• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.281-295
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• 2021

In this study, the direct amination of ethanol was performed over impregnated Ni on SiO2-Al2O3 mixed oxide catalysts prepared by varying Si/(Si + Al) molar ratio to 30 mol%. To characterize the physico-chemical properties of the catalysts used, X-ray diffraction (XRD), N2-physisorption, temperature-programmed desorption of iso-propyl alcohol (IPA-TPD), temperature-programmed desorption of ethanol (EtOH-TPD), temperature-programmed reduction with H2 (H2-TPR), H2-chemisorption and transmission electron microscopy (TEM) were used. The acidic property was continuously increased until Si/(Si + Al) = 30 mol% in SiO2-Al2O3 mixed oxides used. The dispersion of Ni metal and surface area, acid characteristics of the supported Ni catalyst have a complex effect on the catalytic reaction activity. The low reduction temperature of nickel oxide and acidic properties were beneficial to the formation of acetonitrile. In terms of conversion of ethanol, Ni/SiO2-Al2O3 catalyst with a molar ratio of 10 mol% Si/(Si+Al) showed the highest activity and a volcanic curve based on it. The tendency of results were consistent in the metal dispersion and catalytic activity.

• Economic and Environmental Geology
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• v.28 no.6
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• pp.599-612
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• 1995

Some REE ore deposits are located in the middle part the of Korean peninsula. Geotectonically, the REE ore deposits situated on the Kyemyeongsan Formation of northern margin of the Okcheon geosynclinal belt and in the transitional zone between Kyeonggi massif and the Okcheon belt, with a deep-seated fracture separating the two tectonic units. The Kyemyeongsan Formation are different in lithology and metamorphic grade from the Gyeonggi massif and the Okcheon super group. The sequence of Kyemyeongsan Formation is dominantly composed of acidic metavolcanic and volcaniclastic rocks associated with alkaline igneous rocks which are related to volcano-plutonism. The REE ore deposits contain mainly Ce-La, Ta-Nb, Y, Y-Nd and Nd-Th group minerals. More than 15 RE and REE minerals have been found in the deposits, such as allanite, fergusonite, thorite bestnaesite, euxenite, polyclase, monazite, columbite, (Nb)-rutile, okanoganite, sphene, zircon, illmenite and some other unknown minerals. According to the characteristics of the mineral association, the REE ore deposits may be divided into 4 ore types; Zircon-REE, allanite-REE, feldspar-REE and fluorite-REE type. The Sm-Nd isochron age of the REE ore is 330 Ma, and the Sm-Nd model age is 1.11 Ga with ${\varepsilon}_{Nd(t)}$ being - 2.9. This data suggest that the REE ore deposit was formed in the early Carboniferous, and the ore-forming material came from the mantle. The REE ores show distinct light REE enrichment with strong negative Eu anomaly. The REE patterns of schistose rocks from Kyemyeongsan Formation are similar to felsic volcanics from rifts or back arc basins in or near continental crust. The genesis of the REE ore deposit is quite complicated. Different geologic processes are displayed in the studied area; sedimentation, volcanic activity, metamorphism and hydrothermal replacement. Alkali granite has suffered extensive post-magmatic metasomatism of a high temperature to produce alkali metasomatites. Geochemical charateristics show that metasomatism of alkaline fluid was probably the dominant ore-forming process in Chungju district.

• 한국석유지질학회:학술대회논문집
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• spring
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• pp.29-37
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• 1998

The sedimentary succession on the northern coast of Jindo and the adjacent area comprises the thinly bedded, fine-grained deposits of an epiclastic sandstone, siltstone, black shale/mudstone, and cherty mudstone (ca. 200m in vertical thickness), which are interpreted as the finely stratified turbidites mainly by density underflow-induced currents. Most deposits can be divided into eight facies: thin-bedded, ash-rich massive sandstone layer (mS), graded and laminated mudstone layer (glM), graded mudstone layer with ripple lamination (rM), laminated and graded siltstone layer (lgZ), finely laminated black shale layer (IBS), structureless mudstone layer (mM), thin-bedded cherty mudstone layer (lCM), and contorted and laminated mudstone layer (dlM), The thin-bedded, ash-rich sandstone facies is interpreted to be deposited from high-density turbid underflows during a relatively large flooding. Most thinly bedded mudstone facies would be deposited from low-density turbid underflows (turbidity currents) with some different hydrodynamic condition and sediment concentration during the high discharge of river water. Whereas the structureless mudstone facies may result from raining down of suspended sediment intermittently supplied by overflows and interflows. From the entire succession, graded and laminated mudstone layers interbedded with thin-bedded, ash-rich massive sandstone are dominant in the lower part of the succession, and graded mudstone layers with ripple lamination ripple lamination occur mainly in the middle part of it. On the other hand, iaminated/raded siltstone and contorted/laminated mudstone layers prevail in the upper part. The transition of facies association is suggestive of the continuous change of main depositional setting from basin plain to lower slope, which could be due to the movement of depocenter by the increase of sediment supply (volcanic activity).

• Korean Journal of Remote Sensing
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• v.30 no.6
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• pp.719-730
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• 2014

Small BAseline Subset (SBAS) technique using multi master interferograms can be effective to detect surface deformation in forest area. In this paper, The analysis reveals area of 2-dimension surface deformation at Seguam Island in Aleutian Arc., Alaska. We acquired ERS-1/2 data from track 201 and 473 datasets on Seguam Island from 1992 to 2008. This study analyze surface deformation applying Differential Interferometry Synthetic Aperture Radar (DInSAR) and SBAS time series method using two adjacent tracks. As a results, it was calculated that subsidence -1~2 cm in LOS direction and - 2~3 cm in vertical direction. The horizontal direction was repeated contraction and expansion. The observation of 2-dimension displacements explained the volcanic activity on Seguam island. Also, it is believed to be used for basic data to estimate movements of magma source.

• Journal of Soil and Groundwater Environment
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• v.17 no.2
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• pp.22-27
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• 2012

$^{226}Ra$ in groundwater could be analyzed by various methods. LSC (liquid scintillation counter) is used to measure its activity of Ba co-precipitates with Hisafe III scintillation cocktail solution. Counting efficiency was obtained using NIST $^{226}Ra$ standard solution in triplicate and calculated $^{226}Ra$ concentration using the efficiency values. $^{226}Ra$ values of 19 groundwaters having Gross-${\alpha}$ concentrations of more than 5 pCi/L ranged from ND (${\leq}$ 0.1 pCi/L) to 1.18 pCi/L. Geologic settings of the 19 areas are composed of granitic rocks of Pre-Cambrian and Jurassic and Cretaceous, gneiss (schist) of Pre-Cambrian, and volcanic rocks of Cretaceous. No relationship was shown among $^{226}Ra$ a concentrations and in-situ water quality data, and Gross-${\alpha}$, uranium, radon concentrations.

• Journal of Korean Elementary Science Education
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• v.21 no.1
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• pp.1-11
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• 2002

The purpose of the study is to compare and analyze the elementary science textbooks' contents between the United States(Science Horizons) and Korea for teaching the Returnee students. The analyzed contents are the name of chapters, the number of chapters, the page amounts of chapters, the structure of chapters and the studying time of chapters. The results of this study are : 1. Korean science textbook's number is 20. 'Science Horizons' has 6. Korean science textbook's total number of chapter is 58, 'Science Horizons' is 75. Korean science textbook's total number of page is 1,60.3, 'Science Horizons' is 2,106. So 'Science Horizons' has more number of chapter and page than Korean textbooks. 2. The ratio of Korean science textbook's contents is as follows: physical area, 22.4%; chemistry area, 12 1％: biology area, 39.6%; earth science area, 25.9%. But the ratio of 'Science Horizons' science textbook's contents is as follows: physical area,21.3%; chemistry area,4.0%; biology area, 46.7%; earth science area. 28.0%. 3. In case of 'Predicting the Weather' chapter, Korean science textbook has 3 lessons, 17 themes and 11 activities, whereas' Science Horizons' has 5 lessons, 10 themes and 5 activities. 4. The themes or chapters of 'Science Horizons' to propose deeper than Korea are about animals and plants, energy and movement, weather and season. our body, and earth and outer space. In case of Korean textbook are about chemistry area, the rock and volcanic activity and electric circuit. There are some differences between Korean and the United States' elementary science curriculum and textbook's contents. And the returnee students has many troubles to adapt korean science curriculum, textbooks and educational environment,;. Therefore, teachers should know and understand that, and help them.

• Journal of the Korean earth science society
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• v.25 no.4
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• pp.222-231
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• 2004

The purpose of this study is to analyze the seventh curriculum textbooks and teacher's guides of high school science courses in relation to the generation (mechanism) of magma in subduction boundary and find the incorrect descriptions of the texts and the figures (illustrations) and then suggest some improved schemes. According to the result there are many discrepancies in definition of 'magma' among the textbooks and further little scientific explanations about the formation mechanism of magma in most textbooks, and even no descriptions about that. In addition, the figures are inconsistent with the description of the text and also have some incorrect depiction which might contribute to the forming and reinforcing misconceptions about Plate Tectonics as well as a volcanic activity in subduction boundary. On the basis of the previous researches, therefore, some improved schemes (text descriptions and figures) are suggested. The results of this study should be used as a reference for publishing science textbook, developing science curriculum, and teaching effectively in the high school.

• Journal of Soil and Groundwater Environment
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• v.16 no.5
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• pp.67-73
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• 2011

Groundwaters were sampled from 730 wells being used for drinking purposes during 2007-2009. These samples were analysed using a gas-flow type GPC (Gas Proportional Counter) according to the USEPA method (900.0). We obtained a gross-alpha counting TDS (total dissolved solid) efficiency curve (Y = 0.0017X2 - 0.3122X + 19.165, X = TDS, Y = efficiency, $R^2$ = 0.9734) using natural uranium standard to get gross ${\alpha}$ value of the samples. The gross alpha values ranged from MDA (minimum detectable activity) to 14.88 pCi/L and 429 samples showed values higher than MDA (< 0.9 pCi/L). Correlations of the uranium values with the total alpha values and the gross-alpha values indicate that uranium values have high impacts on gross-alpha values. Groundwater samples of study areas were classified into four regions according to the rock types; plutonic (granite) rock region (427 areas), metamorphic rock region (181 aeras), sedimentary rock region (70 areas), volcanic rock region (52 areas). Groundwater of Cretaceous granite presented the highest gross-alpha value. Gross alpha in groundwaters showed no relationship with uranium in terms of the geological ages, rocks and minerals.

• Ocean and Polar Research
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• v.42 no.1
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• pp.33-47
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• 2020

The bulk and partition geochemistry was studied in two sediment cores collected from the axial valley of the north-central Fonualei Rift and Spreading Center (FRSC), Lau back-arc Basin, southwest Pacific. The sediments consist of mostly volcanic ash, although minor amounts of biogenic and other components were present in some intervals. The major element composition of bulk sediments recalculated to a carbonate-free basis was in good agreement with the magma compositions of the adjacent Tofua Arc and the FRSC, with only significant difference in Mn content. The enrichment of Mn and other associated elements (e.g. Cu, Co, Ni, and P) is attributed to hydrothermal input to the sediments, as evidenced by their significant partitioning in the non-detrital phases according to the partition geochemistry. Hydrogenetic and diagenetic inputs were assessed to be relatively insignificant. Estimated hydrothermal Mn fluxes during the Holocene ranged between 5.0 and 37.1 mg cm^-2 kyr^-1, with the higher values in younger sediments, suggesting enhanced hydrothermal activity. The hydrothermal Mn fluxes comparable to or higher than those reported from other spreading centers with strong hydrothermal activities may indicate the presence of unknown hydrothermal vent sites and/or topographic restriction on the dispersal of hydrothermal plumes in the northern part of the FRSC.

• Journal of the Computational Structural Engineering Institute of Korea
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• v.27 no.6
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• pp.477-484
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• 2014

Caldera is a large depression commonly formed by collapse of the ground following explosive eruption of a large body of stored magma. On earth, calderas and caldera complexes range in size from kilometers to tens of kilometers. Historical eruptions associated with caldera collapse have led to huge fatalities in Indonesia as well as left global impacts. This study presents case study on calderas in Indonesia which resembles to Mount Baekdu located at the border of China and North Korea; in the perspectives of similar characteristics, principal hazard, recent symptom of volcanic activity and the threat if eruption occurs in the near future. Calculation by using weighted evaluation matrix for Mount Krakatau, Mount Tambora, Mount Ijen, Tengger Caldera, Mount Rinjani and Ranau Caldera were taken for the selection of a site for future case study.