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Underwater Stability of Surface Chemically Modified Superhydrophobic W18O49 Nanowire Arrays

  • Lee, Junghan;Yong, Kijung
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.601-601
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    • 2013
  • Superhydrophobic W18O49 nanowire (NW) arrays were synthesizedusing a thermal evaporation and surface chemistry modification methods by self-assembled monolayer (SAM). As-prepared non-wetting W18O49 NWs surface shows water contact angle of $163.2^{\circ}$ and has reliable stability in underwater conditions. Hence the superhydrophobic W18O49 NWs surface exhibits silvery surface by total reflection of water layer and air interlayer. The stability analysus of underwater superhydrophobicity of W18O49 NWs arrays was conducted by changing hydrostatic pressure and surface energy of W18O49 NWs arrays. The stability of superhydrophobicity in underwater conditions decreased exponentially as hydrostatic pressure applied to the substrates increased3. In addition, as surface energy decreased, the underwater stability of superhydrophobic surface increased sharply. Specifically, sueprhydrophobic stability increased exponentially as surface energy of W18O49 NWs arrays was decreased. Based on these results, the models for explaining tendencies of superhydrophobic stability underwater resulting from hydrostatic pressure and surface energy were designed. The combination of fugacity and Laplace pressure explained this exponential decay of stability according to hydrostatic pressure and surface energy. This study on fabrication and modeling of underwater stability of superhydrophobic W18O49 NW arrays will help in designing highly stable superhydrophobic surfaces and broadening fields of superhydrophobic applications even submerged underwater.

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A Study on Corrosion Resistance and Electrical Surface Conductivity of an Electrodeposited Ni-W Thin Film (전해도금에 의한 Ni-W 합금의 내식성 및 표면 전도도 특성 연구)

  • Park, Je-Sik;Jeong, Goo-Jin;Kim, Young-Jun;Kim, Ki-Jae;Lee, Churl-Kyoung
    • Journal of the Korean institute of surface engineering
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    • v.44 no.2
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    • pp.68-73
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    • 2011
  • A Ni-W thin-film was synthesized by electrodeposition, and its corrosion resistance and electrical surface conductivity were investigated. Amount of tungsten in the Ni-W thin-film increased linearly with current density during the electrodeposition, and crack-free and low-crystalline Ni-21 at.%W coating layer was obtained. Corrosion resistances of the Ni-W thin-films were examined with an anodic polarization method and a storage test in a strong sulfuric acid solution. As a result, the Ni-21 at.%W thin-film exhibited the greatest corrosion resistance, and maintained the electrical surface conductivity even after the severe corrosion test, which could be applicable as a surface treatment for advanced metallic bipolar plates in fuel cell or redox flow battery systems.

Fabrication and Characteristics of Continuous W-Cu FGM by SPS/Infiltration Process (SPS/용침 공정에 의한 W-Cu연속경사기능재료의 제초와 특성)

  • 신철균;석명진;오승탁;김지순;권영순
    • Journal of Powder Materials
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    • v.11 no.2
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    • pp.158-164
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    • 2004
  • W-Cu composite has been used for the applications requiring both high strength, good thermal and electrical conductivity. A graded combination of W and Cu will reduce thermal stress concerned with heat conduction, maintaining good thermal conductivity and high mechanical strength. In the present work, an attempt was made to fabricate continuous W-Cu FGM by preparing the graded porous structure of W skeleton using spark plasma sintering (SPS) process followed by infiltrating Cu. The graded porous structure was prepared at 150$0^{\circ}C$ for 60s under pressure of 15MPa by SPS process using a graphite mold with varying crr)ss section in the longitudinal direction. Infiltration of Cu was performed at 115$0^{\circ}C$ for 1 hour under $H_2$. W-Cu composite with graded Cu composition of 14 to 27 wt% was finally prepared. In this process the gradient of composition could be conveniently controlled by varying the gradient of cross sectional area of graphite mold, temperature and pressure.

Vibration Monitoring and Analysis of a 6kW Wind Stand Alone Turbine Generator (6kW 독립형 풍력발전기의 진동 모니터링 및 분석)

  • Kim, Seock-Hyun;Nam, Yoon-Su;Yoo, Neung-Soo;Lee, Jeong-Wan;Park, Mu-Yeol;Park, Hae-Gyun;Kim, Tae-Hyeong
    • Journal of Industrial Technology
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    • v.25 no.A
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    • pp.81-86
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    • 2005
  • A vibration monitoring system for a small class of wind turbine (W/T) is established and operated. The monitoring system consists of monolithic integrated chip accelerometer for vibration monitoring, anemometers for wind data acquisition and auxiliary sensors for atmospheric data. Using the monitoring system, vibration response of a 6kW W/T generator is investigated. Acceleration data of the W/T tower under various operation condition is acquired in real time using LabVIEW and is remotely transferred from the test site to the laboratory in school by internet. Vibration state of the tower structure is diagnosed within the operating speed range. Resonance frequency range of the test model is investigated with the wind speed data of the test site.

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The Characteristics of Wiper Blade Rubber with Surface Treatments (와이퍼 블레이드 고무의 표면 처리에 따른 특성)

  • Rho, Seung-Baik;Lim, Mi-Ae;Park, Jin-Kyu;Son, Jeon-Ik
    • Elastomers and Composites
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    • v.33 no.1
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    • pp.27-36
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    • 1998
  • The surface of wiper blade(W/B) rubber was chlorinated by chemical treatment method using the hydrochloric acid(HCI) and sodium hypochlorite(NaOCl). From the results of contact angle measurement, friction coefficient measurement, and ATR-IR spectra, the surface characteristics of chlorinated W/B rubber with time of chlorination were studied. Contact angles for W/B rubber with increasing time of chlorination and chlorine concentration were measured for the water and ethylene glycol. From the results, contact angle fell rapidly with increasing time of chlorination and chlorine concentration, reaching a constant value after about 10min. And the wettability of W/B rubber surface by means of chlorination has been improved. For an unchlorinated W/B rubber, the friction coefficient with time of chlorination decreased from 1.27 to 0.20~0.23 on full chlorination. As the results it was considered that abrasion resistance of W/B rubber surface has been also improved. The values of pH and $Cl^-$ ion concentration in a chlorine treatment solution decreased as the extent of chlorination of W/B rubber surface increased. From the results of ATR-IR spectra, it was observed that C=C double band of W/B rubber surface transformed into C-Cl band, but quantitative determination of the extent of chlorination was not feasible because of the complexity of chlorination reactions.

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Chonbuk National University 60kW and 200kw ICP(RF) Plasma systems for Advance Material processing (전북대학교 소재공정용 60kW 및 200kW ICP(RF) 플라즈마 발생 장치 구축 현황)

  • Lee, Mi-Yeon;Kim, Jeong-Soo;Seo, Jun-Ho;Choi, Seong-Man;Hong, Bong-Guen
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.11a
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    • pp.781-783
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    • 2010
  • Chonbuk national university High-enthalpy plasma research center is under construction for 60kW and 200kw ICP(RF) Plasma system as Advance Material R&D and production equipment. The 60kW & 200kW ICP(RF) plasma systems will contribute to promote Korea's material industrial development and Thermal plasma technology.

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Quality Characteristics and Vitamin K2 (MK-7) Productivity of Cheonggukjang fermented by Bacillus subtilis SRCM100757 with Different Inoculum Concentrations and Fermentation Time (Bacillus subtilis SRCM100757를 이용하여 접종농도와 발효기간을 달리하여 제조한 청국장의 품질 특성 및 Vitamin K2(MK-7) 생성능 평가)

  • Jeong, Min-Hong;Bang, Seon-Ok;Kim, Kum-Suk
    • Journal of the East Asian Society of Dietary Life
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    • v.27 no.3
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    • pp.341-347
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    • 2017
  • This study was carried out to investigate the characteristics and Vitamin $K_2$ (MK-7) productivity of Cheonggukjang fermented by Bacillus subtilis SRCM100757 depending on the inoculum concentration 0.5% (v/w), 1% (v/w) and 2% (v/w). The lowest moisture content and water activity were $53.7{\pm}0.6%$ and $8.39{\pm}0.09$ after fermentation for 72 hours at 2% (v/w). pH slowly became alkalized during fermentation, but there was no significant difference. Amino nitrogen content increased with time and the highest content was $580.8{\pm}1.9mg%$ after fermentation for 72 hours at 2% (v/w). Lightness (L value) and yellowness (b value) decreased with time, whereas redness (a value) hardly changed. MK-7 contents increased with time at each inoculum concentration. The highest content was $20.47{\pm}1.53$ after fermeatation for 72 hours at 2%(v/w) and there were no significant differences between 1%(v/w) and 2%(v/w) inoculum concentrations.

Fermentation Characteristics of Koji inoculated with Cordyceps sp. (동충하초를 이용한 코오지의 발효특성)

  • 권동진
    • Microbiology and Biotechnology Letters
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    • v.30 no.1
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    • pp.46-50
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    • 2002
  • To investigate the quality of Koji produced by Cordyceps sp., a mixed culture of Aspergillus oryzae and the Cordyceps sp. were inoculated in Koji making. Viable cell counts and counts of fungi spore during Koji making for 120 hours were increased rapidly within 24-48 hours, after then their changes were not shown significantly during Koji making. The activities of amylase and protease in Koji inoculated with the mixed culture of A. oryzae and Cordyceps sp. were superior to one with A. oryzae only. The sensory evaluation on the Koji with 0.5% (w/w) A. oryzae and 0.5% (w/w) Cordyceps sp. were evaluated to be superior to ones. The best quality of Koji is prepared from the mixture of Cordyceps sp. and A. oryzae with the ratio of 0.5% and 0.5% (w/w).

Influence of some additives on the process of Ni-W alloy electroplating

  • Wu, Yi-Yong;Kim, Dong-Soo;Chang, Do-Yon;Kwon, Sik-Chol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2001.11a
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    • pp.56-56
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    • 2001
  • Ni-W alloy deposit is one of the best alternatives to hard chromium plating because of its good mechanical properties (high hardness, high strength, and good wear resistance). Ni-W alloy is deposited from weakly acidic or alkaline electrolytic bath with nickel sulfate, sodium tungstate or APT, and some kinds of organic hydroxy-acid complex and ammonia salts. W content of the deposit can be changed from 0 to 5Owt% and the coating with high W content is more attracted. But, meanwhile, the deposited layers are always found high internal stress, which cause them to become brittle and to bond insufficiently with the substrate. On the second hand, as the W content is incresed, the current efficiency reduced, which results in large quantities of hydrogen evolution and then produces bubbles on surface and pitting appearance In this paper, the influence of some additives on Ni-W alloy electroplating was investigated by means of compositional analysis and SEM. The initial results showed that 2-butyne-1,4-diol was the best brightener for Ni-W plating process. It could brighten and level deposit, but decreased the cathodic current efficiency. Its optimum concentration range is from O.lgjL to 0.5gjL. Besides, three kinds of additives including 2-butyne-1,4-diol were examined with Dagguchi method.

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The Reducting Technique of compulsory Misses for S/W managed TLB (S/W관리 TLB의 초기접근실패 감소 기법)

  • Park, Jang-Suk
    • The Transactions of the Korea Information Processing Society
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    • v.5 no.3
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    • pp.620-632
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    • 1998
  • This paper introduces a new teehniquc for reducing the compulsory misses of software-managed TLBs by prefetching necessary TLB entries before being used. This technique is not inherently limited to specific applications. The key of this scheme is to perform the prefetch operations to update the TLB entries before first accesses so that TLB misses can be avoided. For the identifications of the prefctch pages, the new classification is introduced, which is based 0n the view of an object code execution. Then, the algorithms and the implementation technique arc described. Using a quantitative analysis, the proposed scheme is evaluated to prove that it is a useful technique for the perronnall~~ ~nhan~"ment of the S/W managed TLBs. in addition, it is discussed that reducing the miss rate by the prefeteh scheme reduces the total miss penalty and bus traffics in S/W-managed TLBs.

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