• Title/Summary/Keyword: viscosity change

Search Result 627, Processing Time 0.026 seconds

RHEOLOGICAL PROPERTIES OF RESIN COMPOSITES ACCORDING TO THE CHANGE OF MONOMER AND FILLER COMPOSITIONS (단량체 및 무기질 filler 조성 변화에 따른 복합레진의 유변학적 특성)

  • Lee In-Bog;Lee Jong-Hyuck;Cho Byung-Hoon;Son Ho-Hyun;Lee Sang-Tag;Um Chung-Moon
    • Restorative Dentistry and Endodontics
    • /
    • v.29 no.6
    • /
    • pp.520-531
    • /
    • 2004
  • The aim of this study was to investigate the effect of monomer and filler compositions on the rheological properties related to the handling characteristics of resin composites. Methods. Resin matrices that Bis-GMA as base monomer was blended with TEGDMA as diluent at various ratio were mixed with the Barium glass (0.7 um and 1.0 um), 0.04 um fumed silica and 0.5 um round silica. All used fillers were silane treated. In order to vary the viscosity of experimental composites, the type and content of incorporated fillers were changed, Using a rheometer, a steady shear test and a dynamic oscillatory shear test were used to evaluate the viscosity ($\eta$) of resin matrix, and the storage shear modulus (G'), the loss shear modulus (G"), the loss tangent ($tan{\delta}$) and the complex viscosity (${\eta}^*$) ofthe composites as a function of frequency ${\omega}{\;}={\;}0.1-100{\;}rad/s$. To investigate the effect of temperature on the viscosity of composites, a temperature sweep test was also undertaken. Results. Resin matrices were Newtonian fluid regardless of diluent concentration and all experimental composites exhibited pseudoplastic behavior with increasing shear rate. The viscosity of composites was exponentially increased with increasing filler volume%. In the same filler volume, the smaller the fillers were used, the higher the viscosities were. The effect of filler size on the viscosity was increased with increasing filler content. Increasing filler content reduced $tan{\delta}$ by increasing the G' further than the G". The viscosity of composites was decreased exponentially with increasing temperature.

Rheological Behaviors of Mesophase Pitches Prepared from Coal Tar Pitch as Carbon Fiber Precursor (탄소섬유 원재료로서 콜타르로부터 제조된 메조페이스 핏치의 유변학적 거동)

  • Lee, Young-Seak;Kim, Tae-Jin
    • Applied Chemistry for Engineering
    • /
    • v.10 no.5
    • /
    • pp.690-695
    • /
    • 1999
  • An experimental study for mesophase pitch prepared from coal tar pitch has been carried out to clarify the rheological behaviors in the molten state. The apparent viscosity, shear stress, shear rate, Qunoline insoluble(QI), and softening point(SP) change were investigated especially. The conditions to increase mesophase content during polymerization were heat treatment time of 5 hrs, catalyst concentration of 3% and reaction temperature of $420^{\circ}C$. Apparent viscosity change with increase in temperature of pitches was different according to the heat treatment conditions and apparent viscosity increased with increasing heat treatment temperature, heat treatment time, contents of mesophase, on the contrary, fluidity is decreased. Rheological behavior of molten mesophase pitches at about $270^{\circ}C$ showed Newtonian behavior below $375^{\circ}C$ and non-Newtonian behavior above $270^{\circ}C$, the flow behavior was analyzed with Casson model.

  • PDF

A Study on Lubrication Characteristics of Automotive Engine Oil Merchandised in Domestic (국내 판매되는 자동차용 엔진오일의 윤활특성 연구)

  • Kim, Shin;Kang, Hyung-Kyu;Lim, Tae-Yoon;Kwon, Jong-Soo;Kim, Jai-Gueon;Choi, Dae-Sung;Kim, Dong-Kil;Jung, Choong-Sub
    • Tribology and Lubricants
    • /
    • v.25 no.6
    • /
    • pp.432-437
    • /
    • 2009
  • The effect of oxidation in SAE 5W30 engine oils on friction and wear characteristics was investigated using reciprocating bench tester and shell 4-ball tester. Commercial engine oils were collected and oxidized using the KS M 2021 method modifying the oxidation time. Kinematic viscosity, total acid number(TAN), FT-IR spectrum and total base number(TBN) also measured to examine the chemical change of oils with oxidation. The results showed that TAN was slightly changed and Kinematic viscosity was suddenly increased during the oxidation stage. however, TBN results keep a constant slope after TBN linearly decreased with oxidation time. Spectroscopy results showed that spectrums were orderly increased at $1710cm^{-1}$ during the oxidation time. Friction test results showed that oxidation of oils formed unstable friction layers causing higher fluctuating friction. however, the wear resistance was independent of oxidized time due to the different friction characteristics by oxidation. We found several factors in relation to lubrication properties with oxidation time. This factors were Viscosity, TBN, change of FT-IR spectrum, friction coefficient using reciprocating bench tester and wear scar.

Rheological Characterization of Hydrogen Peroxide Gel Propellant

  • Jyoti, B.V.S.;Baek, Seung Wook
    • International Journal of Aeronautical and Space Sciences
    • /
    • v.15 no.2
    • /
    • pp.199-204
    • /
    • 2014
  • An experimental investigation on the rheological behavior of gelled hydrogen peroxide at different ambient temperature (283.15, 293.15 and 303.15 K) was carried out in this study. The gel propellant was rheologically characterized using a rheometer, in the shear rate ranges of 1 to $20s^{-1}$, and 1 to $1000s^{-1}$. Hydrogen peroxide gel was found to be thixotropic in nature. The apparent viscosity value with some yield stress (in-case of shear rate 1 to $20s^{-1}$) drastically fell with the shear rate. In the case of the shear rate range of 1 to $20s^{-1}$, the apparent viscosity and yield stress of gel were significantly reduced at higher ambient temperatures. In the case of the shear rate range of 1 to $1000s^{-1}$, no significant effect of varying the ambient temperature on the gel apparent viscosity was observed. The up and down shear rate curves for hydrogen peroxide gel formed a hysteresis loop that showed no significant change with variation in temperature for both the 1 to $20s^{-1}$ and the 1 to $1000s^{-1}$ shear rate ranges. No significant change in the thixotropic index of gel was observed for different ambient temperatures, for both low and high shear rates. The gel in the 1 to $20s^{-1}$ shear rate range did not lead to a complete breakdown of gel structure, in comparison to that in the 1 to $1000s^{-1}$ shear rate range.

A Study on the Rheological Behavior Properties of Short-term Aged Asphalt Binder (단기노화 된 아스팔트 바인더의 유변학적 거동 특성에 관한 연구)

  • Park, Tae-Soon
    • International Journal of Highway Engineering
    • /
    • v.7 no.4 s.26
    • /
    • pp.203-210
    • /
    • 2005
  • The penetration and viscosity tests have been used for the evaluation of the aged asphalt binder performance change. The improved test method has been required because the conventional tests could not evaluate the viscoelastic characteristics and the real behaviour of the aged asphalt binder. The conventional test methods using a different short term aged asphalt binder were tested and the test results were expressed as the penetration index and the residual penetration. The oscillatory and rotational mode tests were performed to find out the rheological characteristics of the short term aged asphalt binder in this study. The test results showed that the change of testing frequency, the speed of the vehicle effects the complex modules and phase angles. The creep compliance and shear viscosity also showed the different test results when the short term aged asphalt binders were tested. The rheological behavior should consider when the pavement design is conducted.

  • PDF

Physical Property and Optimal Operating Condition in the Salting-out Dye Crystallization System (염료·염석결정화계에서 물성과 최적조업조건)

  • Pyun, Yu Ri;Han, Hyun Kak;Jung, Hyong Ki
    • Korean Chemical Engineering Research
    • /
    • v.47 no.2
    • /
    • pp.157-162
    • /
    • 2009
  • In this paper, the density, viscosity and solubility are measured to know the physical properties of dye. By changing the concentration of dye solution, the density change of the dye solution was very small and the viscosity of the dye solution was increased. Also, by changing the temperature of dye solution, the density change of the dye solution was increased but the viscosity of the dye solution was decreased. Solubility of dye conducts under the changing the salt and concentration of dye. In 20 wt% of dye and 15 wt% KCl, the amount of dye crystal is maximal. Also, batch salting-out experiments were performed with various conditions to know the optimal operating conditions of dye crystal. Under the various experiments, optimal operating condition was found based on amount of dye; added 15 wt% KCl, $25^{\circ}C$ temperature, 100 RPM, added at once.

A Study on Quality Characteristics of Kiwi Fruit-Gruel with Added Kiwi Concentrate (키위 농축액을 첨가한 키위 죽의 품질 특성에 관한 연구)

  • Kim, Jong-Wook;Sung, Ki-Hyub
    • Journal of the East Asian Society of Dietary Life
    • /
    • v.20 no.2
    • /
    • pp.313-320
    • /
    • 2010
  • In this study, kiwi fruit, which has various medical actions and excellent functionality, was used together with gruels for comparison and analysis of to compare and analyze the changes in physico-chemical quality of a kiwi fruit-gruel according to the amount of kiwi concentrate added to the gruel. Analysis on the sensual quality of kiwi fruit-gruel spread was done to indicate to it was executed to find out the merchandising potential of the preparation and to provide basic data for gruel commercialization. Increasing content of kiwi concentrate decreased the solid content and pH of kiwi fruit, and increased sweetness and viscosity. Significant changes in chromaticity to L(lightness) and a(redness), texture qualities of hardness and cohesiveness, gumminess, springiness, color, flavor, sourness, and sweetness were evident with increasing kiwi concentrate. Concerning overall acceptability and sensory evaluation, 20% softness samples were most preferred. The findings may lead to enhanced medical/nutritional activity and functionality of kiwi fruit-supplemented gruel. The more the kiwi concentrate was added to the gruel, solid content and pH of the kiwi fruit-grue decreased. The sweetness and viscosity of kiwi fruit-gruel increased. For chromaticity to L(lightness) and a(redness) of the gruel decreased and showed significant difference between sample groups. For texture, there were significant changes shown for hardness and cohesiveness the amount of kiwi concentrate added was different, increased There was a significant change between samples for gumminess. As for springiness, there was a significant change between samples. There were significant difference between each sample for color, flavor, sourness, sweetness. For softness, overall-acceptability and sensory evalution 20% group was most preferred based on this study, from the physico-chemical and sensual perspective, 20% group is highly recommended for adding kiwi concentrate into gruel. In conclusion, this study is meaningful as it enhanced the functionality and quality of a gruel by combining kiwi fruit with various medical action and excellent functionality, with Kiwi Fruit and presented a basic material for creating a kiwi concentrate combined gruels.

Study on Performance Comparison of MR Damper for Fluid Properties and Orifice Shapes (MR 유체물성과 오리피스 형상에 대한 MR 댐퍼 성능비교 연구)

  • Kwon, Young-Chul;Park, Sam-Jin;Kim, Ki-Young;Baek, Dae-Sung;Lee, Seok-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.15 no.3
    • /
    • pp.1305-1310
    • /
    • 2014
  • MR(Magneto-Rheological) damper generates the magnetic shear force due to the cohesiveness of MR fluid influenced by a magnetic field. MR fluid consists of magnetic particles and a base liquid. In the present study, the damping forces of MR damper were investigated for density 1.3, 1.5 and $1.7g/cm^3$, and viscosity 1000 and 10000cp, and for the change of orifice shapes. It was found that the increase in the density and viscosity of MR fluid could change the damping force of MR damper due to the magnetic effects. Also, the damping forces on orifice shapes increased as the orifice gap and length decreased. These results showed that the properties of MR fluid and orifice shapes were important for the optimum design of MR damper.

Effect of Aminosiloxane Modifier on Chemorheological Properties of Ortho-cresol Novolac Epoxy (Ortho-cresol Novolac형 에폭시의 화학레올로지 특성에 미치는 아민 개질제의 영향)

  • 김윤진;안병길;김우년;서광석;김환건;윤초규
    • Polymer(Korea)
    • /
    • v.26 no.1
    • /
    • pp.88-97
    • /
    • 2002
  • The effect of aminosiloxane modifier on the chemorheological properties of ortho-cresol novolac epoxy/phenol novelac/triphnylphosphine resin system was investigated aat different isothermal curing temperatures. By adding the aminosiloxane to the resin system, not only conversion rate and conversion were increased but also glass transition temperature was promoted. Critical conversion and gelation time obtained at the crossover point between storage and loss moduli were reduced and thus the viscosity was increased by the aminosiloxane. $C_1$ and $C_2$ in the WLF equation calculated from the glass transition temperature as a function of conversion and measured viscosity were found to vary with the curing temperature. By applying the change of glass transition temperature with conversion, $C_1$ and $C_2$ to WLF equation, it was possible to predict accurately the viscosity change with isothermal curing reaction.

Enhancement of Convective Heat Transfer by Using a Micro-Encapsulated Phase-Change-Material Slurry (피복된 미립 상변화물질 슬러리를 이용한 대류 열전달의 향상에 관한 연구)

  • Jung, Dong-Ju;Choi, Eun-Soo
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.24 no.9
    • /
    • pp.1277-1284
    • /
    • 2000
  • To enhance heat transfer characteristics of water, micro-encapsulated octadecane of about $10{\mu}m$ diameter was added to water. Viscosity of the slurry was measured by using a capillary tube viscometer. The measured viscosity decreased as the temperature of the slurry increased, and it increased as the fraction of the capsules in the slurry increased. Thermal characteristics of the octadecane were studied by using a differential scanning calorimeter. The melting temperature and the melting energy of the octadecane were found to be $28.6^{\circ}$ and 34.4kcal/kg, respectively. The convective heat transfer characteristics of the slurry were investigated in a flow loop with a constant heat flux test section. Friction factor of the slurry flow was found to be similar to the expected curve by Petukhov. The Nusselt number of the slurry flow was highest when the octadecane melted. Effective thermal capacity of the 14.2% slurry was found to have 1.67 times of the thermal capacity of water.