• Elastomers and Composites
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• v.47 no.2
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• pp.121-128
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• 2012

Waste EPDM(W-EPDM) collected from the automotive weather strip and the gasket of a laundry machine has not been effectively recycled. Using this W-EPDM powder and other ingredients, i.e., binder(polyolefin resin, polyolefin elastomer, etc.), filler and additives, various economic rubber composites were made by extrusion. In advance of main experiments, the effects of ultrasonic treatment of W-EPDM on the property of rubber composites, comparison in the property of the composites of W-EPDM with those of virgin and devulcanized EPDM, and waste tire rubber were investigated. Also, the properties of the rubber composites extruded with a 12-screw extruder were compared with those extruded with twin-screw extruder. Various W-EPDM composites for synthetic turf filler and car mat were extruded and injection molded, and 3 main properties of tensile strength, elongation and hardness were investigated to develop economical and proper recipes of the rubber composites.

• Elastomers and Composites
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• v.36 no.2
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• pp.86-93
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• 2001

For solving the environmental problem of the waste EPDM and for new TPE blend materials, we developed a new kind of TPE material using a co-rotating twin screw extruder. To improve the mechanical properties of TPE material such as tensile strength, elongation at break, and modulus of the blend, PP and waste EPDM powder were blended with different screw configurations. The mechanical properties of the blends and morphology of the TPE were investigated. As the number of kneading disc and left-handed screw element increased, dynamic vulcanization of the material was increased because the shear stress and residence time of blends increased.

• Journal of Environmental Science International
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• v.17 no.1
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• pp.107-112
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• 2008

A study on the enhancement of environmental durability of EPDM rubber materials for the aerator membrane was performed using a butyl rubber as a modifier. A conventional EPDM rubber formulation was evaluated as having about 26.0 wt% or more oil content from the chloroform immersion test. These oils would be gradually and continuously deleted from the aerator membrane when directly exposed to a waste-water or chemically corrosive fluids, making the membrane less flexible and the performance worse. To improve this, a butyl rubber (IIR) was utilized as the modifier for a low-ENB type of EPDM rubber formulation with low-oil content. The environmental durability of the IIR-modified EPDM rubber material was expected to be greatly enhanced compared to the conventional one. However, the mechanical and performance properties such as elongation, tensile strength, and air bubble size, etc. were still maintained as good as in the conventional one. Furthermore, TGA analysis of the IIR-modified EPDM material showed that there would be partially compatible between IIR and EPDM. It also showed that the initial degradation temperature of the IIR-modified EPDM could be somewhat increased, exhibiting the enhanced compatibility among the components and, thereby, more enhanced environmental durability.

• Elastomers and Composites
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• v.42 no.4
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• pp.249-258
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• 2007

In this study, the EPDM powder which was surface activated by high temperature and shear pulverization process was prepared and the mechanical properties and odor material analysis were investigated. Analysis for particle size and size distribution of waste of the EPDM powder has been performed. The waste EPDMs used in this study were 4 types of solid, sponge, solid+sponge, and solid+metal. According to the results, the solid type showed the smallest particle size among the 4 types of EPDM powder. Effective surface devulcanization of EPDM powder could be obtained by the addition of the reclaiming agent. The dicumyl peroxide was considered as the best crosslink agent for dynamic vulcanization when the surface activated EPDM powder was blended with polyolefin in order to make TPE. Also, the optimum amounts of DCP was 6 phr in terms of surface crosslink reaction and mechanical properties of EPDM powder. The processes of water adsorption and rose oil addition were employed to remove the odor of EPDM powder caused by reclaiming agent. The GC/MS was used to analyze the odor compounds.

• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.581-585
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• 2010

The surface of Alnico, one of the industrial dust waste, was treated with 1,3,5-trivinyl-1,3,5-trimethylcyclotrisilazane (VMS) as a surface treating agent and used as the filler for vibration isolator rubber. Maleated EPDM prepared from bulk polymerization of EPDM with maleic anhydride was copolymerized with ${\alpha},{\omega}$-bis(3-aminopropyl)polydimethylsiloxane to obtain maleated EPDM-polydimethylsiloxane copolymer (MEPDM-PDMS). EPDM/Alnico/MEPDM-PDMS vibration isolator rubber was prepared from compounding with Alnico treated with surface treating agent, 25 and 50 phrs to EPDM, respectvely based on 1 to 10 wt% of MEPDM-PDMS to EPDM. From the measurement of the thermal properties to the rubber, the glass transition temperatures (Tg) for the rubber containing maleated EPDM-PDMS copolymer was slightly lower temperature, $33^{\circ}C$ than EPDM rubber, and also DMA results showed higher tan ${\delta}$ peak to the rubber prepared from compounding with EPDM-PDMS copolymer. From the results, rubber prepared using EPDM-PDMS copolymer had better vibration isolator property.

• Elastomers and Composites
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• v.50 no.4
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• pp.245-250
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• 2015

Recycling of ethylene-propylene-diene terpolymer (EPDM) scrap was tried by blending with polypropylene (PP). EPDM scrap powder was prepared by shear pulverization process at high temperature, which may lead to selective chain scission induced by difference in the critical elastic coefficient. On the other hand, EPDM scrap powder was prepared by adding a selected reclaiming agent during shear pulverization process at high temperature. Terpene as a bonding agent was then introduced to improve adhesion property. PP, used as a matrix for manufacturing thermoplastic elastomer, was modified by the incorporation of dicumyl peroxide and maleic anhydride. The functionalized EPDM and modified PP were blended and cured dynamically at $190^{\circ}C$. The blend materials prepared in this study showed the comparable results to those of conventional TPE in terms of tensile and flow properties. Also, the odor component of recycled EPDM was analyzed using GC-MS.

• International Journal of Highway Engineering
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• v.12 no.4
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• pp.87-92
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• 2010

This study evaluates the laboratory properties of asphalt binder and mixture modified with R-EPDM(Recycling Ethylene Propylene Dien Monometer), which consists of R-EPDM as a main ingredient that is an industrial by-product made by manufacturing waste EPDM below 50 mesh as an additive. Superpave system was used to determine the PG(Performane Grade) and evaluate the property of R-EPDM modified binder. OACs(Optimum Asphalt Contents) of R-EPDM modified asphalt mixtures were determined by Superpave mix design using gyratory compactor and wheel tracking test and moisture susceptibility test were carried out with R-EPDM modified asphalt mixtures at OACs. The results from these tests, rutting-resistance and freezing and thawing resistance by moisture susceptibility of R-EPDM modified asphalt mixtures were superior to one of general asphalt mixtures(AP-5).

• Resources Recycling
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• v.9 no.3
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• pp.46-53
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• 2000

Recently, the efficient disposal of the waste rubber is necessary due to increasing amount of the waste rubbers. In this paper, method of recycling waste rubbers as components of medium for hydroponic rose culture was suggested. We investigated growth of rose, and macro- and micro-elements, pH and EC of the media amended with waste rubber, In the beginning of culture, stress symptoms such as thin brittle stem and incipient wilting were observed, but they disappeared in a few weeks. Concentration of $Zn^{2+}$ in media at flowering increased in proportion to contents of waste tire in the media. pH of media at flowering were in the range of 5.70 to 6.35. Rose growth in all media, except in wasterock wool mixed with EPDM powder at 9:3 ratio, was normal and equivalent to the control in terms of stem length, number of stems harvested and fresh weight.

• Clean Technology
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• v.15 no.3
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• pp.172-179
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• 2009

The thermoplastic polyurethane waste (TPU-S) with good tensile properties, hardness, NBS abrasion resistance, specific gravity and low wet coefficient of kinetic friction was melt-blended with ethylene propylene diene monomer rubber (EPDM) with high wet slip resistance and low mechanical properties to form EPDM/TPU-S blend films, and their composition-property relationship was investigated to find the optimum composition for shoe outsole material. The properties except the wet slip resistance increased with increasing TPU-S contents in the blend. All the properties except elongation at break, specific gravity and the wet coefficient of kinetic friction in the range of $0{\sim}65\;wt%$ of TPU-S did not attain the values predicted by the simple additive rule. The optimum weight ratio of EPDM/TPU-S for the application to the typical shoe outsole material was found to be 30/70.

• Proceedings of the Korean Institute of Resources Recycling Conference
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• 2002.05a
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• pp.163-164
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• 2002