite particles has been predicted by using Usui's model. The experimental results show that both the shape and slurry processing method affect on the local dispersion condition. The agglomeration formed by oblate type graphite particles seems to be more difficult to break up than that of spherical particles.

Keywords

References

  1. Cement and Concrete Research v.28 Crack growth mechanism in four different concretes: microscopic observations and fractal analysis Chiaia, B.;J. G. M. van Mier;A. Vervuurt https://doi.org/10.1016/S0008-8846(97)00221-4
  2. J. Power Sources v.101 Reconsideration of SEI stability : reverse lithium intercalation into graphite electrodes in trans-2,3-Butylene Carbonate Chung, G. C.
  3. J. Power Sources v.68 Recent trends in carbon negative electrode materials Kasuh, T.;A. Mabuchi;K. Tokumitsu;H. Fujimoto https://doi.org/10.1016/S0378-7753(97)02582-2
  4. J. Power Sources v.68 High-capacity lithium-ion cells using graphitized mesophase-pitch-based carbon fiber anodes Ohsaki, T.;M. Kanda;Y. Aoki, H. Shiroki;S. Suzuki
  5. Rheol. Acta v.41 Rheological behavior of concentrated mono-disperse suspensions as a function of preshear conditions and temperature : an experimental study Schmidt, M.;H. Munstedt https://doi.org/10.1007/s003970100205
  6. J. Appl. Phys. v.23 A treatment of the viscosity of concentrated suspensions Simha, R. https://doi.org/10.1063/1.1702338
  7. Colloid and Surfaces v.15 Shear-induced deformation and rupture of suspended solid/liquid clusters Smith, P. O.;T. G. M. V. D Ven https://doi.org/10.1016/0166-6622(85)80072-X
  8. Proc. of World Congress on Powder Technology v.4 Evaluation of local agglomeration in dense slurries under shear Usui, H.;M. Ishizuki;H. Suzuki
  9. Kagaku Kogaku Ronbunshu v.25 A rheological model for an agglomerative slurry of mono-modal silica particles Usui, H. https://doi.org/10.1252/kakoronbunshu.25.459
  10. Chem. Eng. Sci. v.56 non-newtonian viscosity of dense slurries prepared by spherical particles Usui, H.;K. Kishimoto;H. Suzuki https://doi.org/10.1016/S0009-2509(00)00476-0
  11. J. Chem. Eng. Japan v.34 Viscosity prediction of dense slurries prepared by non-spherical particles Usui, H.;L. Li;S. Kinoshita;H. Suzuki https://doi.org/10.1252/jcej.34.360