• Title/Summary/Keyword: waste acid

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Comparison of physiological activities and of useful compounds between new and waste bulbs of different lily (Lilium davidii) varieties

  • Yi, Tae Gyu;Park, Yeri;Yang, Su Jin;Lim, Jung Dae;Park, Sang Un;Park, Kyong Cheul;Park, Nam Il
    • Korean Journal of Agricultural Science
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    • v.43 no.5
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    • pp.734-741
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    • 2016
  • Lily (Lilium davidii) is a high-yielding flowering plant. Besides roses and chrysanthemums, lily bulbs have long been used as food and in oriental medicine. However, the usage and value of cut lily bulbs has not been recognized. A bulb whose yield has been decreased is called a waste bulb, and a large amount of such bulbs is discarded every year. In this study, the functionality of waste bulbs from cut lilies was investigated to explore their potential use as a value-added product. We divided lily bulbs into two groups, one group with six varieties of new bulbs (Medusa, Siberia, Woori Tower, Yelloween, Le Reve, and Morning Star) used for cultivation and the other group with six varieties of waste bulbs (Medusa, Siberia, Woori Tower, Yelloween, Sorbonne, and Sheila). Physiological activities (${\alpha},{\alpha}$-diphenyl-${\beta}$-picrylhydrazyl: DPPH) and 3-ethlbenzthiazolne-6-sulfonic acid (ABTS) radical scavenging capability and tyrosinase inhibiting activity), the amount of total as well as eight individual phenolic compounds (chlorogenic acid, epicatechin, rutin hydrate, p-coumaric acid, kaempferol 3-O-${\beta}$-rutinoside, phloridzin dihydrate, myricetin, and quercetin), and total flavonoid content were measured in the bulbs by high performance liquid chromatography. We detected high amounts of total phenol and total flavonoid as well as high DPPH and ABTS radical scavenging ability. More tyrosinase inhibiting activity was detected in the new bulbs than in the waste bulbs. However, both the new and waste bulbs showed a higher inhibitory activity than the standard (100 ppm ascorbic acid). Although the content of phenolic compounds differed among varieties, under the conditions of the experiment, the most abundant phenolics were epicatechins, followed by chlorogenic acid, and rutins. Overall, the waste bulbs had a higher content of these compounds than the new bulbs. Based on these results, we concluded that bulbs from cut lilies could be used as functional foods in the future and farmers could expect economic gain from the hitherto neglected waste bulbs.

On the Recycling Substances and a Clean Technology Development for the Treatment of Mixed Acid Waste Water with Ozone (오존을 이용한 혼산폐수처리에 관한 청정기술개발 및 재이용 물질 회수에 관한 연구)

  • 김재우
    • Journal of environmental and Sanitary engineering
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    • v.15 no.2
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    • pp.34-40
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    • 2000
  • In the tungsten industry, molybdenum wire which used as the center supporter for coil shape tungsten wire was removed. Nitric acid dissolution method which used prevalently up to the present, takes nitric acid as major component and use noxious material such as sulfuric acid and hydrochloric acid remove molybdenum wire which used as center supporter by dissolve selectively within the range of no damage on tungsten wire. Mixed acid waste water occurred to the process were difficult to be decomposed by the conventional methords. This mixed acid waste water was treated by ozone, and It was obtained using possible by-product through the treatment waste water. For the three reactors with the same volume ; Blank reactor, Disturbance plate reactor, Packed-bed reactor ; the results were as follows : For the blank reactor COD removal efficiency in the pH = 4 (HRT : 6hr) was 28.5%, COD removal efficiency in the pH = 7 (HRT : 6hr) was 28.6%, and COD removal efficiency in the pH = 10 (HRT : 6hr) was 27.8%. For the disturbance plate reactor COD removal efficiency in the pH = 4 (HRT : 6Min.) was 86.5%, COD removal efficiency in the pH =7 (HRT : 6Min.) was 84.4%, and COD removal efficiency in the pH = 10 (HRT : 60Min.) was 86.8%. For the packed-bed reactor COD removal efficiency in the pH = 4 (HRT : 40Min.) was 76.0%, COD removal efficiency in the pH = 7 (HRT : 40Min.) was 81.3%, and COD removal efficiency in the pH = 10 (HRT : 40Min.) was 84.6%. After O3 treatment using possible by-product(Na2SO4) was 150g/ℓ.

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Characteristics of Desorption and Recycling Capacity for Previously Adsorbed Silver into Waste Coffee Grounds (커피찌꺼기에 흡착된 은 이온의 탈착 및 재생 특성)

  • Jeon, Choong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.3
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    • pp.15-21
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    • 2016
  • This experiment was conducted to test desorption and recycling characteristics for silver ion adsorbed into waste coffee grounds by using various desorbing agents such as nitric acid, ethylene diamine triacetic acid (EDTA) and nitrilo triacetic acid (NTA). It is appeared that the highest desorption efficiency for silver ions was obtained as about 97.8 % by 1.0 M of nitric acid solution. Also, in the case of less than 1.0 of the ratio of solid and liquid (S/L) (g/L), silver ions adsorbed onto coffee grounds was desorbed as about 98~100 %, and most of desorption process was completed within 60min. In addition, adsorption capacity of reused waste coffee grounds for silver ions was highly maintained as about 43.9 mg/g until the $2^{nd}$ cycle, as compared with the adsorption capacity with 45.9 mg/g of the adsorption capacity for virgin waste coffee grounds.

Production of Hydrogen and Volatile Fatty Acid by Enterobacter sp. T4384 Using Organic Waste Materials

  • Kim, Byung-Chun;Deshpande, Tushar R.;Chun, Jongsik;Yi, Sung Chul;Kim, Hyunook;Um, Youngsoon;Sang, Byoung-In
    • Journal of Microbiology and Biotechnology
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    • v.23 no.2
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    • pp.189-194
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    • 2013
  • In a study of hydrogen-producing bacteria, strain T4384 was isolated from rice field samples in the Republic of Korea. The isolate was identified as Enterobacter sp. T4384 by phylogenetic analysis of 16S rRNA and rpoB gene sequences. Enterobacter sp. T4384 grew at a temperature range of $10-45^{\circ}C$ and at an initial pH range of 4.5-9.5. Strain T4384 produced hydrogen at 0-6% NaCl by using glucose, fructose, and mannose. In serum bottle cultures using a complete medium, Enterobacter sp. T4384 produced 1,098 ml/l $H_2$, 4.0 g/l ethanol, and 1.0 g/l acetic acid. In a pH-regulated jar fermenter culture with the biogas removed, 2,202 ml/l $H_2$, 6.2 g/l ethanol, and 1.0 g/l acetic acid were produced, and the lag-phase time was 4.8 h. Strain T4384 metabolized the hydrolysate of organic waste for the production of hydrogen and volatile fatty acid. The strain T4384 produced 947 ml/l $H_2$, 3.2 g/l ethanol, and 0.2 g/l acetic acid from 6% (w/v) food waste hydrolysate; 738 ml/l $H_2$, 4.2 g/l ethanol, and 0.8 g/l acetic acid from Miscanthus sinensis hydrolysate; and 805 ml/l $H_2$, 5.0 g/l ethanol, and 0.7 g/l acetic acid from Sorghum bicolor hydrolysate.

Optimal Condition for Citric Acid Production from Milk Factory Waste Water by Using the Immobilized Cells of Aspergillus niger (고정화 Aspergillus niger 세포를 이용한 우유공장 폐수로부터 구연산 생산의 최적 조건)

  • 이용희;서명교;노호석;이동환;정경태;정영기
    • Microbiology and Biotechnology Letters
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    • v.32 no.2
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    • pp.154-157
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    • 2004
  • Immobilized cells of Aspergillus niger was employed to produce citric acid by fermentation of milk factory waste water. A. niger ATCC 9142 as a citric acid production strain was cultured for 3 days and was entrapped with Ca-alginate bead about 2.5∼3.5 mm. The optimal pH and temperature were estimated to be 3.0 and $30^{\circ}C$, respectively. Dilution rate for fermentation was calculated to be $0.025 h^{-1}$ . Maximum amount of citric acid was obtained at 4.5 g/$\ell$ with the optimized fermentation condition. The yield of citric acid produced by immobilized A. niger ATCC 9143 was 70.3%. The yield was increased by 20% with immobilized cell, compared to that of the shake flask culture. Hence, the milk factory waste water is worthy to be used for the substrate of citric acid fermentation.

Solidify Properties of Radioactive Waste using Paraffin Wax (파라핀 왁스를 이용한 방사성 폐기물의 고화 특성)

  • Lee, Han Chul;Chang, Yoon Ho
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.391-396
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    • 2006
  • When radioactive wastewater was solidified treatment by cement, the drying rate of cement and the volume reduction ratio was decreased because of boric acid component in the wastewater. In order to supplement the demerit, effects of paraffin wax investigated in this study. Paraffin wax has a hydrophobic properties and a low affinity with inorganic materials. When the radioactive wastewater was tested by a small of wax, the compressive strength of solidified waste are decreased Therefore boric acid in radioactive wastewater are first treated by alkali salt and coated by the stearic acid. During the solidification step, The amount of paraffin wax addition get the result that the compressive strength of solidification with cement was the same as that with paraffin wax. The leaching properties of radioactive waste solidified was the same CFL (cumulative fraction leached), PR (penetration rate), effective diffusivity if paraffin wax content in solidified waste was 20% or 25%.

Separation of Heavy Metals from Electroplating Waste Water by Solvent Extraction (용매추출법에 의한 광금폐수중 중금속의 분리에 관한 연구)

  • KIM Sung Gyu;LEE Hwa Yeung;OH Jong Kee
    • Resources Recycling
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    • v.12 no.1
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    • pp.25-32
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    • 2003
  • A study on the separation of heavy metals such as iron, copper, zinc and nickel from electroplating waste water has been investigated. The results showed that the PC-88A was more effective extractant for the extraction of zinc and the efficiency of zinc was to be about 100% at pH 2.5. And copper and nickel were extracted about 100% at pH 2 and more than 90% at pH 4~5 with LIX 84, respectively. On the other hand, in the case of solvent extraction of electroplating waste water(Acid-Alkali type) containing heavy metals, the ferric ion was first extracted at pH 2∼2.5 with 20% Naphthenic acid or 10% Versatic acid-10. And then, copper and zinc were extracted at pH 2 with 3% LIX 84 and at pH 2.5∼3 with 20% PC-88A respectively, remaining nickel in the raffinate. In this manner, the heavy metals in electroplating waste water could be effectively separated with solvent extraction method.

Studies on the Influence of Mercaptoacetic Acid (MAA) Modification of Cassava (Manihot sculenta Cranz) Waste Biomass on the Adsorption of Cu2+ and Cd2+ from Aqueous Solution

  • Horsfall, M. Jnr.;Spiff, A.I.;Abia, A.A.
    • Bulletin of the Korean Chemical Society
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    • v.25 no.7
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    • pp.969-976
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    • 2004
  • Cassava peelings waste, which is both a waste and pollutant, was chemically modified using mercaptoacetic acid (MAA) and used to adsorb $Cu^{2+}\;and\;Cd^{2+}$ from aqueous solution over a wide range of reaction conditions at $30^{\circ}C$. Acid modification produced a larger surface area, which significantly enhanced the metal ion binding capacity of the biomass. An adsorption model based on the $Cu^{2+}/Cd^{2+}$ adsorption differences was developed to predict the competition of the two metal ions towards binding sites for a mixed metal ion system. The phytosorption process was examined in terms of Langmuir, Freundlich and Dubinin-Radushkevich models. The models indicate that the cassava waste biomass had a greater phytosorption capacity, higher affinity and greater sorption intensity for $Cu^{2+}\;than\;Cd^{2+}$. According to the evaluation using Langmuir equation, the monolayer binding capacity obtained was 127.3 mg/g $Cu^{2+}$ and 119.6 mg/g $Cd^{2+}$. The kinetic studies showed that the phytosorption rates could be described better by a pseudo-second order process and the rate coefficients was determined to be $2.04{\times}10^{-3}\;min^{-1}\;and\;1.98{\times}10^{-3}\;min^{-1}\;for\;Cu^{2+}\;and\;Cd^{2+}$ respectively. The results from these studies indicated that acid treated cassava waste biomass could be an efficient sorbent for the removal of toxic and valuable metals from industrial effluents.

Feasibility Study on the Vitrification of Concentrated Boric Acid Waste (붕산농축폐액 유리화 타당성 연구)

  • Cho, Hyun-Je;Kim, Deuk-Man;Park, Jong-Kil
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.8 no.2
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    • pp.143-150
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    • 2010
  • Vitrification technology has been gradually recognized as one of effective solidification methods for concentrated boric acid wastes generated in PWR. Vitrification for low- and intermediate-level radioactive wastes has a large volume reduction and good durability for the final products. A feasibility study for the vitrification of concentrated boric acid wastes has been performed with developing the pre-treatment methods of powdered wastes, glass compositions using glass formulation and demonstration test. The pre-treatment method is pelletizing the powder type for stable feeding within cold crucible melter. The glass compositions should be developed considering molten glass are related with wastes reduction. High contents of sodium and boron within borate wastes give influence to waste loading. A variety of factors obtained from the demonstration test are reviewed, which is wastes feeding rate, off-gas characteristics on stack and glass characteristics of final products such as durability for implementing the wastes disposal requirement. The aim of this paper is to present the feasibility of vitrification and review the solidification method for concentrated boric acid wastes and obtain the physicochemical characteristics of solidified glass.

Composition Analysis of Black Soldier Fly (Hermetia illucens) Larvae Fed with Different Three Single Fruit By-products (과채류 부산물 급이에 따른 아메리카동애등에(Hermetia illucens) 유충의 성분 분석)

  • Bonwoo Koo;Ji Yeong Park;Yong-Soon Kim;Ki Hyun Kim;Kwanho Park
    • Journal of Environmental Science International
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    • v.32 no.12
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    • pp.965-972
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    • 2023
  • As the world population growth and economy develops, the importance of eco-friendly organic waste resource treatment and up-cycling increases. Black soldier fly (BSF) (Hermetia illucens) treats organic waste resources that allows it to be recycled as a feed resource. In this study, we analyzed the nutrients composition, amino acid, and fatty acids of BSF larvae fed three agricultural by-products, namely apple pomace, mandarin waste, and oriental melon waste (mainly generated in South Korea). The highest BSF larvae crude protein and amino acid content was obtained in those fed mandarin waste compared with the other two diets (apple pomace and oriental melon waste). BSF larvae fed apple pomace had the highest crude fat, fatty acid, and lauric acid content compared with the other BSF larvae. Furthermore, all crude protein and fat content of BSF larvae fed the three agricultural by-products exceed that of the original agricultural by-products.