• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 1994년도 가을 학술발표회 논문집
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• pp.65-70
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• 1994

The aim of this study is to develop the High Workable Concrete which has not so large slump loss with time using blast-furnace cement and High range water reducing agent. Normal portland cement and blast-furnce cement was used as binders and water-binder ratio were ranging from 34% to 50%. 5 kinds of Superplasticizer and High range water reducing agent were used. Test results show that the blast-furmace cement was much higher flowability than normal portland cement and domestic High rang water reducing and AE agent had very small slump loss than others. The compactability of High Workable Concrete was also confirmed using model wall-form.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2005년도 학술발표논문집
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• pp.97-101
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• 2005

High strength concretes utilizing EVA with micro particles were prepared by varying polymer/binder mass ratio and curing conditions with a constant water/binder mass ratio of 0.3. The EVA modified concretes on the compressive and flexural strength, microstructure, ultrapulse modulus in curing condition(dry and water curing) were studied. Also, scanning electron microscope analysis(SEM) was performed to reveal the presence of polymer film and cement hydrates in the concrete. The compressive strength of the EVA modified concretes cured at water conditions ere higher than that of the EVA modified concretes cured at dry conditions. But, the flexural strength of the specimens cured at dry conditions were higher than that of the specimens cured at water conditions. Due to the interaction of the cement hydrates and polymer film, an interpenetrating network originated in which the aggregates were embedded. The curing of the polymer modified concrete involves two step of cement hydrates and polymer modification, and cement hydrates was promoted in water conditions and polymer film formation take place when water evaporates and was thereby was favored in dry conditions. By SEM analysis, influences of polymer modification was strengthening of the transition zone between the aggregate and the paste, and the porosity of transition zone decreases. By spring analysis, it could known that polymer film affects in porosity decrease and strengthening of transition zone.

• 한국건축시공학회지
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• 제11권6호
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• pp.587-596
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• 2011

폴리머 시멘트 모르타르를 긴급공사의 보수 보강 재료로 사용할 때, 초속경시멘트와 혼입하여 사용함으로써 시멘트의 빠른 응결과 시멘트 매트릭스 내부에서 형성된 폴리머 필름의 작용이 물리적 성질과 내구성을 개선시킬 수 있다. 또한 각종 혼화재료를 혼입함으로써 매트릭스 내부 공극을 충전하여 성질을 개선시킬 수 있는데, 양생방법이 큰 영향을 미칠 수 있다. 본 연구에서는 속경성 SBR 시멘트 모르타르의 압축강도와 휨강도에 영향을 미칠 수 있는 혼화재료와 양생조건에 관하여 실험을 실시하여 그 영향성을 평가하고자 하였다. 본 연구결과, 초속경시멘트 모르타르에 SBR을 혼입함으로써 휨강도와 압축강도가 크게 개선되었으며, 여기에 메타카올린을 혼입함으로써 보다 더 강도를 증진시킬 수 있었다. 또한 양생방법에 있어서도 SBR을 사용한 경우에는 표준양생에서, SBR을 사용하지 않은 경우에는 수중양생에서 강도발현이 크게 나타났다.

• 한국지반공학회논문집
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• 제18권4호
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• pp.75-83
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• 2002

본 연구에서는 준설토, EPS 그리고 고화재를 혼합한 경량혼합토의 역학적 특성을 일축 및 삼축압축시험을 통하여 고찰하였다. 역학적 특성은 다양한 준설토의 초기 함수비, EPS 함유율, 시멘트 함유율 그리고 양생압력에 대한 경량혼합토의 압축강도에 대하여 연구하였다. 삼축압축상태에서 EPS를 함유한 경량혼합토의 압축강도는 유효구속압에 의존 하지 않는 것으로 나타났다. EPS 함유율이 감소할수록($A_E$<2%) 그리고 시멘트 함유율이 증가할수록($A_c$>2%) 삼축압축강도-변형 거동특성은 극한 압축강도를 지나 급격한 압축강도의 감소를 보이는 시멘트 혼합토의 압축강도-변형 거동특성과 유사한 것으로 나타났다. 200kpa 이상의 압축강도를 요구하는 개량지반에 본 경량혼합토를 적용하는 경우에서 적절한 준설토의 초기함수비, EPS 함유율은 각각 약 165%~175%이상 그리고 3%~4%이상으로 제시할 수가 있었다. 삼축 및 일축압축상태에서 극한 압축강도는 시멘트 함유율이 2%이상에서 거의 증가하지 않음으로서 한계 시멘트 함유율은 2%로 제시할 수가 있었다.

• Advances in nano research
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• 제14권1호
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• pp.81-92
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• 2023

In this work, the effect of the addition of Aerosil 200, an insulating resin applied in many industries, on the water absorption of cement plast mixture has been experimentally evaluated. First, the preparation stages of cement plast mixture was evaluated based on corresponding standards and then, the effect of the addition of Aerosil 200 nanoparticles (NPs) to cement plast mixtures with sand weight percentage range of 0-0.1% on the variation of water absorption properties was evaluated based on National Standard Institution of Iran 20185 for Concrete Flooring Blocks - Requirements and Test Procedures. Based on the obtained results, it could be found that excessive addition of NPs did not affect the physical properties of the final product. Water absorption percentage was increased in the weight percentage of cement. By the increase of the amount of Aerosil 200 NPs in the prepared cement plast mixture, the percentage of water absorption in weight percentage of sand was decreased. Cement plast with NPs presented significantly lower water absorption than that without NPs.

• 한국세라믹학회:학술대회논문집
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• 한국세라믹학회 2007년도 제34회 시멘트 심포지엄
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• pp.129-137
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• 2007

This paper presents a numerical model which can predict degree of hydration of cement mineral component, such as $C_{3}S$, $C_{2}S$, $C_{3}A$, $C_{4}AF$ and microstructure of hydrating cement as a function of water to cement ratio, cement particle size distribution, cement mineral components and temperature. In this model cement particles are parked randomly in cell space and hydration process is described using a multi-component integrated kinetic model. The simulation result of degree of hydration of cement mineral component agrees well with experiment result. The content of cement hydration product, such as CSH and CH can be obtained as an accompanied result during hydration process. By introducing of equal-area projection method, water withdrawl mechanism and contact area among cement particles can be considered in detail. By using proposed method, pore size distribution of hydrating cement is predicted.

• 한국세라믹학회지
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• 제27권4호
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• pp.495-500
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• 1990

Investigation for the preparation of high strength hardened cement paste using ordinary portland cement, hydroxypropyl methyl cellulose (HPMC) with admixtures was carried out. For molding of the specimen, the paste was mixed with 0.1 of water cement ratio by twin roll mill. The maximum flexural strength of dried hardened cement paste was about 600∼700kg/㎠. When the SiC was added to the paste, the dry flexural strength was about 920kg/㎠ and the young's modulus was 5.2×105kg/㎠. When the admixtures were added to the specimens, wet strength of the harened cement paste immersed in water was showed around 50∼100kg/㎠ higher than that of plain specimen. Consequently it is recognized the water stability of hardened cement paste was remarkably improved by adequate admixture.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2005년도 학술발표논문집
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• pp.123-127
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• 2005

EVA Powder modified high strength concretes were prepared by varying polymer/binder mass ratio with a constant water/binder mass ratio of 0.3. The effect of EVA powder on the slump, hydration heat, compressive and flexural strength, toughness and water absorption ratio was studied. In hydration heat test, temperature of hydration reaction displayed almost fixed level regardless of containing rate of EVA powder, but peak time of hydration reaction displayed late inclination as containing rate of powder increases. With the same water/binder mass ratio, the compressive strength and water absorption of EVA powder modified concretes decreased slightly when EVA powder was added and the flexural strength of EVA powder modified concretes rised slightly when EVA powder was added. Also, the toughness of the modified concretes can be improved markedly. The interpenetrating structure between the polymeric phase and cement hydrates formed at a $2{\sim}6%$(containing rate of EVA powder). The properties of the polymer modified concretes were influenced by the polymer film, cement hydrates and the combined structure between the organic and inorganic phases.

• 공업화학
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• 제5권4호
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• pp.669-680
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• 1994

친유성기와 친수성기를 함유한 긴 탄화수소 화합물인 dodecylmetacrylate와 2-diethylaminoethyl methacrylate로부터 DMA-co-DAMA를 합성하고 물에 쉽게 유화시키기 위해 양이온화 하여 아세트화 아크릴 공중합체를 합성하였다. 합성된 공중합체와 아세트화 공중합체의 구조를 IR, NMR 등으로 확인하고 GPC로부터 분자량을 산출하였으며 C. H. N분석도 하였다. 아세트화 아크릴 공중합체는 물에 완전히 유화가 가능하였고 물에 대한 유화 안정성이 증진되었다. 위에서 합성한 아세트화 아크릴공중합체에 Sodium Silicate Sodium gluconate, Oleic acid, Triethanolamine을 브렌딩하여 제조된 혼화용 폴리머 분산제(PDCM-PDD)를 제조하였다. 이것을 가지고 용융시험한 결과 45배 희석시 강도비 1.02, 흡수비 0.36~0.57, 투수비는 수압 $100g/cm^2$에서 0.44, $3kg/cm^2$에서 0.55로 우수한 방수성을 확인하였다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2009년도 춘계 학술대회 제21권1호
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• pp.325-326
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• 2009

본 연구에서는 물-시멘트 비에 따른 시멘트계 재료인 시멘트 페이스트, 모르터 및 콘크리트의 pH 저하 저항성을 평가하였다. 우선 시멘트 페이스트에 대해 물-시멘트 비 30%, 40%, 50% 인 보통 포틀랜드 시멘트 페이스트의 산 증가에 따른 pH를 측정하였다. 또한, 페이스트의 pH 저하 저항성에 대한 골재의 영향에 대해 알아보기 위해서 콘크리트, 모르터, 페이스트의 pH 저하 저항성 측정 실험도 수행하였다. 실험결과, 산이 증가할수록 pH는 감소하였으며 특히 pH 10 정도에서 급격한 pH 저하가 발생되었다. 산 증가에 따른 pH 감소정도는 산중화능력으로 나타내었으며 시멘트 수화물에 의해 특정 pH에서 산중화능력이 물-시멘트비에 따라 높게 나타났다.