• Title/Summary/Keyword: void formation

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Void Formation Induced by the Divergence of the Diffusive Ionic Fluxes in Metal Oxides Under Chemical Potential Gradients

  • Maruyama, Toshio;Ueda, Mitsutoshi
    • Journal of the Korean Ceramic Society
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    • v.47 no.1
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    • pp.8-18
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    • 2010
  • When metal oxides are exposed to chemical potential gradients, ions are driven to diffusive mass transport. During this transport process, the divergence of ionic fluxes offers the formation/annihilation of oxides. Therefore, the divergence of ionic flux may play an important role in the void formation in oxides. Kinetic equations were derived for describing chemical potential distribution, ionic fluxes and their divergence in oxides. The divergence was found to be the measure of void formation. Defect chemistry in scales is directly related to the sign of divergence and gives an indication of the void formation behavior. The quantitative estimation on the void formation was successfully applied to a growing magnetite scale in high temperature oxidation of iron at 823 K.

Three Dimensional numerical Simulation of Resin Flow and Void Formation in Resin Transfer Molding Process (RTM 공정에서의 수지 유동과 기공 생성의 3차원 수치해석)

  • 강문구;이도훈;이우일;엄문광;이상관
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2002.10a
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    • pp.284-287
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    • 2002
  • During resin transfer molding(RTM) process, in case of thick parts, resin flow and void formation should be modeled three dimensionally even though for parts of small thickness, resin flow and void formation can be modeled two dimensionally. In this study, numerical simulations of three dimensional mold filling and void formation during RTM process.

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Modeling of central void formation in LWR fuel pellets due to high-temperature restructuring

  • Khvostov, Grigori
    • Nuclear Engineering and Technology
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    • v.50 no.7
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    • pp.1190-1197
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    • 2018
  • Analysis of the GRSW-A model coupled into the FALCON code is extended by simulation of central void formation in fuel pellets due to high-temperature fuel restructuring. The extended calculation is verified against published, well-known experimental data. Good agreement with the data for a central void diameter in pellets of the rod irradiated in an Experimental Breeder Reactor is shown. The new calculation methodology is employed in comparative analysis of modern BWR fuel behavior under assumed high-power operation. The initial fuel porosity is shown to have a major effect on the predicted central void diameter during the operation in question. Discernible effects of a central void on peak fuel temperature and Pellet-Cladding Mechanical Interaction (PCMI) during a simulated power ramp are shown. A mitigating effect on PCMI is largely attributed to the additional free volume in the pellets into which the fuel can creep due to internal compressive stresses during a power ramp.

Effect of Impurities on Stress Induced Void Formation in Al-1% Si Conductors

  • Lee, Seong-Min
    • Transactions on Electrical and Electronic Materials
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    • v.2 no.3
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    • pp.12-17
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    • 2001
  • It is shown in the present study that during the HTS (hot temperature storage) test, the metal contamination by impure elements can be highly susceptible to the void formation, leading to the open failure of the power line in the memory device. Such a functional failure associated with the metal contamination was investigated to be dominant in the early stages of the HTS test while the formation of a stress-driven void is mainly observed in the later stages. In particular, it was found that the void formed in the contaminated metal takes on a slit-like shape which has been known to be characteristic of the stress-related voiding. The impure elements leading to the metal degradation were identified to be carbon and oxygen introduced during the metal sputtering process. The experimental works show that the device reliability was significantly improved by reducing the level of such impure elements within metal. It is shown in the present study that during the HTS (hot temperature storage) test, the metal contamination by impure elements can be highly susceptible to the void formation, leading to the open failure of the power line in the memory device. Such a functional failure associated with the metal contamination was investigated to be dominant in the early stages of the HTS test while the formation of a stress-driven void is mainly observed in the later stages. In particular, it was found that the void formed in the contaminated metal takes on a slit-like shape which has been known to be characteristic of the stress-related voiding. The impure elements leading to the metal degradation were identified to be carbon and oxygen introduced during the metal sputtering process. The experimental works show that the device reliability was significantly improved by reducing the level of such impure elements within metal.

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CD 스터드 용접의 해석 및 결함 분석 Part 2 : 기공 제어

  • Oh Hyun-Seok;Yoo Choong-D.
    • Journal of Welding and Joining
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    • v.24 no.3
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    • pp.42-48
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    • 2006
  • Since the voids occur at the CD stud welds, the mechanism of void formation and void reduction method are investigated in this work. It is speculated that the voids are formed because of high short-circuit current above 1000A. When the simple flow model is used to estimate the void trapping condition, the most voids are trapped at the weld mainly due to fast cooling rate of the CD stud weld. Since it is almost impossible to remove the voids completely, a method is proposed to reduce the void by decreasing the short-circuit current at the end of the arcing time. The experimental results show that the void is reduced by decreasing the short-circuit current to 1000A.

A STUDY ON THE VOID FORMATION AND DETAIL REPRODUCTION ACCORDING TO THE VARIOUS IMPRESSION MATERIALS AND MIXING METHODS (수종 인상재의 혼합방법에 따른 기포형성과 표면 재현력에 관한 연구)

  • Ryu, Hyeong-Seon;Lim, Heon-Song;Lim, Ju-Hwan;Cho, In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.2
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    • pp.140-155
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    • 2002
  • Void-free impression taking is important for the fabrication of accurate dental restorations. One of the essential properties of an impression material used for indirect fabrication of precision castings is the reproduction of the fine detail. The objective in this study was to determine the influence of mixing methods on the number of voids and surface detail reproduction. The number of voids and surface detail reproduction were evaluated with the steteomicroscope $SZ-PT^{(R)}$ and photographed. The results were as follows ; 1. In comparison of the void formation according to mixing methods of all impression materials, mechanical mixing was better than hand mixing and there was significant difference(p<0.05) 2. In comparison of the void formation according to hand mixing of alginate impression materials($TOKUSO\;A-1{\alpha}^{(R)},\;CAVEX\;IMPRESSIONAL^{(R)},\;AROMA \;FINE\;DF\;III^{(R)}$), there was no significant difference among alginate groups. But the number of void was increased in the order of $Panasil^{(R)}\;contact,\;TOKUSO\;A-1{\alpha}^{(R)},\;Permlastic^{(R)}$ light bodied and there was significant difference (p<0.05). 3. In comparison of the void formation according to mechanical mixing of alginate impression materials($TOKUSO\;A-1{\alpha}^{(R)},\;CAVEX\;IMPRESSIONAL^{(R)},\;AROMA FINE\;DF\;III^{(R)}$), there was no significant different among alginate groups. But the number of void was decreased in order of $TOKUSO\;A-1{\alpha}^{(R)},\;Permlastic^{(R)}light\;bodied,\;Panasil^{(R)}$ contact and there was significant difference (p<0.05). 4. In comparison of the surface detail reproduction according to mixing methods of 3 types of impression materials($TOKUSO\;A-1{\alpha}^{(R)},\;Permlastic^{(R)}\;light\;bodied,\;Panasil^{(R)}\;contact$), there was no significant difference between hand mixing and mechanical mixing method 5. The surface detail reproduction was only influenced by impression materials, and produced better in order of $TOKUSO\;A-1{\alpha}^{(R)},\;Panasil^{(R)}\;contact,\;Permlastic^{(R)}$ light bodied. There was significat difference among 3 type of impression materials(p<0.05). From the above results, void formation is influenced by mixing methods and surface detail reproduction is influenced by impression materials than mixing methods. Therefore, to fabricate accurate restorations, proper impression material and mechanical mixing method are more effective and available clinically.

Void Defects in Composite Titanium Disilicide Process (복합 티타늄실리사이드 공정에서 발생한 공극 생성 연구)

  • Cheong, Seong-Hwee;Song, Oh-Sung
    • Korean Journal of Materials Research
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    • v.12 no.11
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    • pp.883-888
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    • 2002
  • We investigated the void formation in composite-titanium silicide($TiSi_2$) process. We varied the process conditions of polycrystalline/amorphous silicon substrate, composite $TiSi_2$ deposition temperature, and silicidation annealing temperature. We report that the main reason for void formation is the mass transport flux discrepancy of amorphous silicon substrate and titanium in composite layer. Sheet resistance in composite $TiSi_2$ without patterns is mainly affected by silicidation rapid thermal annealing (RTA) temperature. In addition, sheet resistance does not depend on the void defect density. Sheet resistance with sub-0.5 $\mu\textrm{m}$ patterns increase abnormally above $850^{\circ}C$ due to agglomeration. Our results imply that $sub-750^{\circ}C$ annealing is appropriate for sub 0.5 $\mu\textrm{m}$ composite X$sub-750_2$ process.

Void Formation Mechanism of Thermoset (열경화성 수지의 기공 생성 원인)

  • 강길호;박상윤
    • Polymer(Korea)
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    • v.28 no.1
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    • pp.35-40
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    • 2004
  • The formation mechanism of void defect which deteriorate composite's property is various according to each composite process. In this paper, void formation and growth mechanism is analyzed by thermal analysis and GC/MS. We made a vacuum chamber for observing pressure effect. Thermal analysis has been done in various condition. Elements of volatiles during resin curing were turned out by GC/MS. The most of volatiles of polyester were composed of styrene (over 80%) and a small quantity of toluene. In case epoxy resin, butyl glycidyl ether was the main element of volatiles (over 90%). We concluded that the original sites of void growth existed in resin and they were eliminated by vacuum and heating process. And the growth of void was influenced by water, diluents, solvent, and reactants in resin.

A Study on Formation of Void Space by Geometric Method and Environment-friendly Characteristics in Contemporary Housing (현대주거의 기하조작에 의한 보이드 공간의 생성과 친환경적 특성에 관한 연구)

  • Lee, Dong-Ki
    • Journal of the Korean housing association
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    • v.21 no.6
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    • pp.131-141
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    • 2010
  • This study is aimed to grasp the spatial characteristics exhibited in the modern housing architecture from the aspect of a geometrical manipulation, which transforms basic geometrical shapes and persue the formative diversity, to identify and verify the various characteristics of spatial structure in modern housing architecture. In this regard, this paper analyze and identify the influences of the void spaces that are created by geometrical manipulations on housing architecture, in terms of morphological and environmental aspects. Theoretical approaches define the concept of geometrical manipulation according to the characteristics of residence and examine the spatial features of void spaces. Additionally, case studies result in the classification of void spaces that are created by geometrical manipulation. Furthermore, to understand environment-friendly characteristics of the void space, the researcher elicited the factors that can affect environment friendly housing from previous studies, and analyzed their correlation between those factors and the void spaces that are classified.