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Underwater Stability of Surface Chemically Modified Superhydrophobic W18O49 Nanowire Arrays

  • Lee, Junghan;Yong, Kijung
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.601-601
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    • 2013
  • Superhydrophobic W18O49 nanowire (NW) arrays were synthesizedusing a thermal evaporation and surface chemistry modification methods by self-assembled monolayer (SAM). As-prepared non-wetting W18O49 NWs surface shows water contact angle of $163.2^{\circ}$ and has reliable stability in underwater conditions. Hence the superhydrophobic W18O49 NWs surface exhibits silvery surface by total reflection of water layer and air interlayer. The stability analysus of underwater superhydrophobicity of W18O49 NWs arrays was conducted by changing hydrostatic pressure and surface energy of W18O49 NWs arrays. The stability of superhydrophobicity in underwater conditions decreased exponentially as hydrostatic pressure applied to the substrates increased3. In addition, as surface energy decreased, the underwater stability of superhydrophobic surface increased sharply. Specifically, sueprhydrophobic stability increased exponentially as surface energy of W18O49 NWs arrays was decreased. Based on these results, the models for explaining tendencies of superhydrophobic stability underwater resulting from hydrostatic pressure and surface energy were designed. The combination of fugacity and Laplace pressure explained this exponential decay of stability according to hydrostatic pressure and surface energy. This study on fabrication and modeling of underwater stability of superhydrophobic W18O49 NW arrays will help in designing highly stable superhydrophobic surfaces and broadening fields of superhydrophobic applications even submerged underwater.

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전해도금에 의한 Ni-W 합금의 내식성 및 표면 전도도 특성 연구 (A Study on Corrosion Resistance and Electrical Surface Conductivity of an Electrodeposited Ni-W Thin Film)

  • 박제식;정구진;김영준;김기재;이철경
    • 한국표면공학회지
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    • 제44권2호
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    • pp.68-73
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    • 2011
  • A Ni-W thin-film was synthesized by electrodeposition, and its corrosion resistance and electrical surface conductivity were investigated. Amount of tungsten in the Ni-W thin-film increased linearly with current density during the electrodeposition, and crack-free and low-crystalline Ni-21 at.%W coating layer was obtained. Corrosion resistances of the Ni-W thin-films were examined with an anodic polarization method and a storage test in a strong sulfuric acid solution. As a result, the Ni-21 at.%W thin-film exhibited the greatest corrosion resistance, and maintained the electrical surface conductivity even after the severe corrosion test, which could be applicable as a surface treatment for advanced metallic bipolar plates in fuel cell or redox flow battery systems.

SPS/용침 공정에 의한 W-Cu연속경사기능재료의 제초와 특성 (Fabrication and Characteristics of Continuous W-Cu FGM by SPS/Infiltration Process)

  • 신철균;석명진;오승탁;김지순;권영순
    • 한국분말재료학회지
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    • 제11권2호
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    • pp.158-164
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    • 2004
  • W-Cu composite has been used for the applications requiring both high strength, good thermal and electrical conductivity. A graded combination of W and Cu will reduce thermal stress concerned with heat conduction, maintaining good thermal conductivity and high mechanical strength. In the present work, an attempt was made to fabricate continuous W-Cu FGM by preparing the graded porous structure of W skeleton using spark plasma sintering (SPS) process followed by infiltrating Cu. The graded porous structure was prepared at 150$0^{\circ}C$ for 60s under pressure of 15MPa by SPS process using a graphite mold with varying crr)ss section in the longitudinal direction. Infiltration of Cu was performed at 115$0^{\circ}C$ for 1 hour under $H_2$. W-Cu composite with graded Cu composition of 14 to 27 wt% was finally prepared. In this process the gradient of composition could be conveniently controlled by varying the gradient of cross sectional area of graphite mold, temperature and pressure.

6kW 독립형 풍력발전기의 진동 모니터링 및 분석 (Vibration Monitoring and Analysis of a 6kW Wind Stand Alone Turbine Generator)

  • 김석현;남윤수;유능수;이정완;박무열;박해균;김태형
    • 산업기술연구
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    • 제25권A호
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    • pp.81-86
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    • 2005
  • A vibration monitoring system for a small class of wind turbine (W/T) is established and operated. The monitoring system consists of monolithic integrated chip accelerometer for vibration monitoring, anemometers for wind data acquisition and auxiliary sensors for atmospheric data. Using the monitoring system, vibration response of a 6kW W/T generator is investigated. Acceleration data of the W/T tower under various operation condition is acquired in real time using LabVIEW and is remotely transferred from the test site to the laboratory in school by internet. Vibration state of the tower structure is diagnosed within the operating speed range. Resonance frequency range of the test model is investigated with the wind speed data of the test site.

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와이퍼 블레이드 고무의 표면 처리에 따른 특성 (The Characteristics of Wiper Blade Rubber with Surface Treatments)

  • 노승백;임미애;박진규;손전익
    • Elastomers and Composites
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    • 제33권1호
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    • pp.27-36
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    • 1998
  • The surface of wiper blade(W/B) rubber was chlorinated by chemical treatment method using the hydrochloric acid(HCI) and sodium hypochlorite(NaOCl). From the results of contact angle measurement, friction coefficient measurement, and ATR-IR spectra, the surface characteristics of chlorinated W/B rubber with time of chlorination were studied. Contact angles for W/B rubber with increasing time of chlorination and chlorine concentration were measured for the water and ethylene glycol. From the results, contact angle fell rapidly with increasing time of chlorination and chlorine concentration, reaching a constant value after about 10min. And the wettability of W/B rubber surface by means of chlorination has been improved. For an unchlorinated W/B rubber, the friction coefficient with time of chlorination decreased from 1.27 to 0.20~0.23 on full chlorination. As the results it was considered that abrasion resistance of W/B rubber surface has been also improved. The values of pH and $Cl^-$ ion concentration in a chlorine treatment solution decreased as the extent of chlorination of W/B rubber surface increased. From the results of ATR-IR spectra, it was observed that C=C double band of W/B rubber surface transformed into C-Cl band, but quantitative determination of the extent of chlorination was not feasible because of the complexity of chlorination reactions.

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전북대학교 소재공정용 60kW 및 200kW ICP(RF) 플라즈마 발생 장치 구축 현황 (Chonbuk National University 60kW and 200kw ICP(RF) Plasma systems for Advance Material processing)

  • 이미연;김정수;서준호;최성만;홍봉근
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2010년도 제35회 추계학술대회논문집
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    • pp.781-783
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    • 2010
  • 전북대학교 고온 플라즈마 응용 연구 센터 구축사업단은 교육과학기술부 기초연구사업 중 고가연구장비 구축사업을 통하여 고부가가치 재료 연구 및 시험생산이 가능한 소재공정용 60kW 와 200kW ICP(RF) 플라즈마 발생장치를 구축하고 있다. 나노분말소재의 합성과 플라즈마 용사 코팅이 가능한 대형 ICP(RF) 플라즈마 장치 구축을 통하여 차세대 전자 부품 소재의 개발 및 고온 플라즈마 기술의 산업화에 이바지 하고자 한다.

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Bacillus subtilis SRCM100757를 이용하여 접종농도와 발효기간을 달리하여 제조한 청국장의 품질 특성 및 Vitamin K2(MK-7) 생성능 평가 (Quality Characteristics and Vitamin K2 (MK-7) Productivity of Cheonggukjang fermented by Bacillus subtilis SRCM100757 with Different Inoculum Concentrations and Fermentation Time)

  • 정민홍;방선옥;김금숙
    • 동아시아식생활학회지
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    • 제27권3호
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    • pp.341-347
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    • 2017
  • This study was carried out to investigate the characteristics and Vitamin $K_2$ (MK-7) productivity of Cheonggukjang fermented by Bacillus subtilis SRCM100757 depending on the inoculum concentration 0.5% (v/w), 1% (v/w) and 2% (v/w). The lowest moisture content and water activity were $53.7{\pm}0.6%$ and $8.39{\pm}0.09$ after fermentation for 72 hours at 2% (v/w). pH slowly became alkalized during fermentation, but there was no significant difference. Amino nitrogen content increased with time and the highest content was $580.8{\pm}1.9mg%$ after fermentation for 72 hours at 2% (v/w). Lightness (L value) and yellowness (b value) decreased with time, whereas redness (a value) hardly changed. MK-7 contents increased with time at each inoculum concentration. The highest content was $20.47{\pm}1.53$ after fermeatation for 72 hours at 2%(v/w) and there were no significant differences between 1%(v/w) and 2%(v/w) inoculum concentrations.

동충하초를 이용한 코오지의 발효특성 (Fermentation Characteristics of Koji inoculated with Cordyceps sp.)

  • 권동진
    • 한국미생물·생명공학회지
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    • 제30권1호
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    • pp.46-50
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    • 2002
  • 일반 상법으로 제조되는 코오지, 즉 밀 또는 대두에 A. oryzae만으로 제조하는 코오지에 Cordyceps sp.를 첨가하여 코오지의 품질에 미치는 영향을 조사하였다. A. oryzae만으로 제조하는 코오지에 Cordyceps sp.를 일정량 혼합 첨가하여 제국하여 생균수 및 포자수를 측정한 결과 48시간까지 급격히 증가했다. 이후 생균수 및 곰팡이의 포자수의 유의할만한 변화를 볼 수 없어 제국시간을 48시간 전후로 조정하는 것이 바람직한 것으로 나타났다. 또한 amylase 및 protease등의 효소역가를 측정한 결과 Cordyceps sp.를 첨가한 코오지가 Cordyceps sp.를 첨가하지 않은 코오지보다 효소역가가 높은 것으로 나타났다. 제국이 끝난 코오지에 대하여 맛, 향 및 색깔에 대하여 관능검사를 실시한 결과 A. oryzae와 Cordyceps sp.를 각각 0.5%(w/w)를 혼합 참가한 것이 더 좋게 나타났다.

Influence of some additives on the process of Ni-W alloy electroplating

  • Wu, Yi-Yong;Kim, Dong-Soo;Chang, Do-Yon;Kwon, Sik-Chol
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2001년도 추계학술발표회 초록집
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    • pp.56-56
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    • 2001
  • Ni-W alloy deposit is one of the best alternatives to hard chromium plating because of its good mechanical properties (high hardness, high strength, and good wear resistance). Ni-W alloy is deposited from weakly acidic or alkaline electrolytic bath with nickel sulfate, sodium tungstate or APT, and some kinds of organic hydroxy-acid complex and ammonia salts. W content of the deposit can be changed from 0 to 5Owt% and the coating with high W content is more attracted. But, meanwhile, the deposited layers are always found high internal stress, which cause them to become brittle and to bond insufficiently with the substrate. On the second hand, as the W content is incresed, the current efficiency reduced, which results in large quantities of hydrogen evolution and then produces bubbles on surface and pitting appearance In this paper, the influence of some additives on Ni-W alloy electroplating was investigated by means of compositional analysis and SEM. The initial results showed that 2-butyne-1,4-diol was the best brightener for Ni-W plating process. It could brighten and level deposit, but decreased the cathodic current efficiency. Its optimum concentration range is from O.lgjL to 0.5gjL. Besides, three kinds of additives including 2-butyne-1,4-diol were examined with Dagguchi method.

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S/W관리 TLB의 초기접근실패 감소 기법 (The Reducting Technique of compulsory Misses for S/W managed TLB)

  • 박장석
    • 한국정보처리학회논문지
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    • 제5권3호
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    • pp.620-632
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    • 1998
  • 본 논문에서는 S/w 관리 TLB(Translation Lookaside Buffer)의 실패 패널티를 감소시키기 위하여 사용될 TLB 엔트리를 선인출하여 S/W관리 TLB의 초기 접근 실패를 감소시키는 새로운 기법을 제시한다. 이 방법은 특별한 응용 프로그램에만 동작하는 것은 아니다. 제안하는 방법의 핵심은 임의의 페이지에 대한 첫 번째의 TLB 접근 전에 선인출 명령어를 수행하여 TLB 실패 분류법을 제안하고, 이를 이용한 알고리즘과 구현방법을 기술하며, 정량적인 분석에 의해 제안한 기법이 S/W 관리 TLB의 성능 향상을 위한 유효한 기법임을 보인다. 또 제안한 방법이 S/W 관리 TLB에서 버스 트래픽을 감소시키는 부가적인 장점에 대해 논한다.

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