• 한국세라믹학회지
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• 제47권1호
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• pp.8-18
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• 2010

When metal oxides are exposed to chemical potential gradients, ions are driven to diffusive mass transport. During this transport process, the divergence of ionic fluxes offers the formation/annihilation of oxides. Therefore, the divergence of ionic flux may play an important role in the void formation in oxides. Kinetic equations were derived for describing chemical potential distribution, ionic fluxes and their divergence in oxides. The divergence was found to be the measure of void formation. Defect chemistry in scales is directly related to the sign of divergence and gives an indication of the void formation behavior. The quantitative estimation on the void formation was successfully applied to a growing magnetite scale in high temperature oxidation of iron at 823 K.

• Nuclear Engineering and Technology
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• 제52권6호
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• pp.1131-1136
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• 2020

Xenon behaves differently in molten salt reactors (MSRs) compared to solid fuel reactors. This behavior needs exploring due to the large reactivity effect of the ¹³⁵Xe isotope, given the current interest in MSR power plant development for commercial deployment. This paper focuses on select topics in xenon transport, reviews relevant past works, and proposes specific research questions to advance the state of the art in each of the focus areas. Specifically, the paper discusses the issue of xenon solubility in MSRs, the behavior of particulates circulating in MSR fuel salt and its influence on the xenon transport, the possibility of ionization of xenon atoms which changes its effective size and thus affects its mass transport, and finally the issue of circulating void fraction and how it is measured. This work presents specific recommendations for MSR designers to research the limits of Henry's law validity, circulating particulate scrubbers, validity of mass transport coefficients in high radiation fields, and the effects of pump speed on circulating void fraction.

• Composites Research
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• 제16권6호
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• pp.10-15
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• 2003

RTM 공정에 의하여 생성된 제품은 microvoids의 함유량에 의하여 기계적인 물성치에 큰 영향을 받는다. 본 연구에서는 이러한 microvoid의 형성과 이동을 실험적으로 관찰할 수 있는 방법을 제시하였다. Vacuum assisted RTM공정에서 유동선단에서의 microvoid의 형성과 이동을 DV camera로써 관찰을 한 후, 그것에서 void의 함유량을 구하고, 실험에서 얻어진 결과로 microvoid model에 필요만 factor들을 얻어낼 수 있었다. 이렇게 하여 얻어진 결과를 다시 실험적인 결과와 비교함으로써 서로 일치하는 결과를 얻어낼 수 있었다. 이번 연구에서 얻어진 결과를 수학적인 모델에 대입함으로써 VARTM 공정 중 microvoid의 함유량을 예측할 수 있다.

• Journal of Advanced Marine Engineering and Technology
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• 제27권4호
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• pp.487-493
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• 2003

More reliable design of thermal transport. Power acquisition and thermal management systems requires the through understanding of the flow hydrodynamic. the differences and similarities between the two-phase flow characteristics of two-Phase flow influenced by the gravity levels. The data of flow Patterns, void fraction, frictional pressure drop associated with their characteristics were obtained at $\mu\textrm{g}$. 1g and 2g. Flow patterns and void fraction data obtained at three gravity levels were compared with each other and previous models and correlations.

• 한국막학회:학술대회논문집
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• 한국막학회 1997년도 추계 총회 및 학술발표회
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• pp.27-30
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• 1997

1. Introduction : Molecular diffusion of small molecules in polymers plays an important role in many areas where polymers are acting as barriers, and in separation processes, such as selective diffusion. Different applications of polymers have different requirements on their transport properties. Therefore, reliable predictions of diffusion coefficients for small molecules in polymeric materials could be a useful tool to design appropriate materials. For many years, the theories based on free-volume concepts have been widely used to correlate and predict diffusion behavior in polymer/solvent systems. In the theory derived by Vrentas and Duda, the empty space between molecules that is available for molecular transport, referred to as hole free-volume, is being redistributed. Molecular transport will occur only when a free-volume of sufficient size appears adjacent to a molecule and the molecule has enough energy to jump into this void. The diffusive jump is considered complete when the void left behind is closed before the molecule returns to its original position. In this paper, the Vrentas-Duda free-volume theory is presented and the methods to estimate free-volume parameters for predicting polymer/ solvent diffusion coefficients are described in detail.

• 한국재료학회지
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• 제12권11호
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• pp.883-888
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• 2002

We investigated the void formation in composite-titanium silicide($TiSi_2$) process. We varied the process conditions of polycrystalline/amorphous silicon substrate, composite $TiSi_2$ deposition temperature, and silicidation annealing temperature. We report that the main reason for void formation is the mass transport flux discrepancy of amorphous silicon substrate and titanium in composite layer. Sheet resistance in composite $TiSi_2$ without patterns is mainly affected by silicidation rapid thermal annealing (RTA) temperature. In addition, sheet resistance does not depend on the void defect density. Sheet resistance with sub-0.5 $\mu\textrm{m}$ patterns increase abnormally above $850^{\circ}C$ due to agglomeration. Our results imply that $sub-750^{\circ}C$ annealing is appropriate for sub 0.5 $\mu\textrm{m}$ composite X$sub-750_2$ process.

• 한국가시화정보학회지
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• 제15권1호
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• pp.41-46
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• 2017

Control of mixing and transport processes are the key areas that can be benefited by understanding the hydrodynamics in gas-liquid two-phase flows. In particular, the enhanced bubble-induced liquid-phase mixing is known to be a function of void fraction distribution, gas phase velocity and so on. To further our insight on the characteristics of the liquid-phase mixing induced by the bubbles, in the present study, we experimentally investigate the mixing performance of a rectangular bubble column while changing the void fraction from 0.006 to 0.075%. A shadowgraphy technique is used to measure the gas-phase properties such as void fraction and size/velocity of bubbles. On the other hand, we use dye visualization with low diffusive buoyant dye to directly measure the level of mixing. Finally, we confirm that the time taken for full mixing scales with the inverse of volume void fraction.

• 한국원자력학회:학술대회논문집
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• 한국원자력학회 1996년도 춘계학술발표회논문집(2)
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• pp.241-246
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• 1996

An analytical model to calculate rate of vapor generation due to heterogeneous wall nucleation in flashing flow is developed. In the present model, an important parameter of the vapor generation term, i.e. nucleation site density is calculated by integrating its probability distribution function with respect to active cavity radius. The limits of integration are minimum and maximum active cavity radii, and these are formulated using an active cavity model for nucleate boiling. This formulation, therefore. can statistically account for the effect of surface specific thermo-physical and geometric conditions on the vapor generation rate and flashing inception. For verifying the adequacy of the present model, steady state two-fluid and the bubble transport equations are solved with applicable constitutive equations. The applicable region of the bubble transport equation is also extended to churn-turbulent flow regime to predict interfacial area concentration at high void fraction. Predicted results in terms of axial pressure and void fraction profiles along the channels are compared with experimental data of Super Moby Dick and BNL Reasonable agreements have been achieved and this shows the applicability of the present model to flashing flow analysis.

• Nuclear Engineering and Technology
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• 제49권7호
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• pp.1379-1387
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• 2017

This paper presents a comparison of homogenization techniques implemented in the APOLLO3 platform for transport core calculations: standard scalar flux weighting and new flux-moment homogenization, in different combinations with (or without) leakage models. Besides the historical B1-homogeneous model, a new B-heterogeneous one has indeed been implemented recently in the two/three-dimensional-transport solver using the method of characteristics. First analyses have been performed on a very simple Sodium Fast Reactor core with a regular hexagonal lattice. They show that using the heterogeneous leakage model in association with flux-moment homogenization strongly improves the prediction of $k_{eff}$ and void reactivity effects. These good results are confirmed when the application is done to the fissile assemblies of the more complex CFV (Low Void Effect) core of the ASTRID (Advanced Sodium Technological Reactor for Industrial Demonstration) project of sodium-cooled fast breeder reactor (Generation IV).

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집C
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• pp.246-250
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• 2001

In resin transfer molding (RTM), resin is forced to flow through the fiber perform of inhomogeneous permeability. This inhomogeneity is responsible for the mismatch of resin velocity within and between the fiber tows. The capillary pressure of the fiber tows exacerbates the spatial variation of the resin velocity. The resulting microscopic perturbations of resin velocity at the flow front allow numerous air voids to form. In this study, a mathematical model was developed to predict the formation and migration of micro-voids during resin transfer molding. A transport equation was employed to account for the migration of voids between fiber tows. Incorporating the proposed model into a resin flow simulator, the volumetric content of micro-voids in the preform could be obtained during the simulation of resin impregnation.