• Korean Chemical Engineering Research
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• 제55권5호
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• pp.668-678
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• 2017

Intermolecular interactions were studied for binary mixtures of 2-propanol + cyclohexane, n-hexane, benzene, toluene, o-, m- and p-xylenes by measuring ultrasonic speeds (u) over the entire range of composition at 298.15 K and 308.15 K. From these results the deviation in ultrasonic speed was calculated. These results were fitted to the Redlich-Kister equation to derive the binary coefficients along with standard deviations between the experimental and calculated data. Acoustic parameters such as excess isentropic compressibility ($K_s^E$), intermolecular free length ($L_f$) and available volume ($V_a$) were also derived from ultrasonic speed data and Jacobson's free length theory. The ultrasonic speed data were correlated by Nomoto's relation, Van Dael's mixing relation, impedance dependence relation, and Schaaff's collision factor theory. Van Dael's relation gives the best prediction of u in the binary mixtures containing aliphatic hydrocarbons. The ultrasonic speed data and isentropic compressibility were further analyzed in terms of Jacobson's free length theory.

• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1686-1692
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• 2012

Densities (${\rho}$), Viscosities (${\eta}$) and ultrasonic speeds (u) of pure acetophenone (AP), propiophenone (PP), $p$-methyl acetophenone ($p$-MeAP), $p$-chloroacetophenone ($p$-ClAP) and those of their binary mixtures with $N$-ethyl aniline ($N$-EA) as a common component, were measured at 303.15 K over the entire composition range. These experimental data were used to calculate the excess volume $V^E$, deviation in ultrasonic speeds ${\Delta}u$, isentropic compressibility $K_s$, intermolecular free length $L_f$, acoustic impedance Z, deviations in isentropic compressibility ${\Delta}K_s$, deviation in viscosity ${\Delta}{\eta}$ and excess Gibbs free energy of activation of viscous flow ($G^{*E}$) at all mole fractions of $N$-ethyl aniline. These parameters, especially excess functions, are found to be quite sensitive towards the intermolecular interactions between component molecules. Theoretical values of viscosity of the binary mixtures were calculated using different empirical relations and theories. The relative merits of these relations and theories were discussed. The experimental results were correlated by using the polynomial proposed by Redlich-Kister equation.

• Journal of Mechanical Science and Technology
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• 제17권1호
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• pp.146-156
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• 2003

A numerical algorithm is developed to analyze the performance of a Unit-injector (UI) System for a diesel engine. The fundamental theory of the algorithm is based on the continuity equation of fluid dynamics. The loss factors that should be seriously regarded on the continuity equation are the compressibility effect of liquid fuel, the wall friction loss in high-pressure fuel lines of the system, the kinetic energy loss of fuel in the system, and the leakage of fuel out of the control volume. For an evaluation of the developed simulation algorithm, the calculation results are compared with the experimental outputs provided by the Technical Research Center of Doowon Precision Industry Co. (DPICO) ； the maximum pressure in the plunger chamber (P$\_$p/) and total amount of fuel injected into a cylinder per cycle (Q$\_$f/) at each operational condition. The result shows that the average error rate (%) of P$\_$p/ and Q$\_$f/ are 2.90% and 4.87%, respectively, in the specified operational conditions. Hence, it can be concluded that the analytical simulation algorithm developed in this study can be reasonably applied to the performance prediction of newly designed UI system.

• 한국지반공학회논문집
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• 제21권5호
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• pp.45-50
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• 2005

최근에 샌드드레인공법이나 샌드콤팩션파일공법 등과 같이 모래말뚝을 이용한 연약점토지반 개량공법의 적용이 증가하고 있다. 이러한 공법들로 개량된 연약점토지반에서는 모래말뚝에 의한 압밀촉진효과를 기대 할 수 있는데 실무에서는 보통 Barren의 이론해 등과 같은 이론식을 이용하여 그 효과를 평가하고 있다. 그러나 이러한 이론식들은 복합지반의 비선형 체적압축거동과 압밀중의 투수계수 변화 현상을 고려할 수 없으며, 따라서 그 평가결과가 합리적 이라고 판단하기 힘들다. 본 연구에서는 일련의 수치해석을 실시하여 Barren의 이론해에 적용되는 복합지반의 압밀정수 결정법에 대하여 고찰하였다. 수치해석 결과의 분석을 통하여 압밀 중에 변화하는 점토부의 체적압축거동특성과 투수성의 변화특성을 고려한 압밀정수의 결정방법을 제안하였다.

• Ocean and Polar Research
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• 제37권1호
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• pp.73-80
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• 2015

In order to determine the appropriate volume of the a pressure compensator of deep seabed mining robots, this paper reports on an experimental test for oil volume change in an oil-filled box. At the design stage of underwater robots, it is crucial to determine the capacity of the hydraulic compensator which is replenished as much as the contracted oil volume of the robots. A pilot mining robot, MienRo was designed to work under 6,000 m in the deep sea. The hydraulic actuating oil and pressure compensating oil of MineRo may be exposed at a hydrostatic pressure environment of 600 bar. Although the oil can be assumed to be incompressible, its volume is actually changed under high pressure conditions due to air contained in the oil and oil contraction. To determine the capacity of the pressure compensator, the oil contraction rate should be verified through an experimental test using a hyperbaric chamber.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2008년도 학술발표회 논문집
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• pp.1624-1629
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• 2008

The governing equations in generalized curvilinear coordinates for a 3D pulsatile flow are the Incompressible Navier-Stokes (INS) equations with the artificial dissipative terms and continuity equation discretized using a second-order accurate, finite volume method on the nonstaggered computational grid. This method adopts a dual or pseudo time-stepping Artificial Compressibility (AC) method integrated in pseudo-time. The computational technique implements the implicit approximate factorization method of the Beam and Warming method (1978), which is the extension of the Alternate Direction Implicit (ADI) method. The algorithm yields practically identical velocity profiles and secondary flows that are in excellent overall agreement with an experimental measurement (Rindt & Steenhoven, 1991).

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2007년도 학술발표회 논문집
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• pp.1392-1396
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• 2007

The governing equations in generalized curvilinear coordinates for 3D laminar flow are the Incompressible Navier-Stokes (INS) equations with the artificial dissipative terms. and continuity equation discretized using a second-order accurate, finite volume method on the nonstaggered computational grid. This method adopts a dual or pseudo time-stepping Artificial Compressibility (AC) method integrated in pseudo-time. Multigrid methods are also applied because solving the equations on the coarse grids requires much less computational effort per iteration than on the fine grid. The algorithm yields practically identical velocity profiles and secondary flows that are in excellent overall agreement with an experimental measurement (Humphrey et al., 1977).

• 설비공학논문집
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• 제7권1호
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• pp.98-111
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• 1995

The objective of this work is to investigate the form of equations of state for specific refrigerants. In particular, equations of the extended van der Waals form have been studied. As a result, a new equation of state has been developed and tested over ranges of pressure and density up to 5 and 1.5 times critical, respectively. The equation of state separates the compressibility factor into two parts. One is the repulsive compressibility factor and the other is attractive. The former is in the same form of Carnahan-Starling's repulsive term with constant hard-sphere volume. The latter is based on a combination of two different functions linear to density. The equation of state developed here has 12 adjustable parameters and correlates PVT data successfully. All properties are in reduced forms.

• 암석학회지
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• 제3권1호
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• pp.34-40
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• 1994

High pressure X-ray diffraction study was carried out on a graphite to investigate its compressibility as well as any possible phase transition to the hexagonal diamond structure at room temperature. Energy dispersive X-ray diffraction method was introduced using a Mao-Bell type diamond anvil cell with Synchrotron Radiation. Polycrystalline sodium chloride was compressed together with graphite for the high pressure determinations. Because of the poor resolution of the X-ray diffraction pattern of graphite, its compressibility was estimated to be almost same as that of NaCl by graphite (002) X-ray diffraction peak only. An observation of any new peak from a possible hexagonal diamond phase seems very unplausible for its definite identification based on the present data. Alternative approaches such as an Wiggler Radiation source as well as a Large Volume high pressure apparatus will be necessary for the detailed studies on a graphite in future.

• International Journal of Naval Architecture and Ocean Engineering
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• 제12권1호
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• pp.479-490
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• 2020

The hydrodynamic characteristic of transonic motion projectiles with different head diameters are investigated by numerical simulation. Compressibility effect in liquid-phase water are modeled using the Tait state equation. The result shows that with increasing of velocity the compression waves transfer to shock waves, which cause the significant increasing of pressure and decreasing the dimensions of supercavities. While the increasing of head diameter, the thickness, the vapor volume fraction and the drag coefficient of supercavities are all enhanced, which is conducive to the stability of transonic-speed projectiles. The cavity dynamics of the different head projectiles are compared, and the results shows when Mach number is in high region, the truncated cone head projectile is enveloped by a cavity which results in less drag and better stability.