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Cu-W 전극의 DC Arc 시험에 있어서 Nickel 첨가 영향 (Effect of Nickel addition in DC arc test of Cu-W electrode)

  • 김봉서;정현욱;이희웅
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 유기절연재료 방전 플라즈마연구회
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    • pp.11-14
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    • 2003
  • Sintered Cu-W has been used for the electrode of GIS for interrupting the abnormal current. In this study the effect of Ni addition in Cu-W electrode was investigated. Cu-W electrodes used contains 0.1~0.2wt% Ni and were conducted the experiments which was attacked by DC arc test (70V-70A) for 300 times periodically. As the contents of Ni in Cu-W electrode increase, the hardness and electrical conductivity were decreased. The weight change ($\Delta$mg) of electrode after DC arc test increased with increasing Ni contents and test times. The hardness and electrical conductivity of electrode after DC arc test were decreased compared with non-arc affected electrode, which was owing to the defects near surface of electrode and degradation by arc heat. It was considered that Cu in the Cu-W electrode was scattered to all directions by arc heat, therefore, the electrodes were damaged and deformed in the surface and cross-section of electrode. It is difficult to estimate directly the characteristics of Cu-W electrode for GIS related with high voltage and current from the results of DC arc test conducted in this study. However, the results of the effect of Ni addition in Cu-W electrode could be applied for the research of electrode for GIS.

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W-USB를 위한 NFC Handover 기술 (NFC Handover Technology for W-USB)

  • 한영선;김태선
    • 정보처리학회논문지A
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    • 제17A권3호
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    • pp.137-144
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    • 2010
  • 최근 모바일 장치 시장이 급격히 성장하면서 모바일 장치의 기능성 또한 빠르게 발전하고 있다. 소비자는 모든 환경에서 이기종 모바일 장치간 데이터 전송 또는 무선 인터넷을 통한 멀티미디어 데이터 전송이 가능하기를 원한다. 이와 더불어, 단일 모바일 장치가 블루투스, 와이파이(Wi-Fi), W-USB, NFC와 같은 다양한 connectivity 기술을 채용하는 경향도 보인다. 이와 같은 시장의 흐름에 따라 이기종간 association 기술의 중요성이 점차 부각되고 있다. 본 논문은 기존 NFC handover 프로토콜을 확장하여 W-USB 기술의 NFC association을 지원하는 방법을 다룬다. 또, W-USB 기술의 NFC association 표준과 NFC handover 프로토콜 간의 차이점을 설명하고 기존 NFC handover 프로토콜을 확장하여 이를 해결할 수 있는 방법을 제시한다. 마지막으로 본 논문은 W-USB handover 프로토콜 지원을 위한 NFC 시스템 구현에 대해 기술한다.

중성자 회절법에 의한 Ni-W 합금 소결체의 격자상수 측정 (Estimation of a Lattice Parameter of Sintered Ni-W Alloy Rods by a Neutron Diffraction Method)

  • 김찬중;김민우;박순동;전병혁;장석원;성백석
    • 한국분말재료학회지
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    • 제15권3호
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    • pp.239-243
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    • 2008
  • Ni-W(1-5 at.%) alloy rods were made by powder metallurgy process including powder mixing, compacting and subsequent sintering. Ni and W powder of appropriate compositions were mixed by a ball milling and isostatically pressed in a rubber mold into a rod. The compacted rods were sintered at $1000^{\circ}C-1150^{\circ}C$ at a reduced atmosphere for densification. The lattice parameters of Ni-W alloys were estimated by a high resolution neutron powder diffractometer. All sintered rods were found to have a face centered cubic structure without any impurity phase, but the diffraction peak locations were linearly shifted with increasing W content. The lattice parameter of a pure Ni rod was $3.5238{\AA}$ which is consistent with the value reported in JCPDS data. The lattice parameter of N-W alloy rods increased by $0.004{\AA}$ for 1 atomic % of W, which indicates the formation of a Ni-W solid solution due to the substitution of nickel atoms by tungsten atoms of larger size.

한국과 캐나다산 치즈중 PCBs의 농도 특성 (PCBs concentration patterns in Korean and Canadan cheese)

  • 천만영;김태욱
    • 한국환경농학회지
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    • 제24권2호
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    • pp.139-145
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    • 2005
  • 한국과 캐나다에서 생산된 우유로 제조된 치즈를 슈퍼마켓에서 구매하여(한국 5종, 캐나다 10종) 치즈에 포함된 총 209 PCBs congener 농도와 homologue별 농도 양상을 연구하였다. 한국과 캐나다산 치즈중 PCBs 총농도는 각각 299.81과 200.96(pg/g w.w.)으로 한국산 치즈중 PCBs 농도가 캐나다산 치즈보다 1.5배 더 높았다. 그러나 TEQ 농도는 한국산과 캐나다산이 각각 0.0067과 0.0064(pg-TEQ/g w.w.)으로 거의 같았으며, PCDD/Fs는 전혀 검출이 되지 않았다. 한국과 캐나다산 치즈에서 검출된 PCBs와 PCDD/Fs 농도는 세계 다른 지역에서 제조된 치즈중 농도보다 훨씬 낮았다. 두 나라의 치즈에서 검출된 PCBs congener수는 한국산이 93종, 캐나다산이 83종으로 한국산 치즈에서 10종 더 많은 PCBs congener가 검출되었다. 두 나라 치즈중 각 PCBs congener 농도에서 구한 회귀직선의 결정계수$(R^2)$는 0.752로 상관성이 커서 두 나라의 PCBs 발생원이 유사함을 알 수 있었고, 각 homologue별 농도 분포도 유사성이 컸다.

Phytase를 생산하는 Enterobacter cloacae의 분리 및 효소 생산의 배지 최적화 (Isolation of Enterobacter Cloacae Producing Phytase and Medium Optimization of Its Production)

  • 송민동;김영훈;양시용;김대영;김창원;정원형;권문남
    • 한국미생물·생명공학회지
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    • 제29권2호
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    • pp.78-83
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    • 2001
  • 본 연구는 phytic acid를 myo-inositol과 무기태인으로 분해시키는 효소인 phytase 생산균주의 분리 및 효소생산의 배지최적하에 관한 것이다. 1차로 calcium phytate를 기질로 함유한 phytase screening 배지를 이용하여 phytase 생산을 나타내는 균주 35가지를 이용하여 분리한 후, sodium phytate를 기질로 하여 재현성 있는 phytase 활성을 나타내는 균주 12가지를 선발하였다. 12개의 균주 중 BHI broth에서 배양한 조효소액의 phytase 활성이 가장 우수한 것으로 나타난 YH100을 선발하여 주사현미경 관찰, 16S rRNA sequence 분석, GC conten(mol%) 조성, 지방산 분석, API 20E kit를 이용한 test 결과 Enterobacter cloacae로 동정되어, 이 균주를 Enterobacter cloacae YH100이라 명명하였다. Enterobacter cloacae YH100에 의한 phytase 생산을 위한 최적 배지 조성을 파악한 결과 glucose 2.0%(w/v), peptone 1.0%(w/v), beef extract 1.0%(w/v), KCI 0.1%(w/v), sodium phytate 0.1%(w/v)로 나타났다.

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겔화에 의한 Water-in-Oil에멀젼의 안정성;이산화티타늄($TiO_{2}$)이 함유된 Sun-block Cream의 응용 (Stability of Water-in-Oil Emulsion by Gelation;Application of Sun-Block Cream containing Titanium Dioxide($TiO_{2}$))

  • 김인영
    • 한국응용과학기술학회지
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    • 제17권2호
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    • pp.67-75
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    • 2000
  • Cosmetic industries have recently developed sun-block products, which are composed of W/O or O/W emulsion system. It was very difficult for waterproofing product to show the stability in W/O emulsion with $TiO_{2}$. To enhance the stability of W/O emulsion, it needs to be combined with the water and oil soluble components as the gelling agents. The emulsifiers used in W/O were 3.0% of cetyl dimethicone copolyol, 2.0% of sorbitan sesquioleate as the basic emulsifiers, and 0.6% of quaternium-18 bentonite and 1.5% of dextrin palmitate as stabilizer were used. The content of titanium dioxide was optimized up to 8.0%. Titanium dioxide was used as the UV scattering powder coated with $Al_{2}O_{3}$(UV-sperse T40/TN). The sunscreen cream prepared with W/O emulsion system by using QB and DP showed higher stability than that of W/O emulsion system by using each QB and DP. W/O emulsion from Formula 3 for passing one year was very durable more than F1 and F2. Within W/O emulsion by observing F1, F2 and F3 for one year, F3 was more excellent than F2 and F3 when they were observed at RT, $4^{\circ}C$, $40^{\circ}C$, because F3 used the mixed QB and DP in W/O emulsion. The zeta potential for F1, F2, and F3 after one year were 21, 30 and 43, respectively. From these result F3 was found best stable emulsion. The in-vitro SPF value for F3 was 35 for the initial product at room temperature and also, the in-vitro SPF values of F3 was 32 for after one year. Finally, the mean in-vivo SPF value of 10 volunteers for F3 was 27.3 by the Korea cosmetic association made the rules of SPF.

Application of Pulsed Chemical Vapor Deposited Tungsten Thin Film as a Nucleation Layer for Ultrahigh Aspect Ratio Tungsten-Plug Fill Process

  • Jang, Byeonghyeon;Kim, Soo-Hyun
    • 한국재료학회지
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    • 제26권9호
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    • pp.486-492
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    • 2016
  • Tungsten (W) thin film was deposited at $400^{\circ}C$ using pulsed chemical vapor deposition (pulsed CVD); film was then evaluated as a nucleation layer for W-plug deposition at the contact, with an ultrahigh aspect ratio of about 14~15 (top opening diameter: 240~250 nm, bottom diameter: 98~100 nm) for dynamic random access memory. The deposition stage of pulsed CVD has four steps resulting in one deposition cycle: (1) Reaction of $WF_6$ with $SiH_4$. (2) Inert gas purge. (3) $SiH_4$ exposure without $WF_6$ supply. (4) Inert gas purge while conventional CVD consists of the continuous reaction of $WF_6$ and $SiH_4$. The pulsed CVD-W film showed better conformality at contacts compared to that of conventional CVD-W nucleation layer. It was found that resistivities of films deposited by pulsed CVD were closely related with the phases formed and with the microstructure, as characterized by the grain size. A lower contact resistance was obtained by using pulsed CVD-W film as a nucleation layer compared to that of the conventional CVD-W nucleation layer, even though the former has a higher resistivity (${\sim}100{\mu}{\Omega}-cm$) than that of the latter (${\sim}25{\mu}{\Omega}-cm$). The plan-view scanning electron microscopy images after focused ion beam milling showed that the lower contact resistance of the pulsed CVD-W based W-plug fill scheme was mainly due to its better plug filling capability.

Preparation of W-V functionally gradient material by spark plasma sintering

  • Tang, Yi;Qiu, Wenbin;Chen, Longqing;Yang, Xiaoliang;Song, Yangyipeng;Tang, Jun
    • Nuclear Engineering and Technology
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    • 제52권8호
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    • pp.1706-1713
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    • 2020
  • Functionally gradient material (FGM) is promisingly effective in mitigating the thermal stress between plasma facing materials (PFM) and structural materials. However, the corresponding research with respect to W/V FGM has not been reported yet. In this work, we firstly report the successful fabrication of W/V FGM by a combined technology of mechanical alloying (MA) and spark plasma sintering (SPS). The microhardness and microstructure of the consolidated sample were both investigated. W/V stacks show significantly enhanced microhardness (>100%) compared with pure W plate, which is beneficial to the integral strength of the hybrid structure. Furthermore, we clarify that the different ductility of W and V should be carefully considered, otherwise W/V powder might aggregate and lead to the formation of compositional segregation, and simultaneously unmask the impact of V proportion on the distribution of second phase in W-V binary alloy system. This work provides an innovative approach for obtaining W-V connections with much better performance.

1kW 고체산화물 연료전지(SOFC) 시스템 설계 및 자열운전 (Design and Self-sustainable Operation of 1 kW SOFC System)

  • 이태희;최진혁;박태성;유영성;남석우
    • 한국수소및신에너지학회논문집
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    • 제20권5호
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    • pp.384-389
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    • 2009
  • KEPRI (Korea Electric Power Research Institute) has studied planar type solid oxide fuel cell (SOFC) stacks using anode-supported cells and kW class co-generation systems for residential power generation. In this work, a 1 kW SOFC system consisted of a hot box part, a cold BOP (balance of plant) part, and a hot water reservoir. The hot box part contained a SOFC stack made up of 48 cells, a fuel reformer, a catalytic combustor, and heat exchangers. Thermal management and insulation system were especially designed for self-sustainable operation in that system. A cold BOP part was composed of blowers, pumps, a water trap, and system control units. When the 1 kW SOFC stack was tested using hydrogen at $750^{\circ}C$, the stack power was about $1.2\;kW_e$ at 30 A and $1.6\;kW_e$ at 50 A. Turning off an electric furnace, the SOFC system was operated using hydrogen and city gas without any external heat source. Under self-sustainable operation conditions, the stack power was about $1.3\;kW_e$ with hydrogen and $1.2\;kW_e$ with city gas respectively. The system also recuperated heat of about $1.1\;kW_{th}$ by making hot water.

5세대 이동통신을 위한 FBMC와 UFMC 시스템의 비선형 특성 평가 (Nonlinear Characteristics Evaluation of the FBMC and UFMC System for the 5G Mobile Communication)

  • 안창영;유흥균
    • 한국전자파학회논문지
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    • 제27권8호
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    • pp.725-734
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    • 2016
  • 5세대 이동통신 시스템에서 스펙트럼 효율을 향상시키기 위한 새로운 후보 변조기술들이 제안되고 있다. 후보 변조기술로 다중반송파 기반의 UFMC(Universal Filtered Multi-Carrier), FBMC(Filter Bank Multi-Carrier)가 큰 주목을 받고 있으며, 최근 저복잡도 처리가 가능한 W(Weighted)-OFDM(Orthogonal Frequency Division Multiplexing) 시스템 또한 주목받고 있다. 본 논문에서는 기본적인 OFDM 시스템과 함께 UFMC, FBMC, W-OFDM 시스템에 HPA(High Power Amplifier) 비선형 특성이 고려되었을 경우, 각 시스템의 스펙트럼 특성과 BER(Bit Error Rate) 특성을 종합적으로 평가하여 보다 유력한 시스템을 찾는다. 시뮬레이션 결과로, 동일한 비선형 HPA 환경에서는 UFMC, FBMC, W-OFDM 시스템이 모두 유사한 스펙트럼 특성과 BER 특성을 보이는 것을 확인할 수 있다. 이러한 이유로 비선형 HPA 환경에서는 시간영역에서 저복잡도의 Windowing 처리만을 요구하는 W-OFDM 시스템이 다른 시스템에 비하여 유리함을 확인할 수 있다.