• Title/Summary/Keyword: waste alkali

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Performance of one-part alkali activated recycled ceramic tile/fine soil binders

  • Mawlod, Arass Omer
    • Advances in concrete construction
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    • v.10 no.4
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    • pp.311-317
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    • 2020
  • Performance of Sustainable materials continues through using of recycled waste construction materials to minimize the utilization of the natural resources. The cement industry is a major source of CO2 in the atmosphere which is the main cause of global warming. Replacement of OPC with other sustainable cementitious materials has been the most interesting area of researches. This investigation focuses on the properties of alkali-activated mortar with the different replacement ratios of ceramic tile powder (CTP) by fine soil powder (FSP) (0 to 100)% and different molarities of sodium hydroxide concentrations. The experimental program was conducted by examining the compressive strength, water absorption, and water sorptivity. The results showed that the compressive strength of the specimens at age of (28, 56, and 90 days) increases with an increase in the amount of fine soil powder content and decreases at the age of 120 days. Also, minimum water absorption at the age of 90 days was found in the mixes containing 100% fine soil powder. However, fine soil powder replacement had a negative effect on the sorptivity and water absorption values at the age of 120 days. On the other hand, the 12M sodium hydroxide concentration was considered the optimum concentration compared to other concentrations.

Kraft Pulping of Sapwood-A Sawmill Waste

  • Jahant M. Sarwar;Chowdhury D.A. Nasima;Islam M. Khalidul;Mun Sung Phil
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.37 no.5 s.113
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    • pp.41-49
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    • 2005
  • This paper deals the effect of anthraquinone (AQ) on the contribution of sulphidity in kraft pulping of sapwood. The pulping conditions namely- active alkali concentration, pulpingtime, temperature and liquor ratio were varied in low ($15\%$) and high ($30\%$) sulphidity. $0.1\%$ AQ was added in the low and high sulphidity pulping with varying active alkali concentration and cooking time. At optimum conditions, low sulphidity kraft process produced about $44\%$ pulp yield with kappa number of about 23. But in high sulphidity kraft process kappa number was reduced to about 20 at the same yield. An addition of AQ reduced alkali requirement by $2\%$ on oven dried raw material and cooking time by 1 hour to produce pulp yield of about $44\%$ at kappa number 20. AQ is more effective in low sulphidity pulping than the high sulphidity pulping. The breaking length of kraft-AQ pulp was slightly higher than that of kraft pulp.

Estimation of Alkali Overdosing in a Lime Neutralization Process for Acid Mine Drainage

  • Cheong, Young-Wook;Cho, Dong-Wan;Lee, Jin-Soo;Hur, Won
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.109-112
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    • 2022
  • Lime has been used for the neutralization of acidic waste because it is cheap and available in large quantities. The resulting sludge often contains a considerable amount of unreacted lime due to alkali overdosing, even during automatic neutralization processes, which mainly arises from the poor solubility of lime. The sludge cake from lime neutralization of Ilkwang Mine also contained high percentages of calcium and magnesium. The elemental content of the sludge cake was compared with those obtained from a simulation of the lime neutralization facility installed at Ilkwang Mine. A Goldsim® model estimated the degree of lime overdosing to be 19.1% based on the fractions of ferrous oxide. The analysis suggests that resolubilization of aluminum hydroxide could occur in the settling basin, in which pH exceeded 10 due to the continued dissolution of the overdosed lime. The present study demonstrated that chemical analysis of sludge combined with process simulation could provide a reasonable estimate of mass balance and chemistry in a neutralization facility for acid mine drainage.

Properties of High Volume Blast Furnace Slag Concrete using Recycled Aggregate with Incineration Waste Ash (소각장애시의 치환에 따른 고로슬래그 미분말 다량치환 순환골재 콘크리트의 특성)

  • Han, Cheon-Goo;Lee, Hyang-Jae;Kim, Jun-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.2
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    • pp.107-113
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    • 2013
  • This study is the study desiring to solve the problem by utilizing the kinds of recycled resources considered to be troubled complementarily. Namely the reaction of potential hydraulicity of Blast Furnace Slag Powder (BS) shall be reacted with the alkali of Recycled Fine Aggregates Coarse Aggregate, it has been experimented to obtain the optimum value with the replacement ratio of incineration plant ash (WA) treated with the slaked lime as the experiment variable by solving the alkali of shortage with the Ordinary Portland Cement (OPC). As a result, the liquidity and the air volume are declined slightly as the replacement ratio of incineration plant ash WA increases, the mixture of incineration plant ash WA 1% has been analyzed to be the most suitable considering the viewpoint of effective handling of waste as the compression and the tensile strength showed the maximum value before and after 1% even though it was disadvantageous with the increase of chloride content.

Preparation and Characterization of Copper Oxychloride from Acidic Copper Chloride Etchant (PCB 산업에서 배출되는 산성 염화동 폐액으로부터 Copper Oxychloride의 제조 및 특성분석)

  • 김영희;김수룡;정상진;이윤주;어영선
    • Resources Recycling
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    • v.12 no.2
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    • pp.3-10
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    • 2003
  • Copper oxychloride used as an agricultural fungicide has been recovered from copper-containing waste etchant by the neutralization with alkali hydroxides. Large amount of copper-containing waste etchant is generated from Printed Circuit Board industry. In an environmental and economic point of view, retrieve of the valuable natural resource from the waste is important. Recycling process of copper oxychloride from the waste etchant is discovered through the our study. In the range of reaction temp. 2$0^{\circ}C$-4$0^{\circ}C$, pH 5-7, pure copper oxychloride was able to prepare and the yield of copper oxychloride was higher than 95%. Physical properties of the sample have been characterized using SEM, XRD, TGA, ICP and Atomic absorption spectroscopy.

Durability properties of fly ash-based geopolymer mortars with different quarry waste fillers

  • Tammam, Yosra;Uysal, Mucteba;Canpolat, Orhan
    • Computers and Concrete
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    • v.29 no.5
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    • pp.335-346
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    • 2022
  • Geopolymers are an important alternative material supporting recycling, sustainability, and waste management. Durability properties are among the most critical parameters to be investigated; in this study, the durability of manufactured geopolymer samples under the attack of 10% magnesium sulfate and 10% sodium sulfate solution was investigated. 180 cycles of freezing and thawing were also tested. The experimentally obtained results investigate the durability of geopolymer mortar prepared with fly ash (class F) and alkali activator. Three different quarry dust wastes replaced the river sand aggregate: limestone, marble, and basalt powder as fine filler aggregate in three different replacement ratios of 25%, 50%, and 75% to produce ten series of geopolymer composites. The geopolymer samples' visual appearance, weight changes, UPV, and strength properties were studied for up to 12 months at different time intervals of exposure to sulfate solutions to investigate sulfate resistance. In addition, Scanning Electron Microscopy (SEM), EDS, and XRD were used to study the microstructure of the samples. It was beneficial to include quarry waste as a filler aggregate in durability and mechanical properties. The compact matrix was demonstrated by microstructural analysis of the manufactured specimens. The geopolymer mortars immersed in sodium sulfate showed less strength reduction and deterioration than magnesium sulfate, indicating that magnesium sulfate is more aggressive than sodium sulfate. Therefore, it is concluded that using waste dust interrogation with partial replacement of river sand with fly ash-based geopolymers has satisfactory results in terms of durability properties of freeze-thaw and sulfate resistance.

New Korean Traditional Papermaking from Paper Mulberry(III)-Properties of the Hanjis Mixed with Bast Part and Whole Stalk Pulps- (닥나무를 이용한 새로운 한지의 제조(제3보)-인피부 및 전간부 펄프 혼합초지 한지의 특성-)

  • 최태호;조남석
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.30 no.2
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    • pp.85-95
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    • 1998
  • Traditionally, Hanji had been made only with the bast fiber of paper mulberry (Broussonetia kazinoki). Nowadays, Hanji has been made mainly in the mixed forms of paper mulberry bast fiber and waste paper, and consequently it has raised many problems using them. This study was carried out to investigate the characteristics of Hanji mixed with paper mulberry bast part and whole stalk pulps. Hanjis made from the solfomethylated pulp were shown higher brightness and sheet strengths than those from alkali and alkali-hydrogen peroxide pulps. The brightness of solfomethylated pulp was found to be high enough not to need additional bleaching. The sheet formations were improved as the increase of whole stalk pulp contents, while the sheet strengths were decreased. In the physical properties of the Hanji mixed with bast part and whole stalk pulps, the handsheet strengths were decreased as the increase of the whole stalk pulp contents. The tensile strength and folding endurance of the Hanji containing 40∼60% of whole stalk pulps were higher as compared to the others.

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Mechanical Properties and ASR Behavior of Recycled Glass Fine Aggregate Mortar Mixed with Mineral Admixture (혼화재를 혼입한 순환유리잔골재 모르타르의 역학적 특성과 ASR 거동)

  • Eu, Ha-Min;Kim, Guy-Yong;Park, Jun-Young;Sasui, Sasui;Choi, Byung-Cheol;Nam, Jeong-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.05a
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    • pp.195-196
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    • 2023
  • In this study, the mechanical properties, alkali-silica reaction(ASR) expansion and residual mechanical properties after ASR of waste glass fine aggregate(GS) mortar according to mineral mixture were evaluated. As a result, it was found that the mineral mixture reduces the ASR expansion. However, mechanical properties and residual mechanical properties have decreased.

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Physical Characteristics of Cement Mortar Prepared Using Waste Glass and Graphene Oxide (폐유리와 산화 그래핀을 사용한 시멘트 모르타르의 물성 연구)

  • Kim, Kyoungseok;Chu, Yongsik
    • Resources Recycling
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    • v.28 no.6
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    • pp.54-63
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    • 2019
  • This study investigated on the compressive strength and the length change test with using the waste glass and graphene oxide for recycling the waste glass as the aggregate. Curing on 3-day and 7-day, the compressive strength was enhanced as the usage of waste glass was increased. Especially, the huge difference in the compressive strength was observed when the amount of substituting on the waste glass was used on 10~50%. With 50% of waste glass condition, the compressive strength was portionally enhanced as the usage of graphene oxide was increased and its value was 42.6 N/㎟ with 0.2% of graphene oxide. In terms of the length change test, the use of high content of waste glass led length change value to increase, but it was dropped down as the portion of waste glass was above 50%. Furthermore, in the case of using 50% of waste glass, the use of high amount of graphene oxide tended to decrease the length change value. That is, graphene oxide may contribute on boosting the cement hydration reaction and blocking the ion's movement.

Effect of pH on Hydrogen Fermentation of Food Waste with Livestock Wastewater (음식물쓰레기 수소발효 시 pH 영향 및 축산폐수와의 혼합 발효)

  • Jang, Hae-Nam
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.5-9
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    • 2016
  • In the modern industrial society, huge amount of organic wastes have exceeded the society's self-cleaning capability, caused pollution of the whole environment, including water quality, soil, and the air, and become a big burden of waste treatment. Moreover, the emission of green house gases brought by the continual combustion of fossil fuels has facilitated the global warming. The simultaneous effect of initial and operational pH on $H_2$ yield was expressed using mathematical equation and optimized. The optimal initial and cultivation pH was 7.50 and 6.01, respectively. Addition of livestock wastewater to food waste substantially decreased the amount of alkali requirement and also improved the $H_2$ fermentation performance.