• Title/Summary/Keyword: viscosities

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The Viscoelastic Properties of Gelatin Hydrogel (Gelatin Gel의 점탄성에 관한 연구)

  • 정기용;김남희;유근희;정미원
    • YAKHAK HOEJI
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    • v.25 no.4
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    • pp.175-179
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    • 1981
  • Rheological studies on the gelatin hydrogels were carried out by rheometer. In the temperature range of $32^{\circ}~90{\circ}C$, the viscosities of the gelatin hydrogels were measured. In order to observe the formation of gel structure, the stress-relaxation tests of the creep-curves were investigated. The structure of viscoelastic substance could be considered of a three dimensional crosslinked matrix. As the result viscoelastic coefficients were obtained by Maxwell element, which are correspond to the network structure. From the relationship between the stress-relaxation time and temperature, activation energy correspond to breaking the formation of gels was calculated to be 13.91kcal/mole.

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Measurement of the Viscosity of Semi-Soild Foods by Extrusion Capillary Viscometer (Extrusion Capillary Viscometer를 이용한 반고체 식품의 점도 측정 방법)

  • 김길환;이부용;김동만
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.5
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    • pp.509-512
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    • 1991
  • Rheological property and apparent viscosity(η)of several semi-solid foods were measured with extrusion capillary viscometer. Apparent viscosities of several semi-solid foods ranged from 0.2714 Pa.s to 2.6453 Pa.s Rheological property of spread type semi-solid foods was pseudoplastic (with yield value). Especially, as the moisture content and temperature of Chungkook-jang spread increased, apparent viscosity decreased. On the contrary, as the added soybean oil content of Chungkook-jang spread increased, apparent viscosity also increased.

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A Simplified Phenomenological Theory of Viscosity for Liquid Metals

  • Kim, Won Su;Chae, Dong Sik
    • Bulletin of the Korean Chemical Society
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    • v.22 no.1
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    • pp.43-45
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    • 2001
  • This study simplifies the phenomenological theory of viscosity previously proposed by the present authors. This simplified theory has only two thermodynamic properties and one parameter, as opposed to its predecessor, which has many, allowing for easy calculation of the liquid viscosities. The viscosity of liquid metals, an excellent test for checking the validity of the liquid theory, can be calculated using the equation based on the simplified theory. The calculated results by the current theory turn out to be good for the liquid metals, including sodium, potassium, rubbidium, cesium, lead and mercury.

Photopolymerization of Methacrylic Acid with Phenylsilane

  • 우희권;박선희;홍란영;강행구;송순정;함희숙
    • Bulletin of the Korean Chemical Society
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    • v.17 no.4
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    • pp.376-379
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    • 1996
  • The bulk photopolymerization of methacrylic acid (MA) with phenylsilane was performed to produce poly(MA)s containing phenylsilyl moiety presumably as an end group. It was found that while the polymerization yields and intrinsic viscosities decreased, the TGA residue yields and the relative intensities of SiH IR stretching bands increased with increasing molar ratio of phenylsilane over MA. The phenylsilane seemed to significantly influence on the photopolymerization as both chain initiation and chain transfer agents.

A Calculation for the Viscosity of Liquid Metals

  • Kim, Won-Soo;Chair, Tong-Seek
    • Bulletin of the Korean Chemical Society
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    • v.11 no.5
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    • pp.446-449
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    • 1990
  • A phenomenological theory of viscosity which has been proposed by authors is applied to liquid metals for which the calculation is a severe test for liquid theories. The thermodynamic properties used in the calculations can be obtained by using the Roulette liquid theory. The calculated values of the viscosities for liquid metals are in good agreements with the observed values.

A Paradigm for the Viscosity of Fluids

  • Kim, Won-Soo;Chair, Tong-Seek;Pak, Hyung-Suk
    • Bulletin of the Korean Chemical Society
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    • v.9 no.4
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    • pp.213-217
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    • 1988
  • A new paradigm for the viscosity of fluid is presented by considering the fact that the viscosity is equal to the shear stress divided by the shear rate. The shear stress is obtained from the sum of kinetic and internal pressures of fluid, and the shear rate is found from the phonon velocity divided by the mean free path of the phonon. The calculated viscosities for various simple substances are in excellent agreements with those of the observed data through the wide temperature range covered both of liquid and gas phase.

Melt viscosity and Morphology of Reactive Blends (Coupling Agent를 이용한 Polyamide 6와 Polyester Elastomer의 반응동반 블랜드)

  • Byung Kyu Kim;Sang Hyun Baek;Lee Keun Yoon
    • The Korean Journal of Rheology
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    • v.11 no.1
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    • pp.50-56
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    • 1999
  • Melt blends of polyamide 6 (PA 6) with polyester elastomer (PEL) were prepared in a corotating twin screw extruder using two types of coupling agent(CA), viz. diglycidyl ether of bisphenol A (DGEBA) and 1,4-phenylene bis(2-oxazoline) (PBO). Notched impact strength of PA 6 as well as PA 6/PEL blends increased with the addition of coupling agent, especially with DGEBA and the maximum impact toughening of the blend was obtained with 0.6%(by mol) DGEBA, where a minimum domain size was observed from SEM. Melt viscosities of the untreated blends were higher than those of base resins at low frequencies. Viscosities of base resins as well as blends increased with the addition of CA, and the effect was much more pronounced with DGEBA, especially for PA 6 and PA 6-rich blends.

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Viscosities of Anilinium Chloride Solutions in Isopropanol-Water Mixtures (2-프로판올-물 혼합용매중의 Anilinium Chloride 용액의 점도에 관한 연구)

  • Byung-Rin Cho;Young-Ja Lee;Ikchoon Lee
    • Journal of the Korean Chemical Society
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    • v.17 no.1
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    • pp.10-14
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    • 1973
  • The relative viscosities ηr of anilinium chloride solutions in a series of isopropanol-water mixtures have been determined at $20^{\circ}$, $30^{\circ}$and $40^{\circ}$, using Ubbelohde-type viscometers. The viscosity data have been interpreted in terms of viscosity A-and B-coefficients calculated from the Jones-Dole equation,${\eta}{\tau}=1+AC^{1/2}+BC$. The energy of activation for viscous flow have also been calculated according to the concept of rate processes. The results indicate that at $0.10{\sim}0.15$ mole fraction isopropanol the maximum structuredness of water gives a minimum values of viscosity A-and B-coefficients, and that anilinium chloride belongs to the borderline case in respect of the structure-making or structure-breaking effects on water.

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A Study of Penetration Depth into Ceiling Materials containing Asbestos according to Dilution Rate of Scattering Prevention Agent (석면 함유 천장재의 안정화제 희석에 따른 침투깊이 연구)

  • Shin, Hyungyoo;Choi, Youngkue;Jeon, Boram;Ha, Jooyeon
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.25 no.1
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    • pp.82-88
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    • 2015
  • Objectives: This study is designed to analyze the penetration performance into ceiling materials containing asbestos of scattering prevention agents and investigate the change in penetration depth and viscosity according to the dilution rate of anti-scattering agents diluted with distilled water. Methods: Five different types of scattering prevention agents were spread on plate-type asbestos ceiling materials. The penetration depth of each coated ceiling material was measured by energy dispersive spectroscopy (EDS) analysis, based on X-ray fluorescence (XRF) results of the non-coated ceiling materials. Test equipment installed the ceiling materials and 60 minutes were collected at a flow rate of $10{\ell}/min$ at a filter of 25 mm. Results: An EDS analysis of the cross-section of ceiling materials constructed with a scattering prevention agent revealed that potassium is detected in the process of penetrating hardener solidification and this element could be an indicator for infiltration. When anti-scattering agents with different viscosities were constructed and the penetration depth was analyzed by potassium detection assessment using EDS, the depth results with viscosities of 5.0, 2.5, and 1.9 cP were 98.5, 103, and $147{\mu}m$, respectively. Penetration performance improved with decrease in viscosity. Conclusions: For asbestos ceiling materials, it is concluded that a higher dilution rate of the scattering prevention agent leads to lower viscosity, and hence a deeper penetration depth from $156{\mu}m$ to 3 mm. The asbestos anti-scattering properties according to the penetration depth will be confirmed through further study.

Fermentation of rice flour with Weissella koreensis HO20 and Weissella kimchii HO22 isolated from kimchi and its use in the making of jeolpyeon (김치유산균(Weissella koreensis HO20, Weissella kimchii HO22)으로 발효한 쌀가루의 이화학적 특성 및 이를 이용한 절편의 제조)

  • Choi, Hyejung;Lee, Hwawon;Yoon, Sun
    • Korean journal of food and cookery science
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    • v.29 no.3
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    • pp.267-274
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    • 2013
  • Demand for a rice cake, a popular traditional food in Korea, is rising, but its industrial-scale production is extremely difficult due to its short shelf-life caused by starch retrogradation and microbial spoilage. By means of the sourdough fermentation technique, we attempt to develop rice cakes with a longer shelf-life. Heterofermentative lactic acid bacteria (Weissella koreensis HO20, Weissella kimchii HO22) isolated from kimchi were used to ferment wet-milled rice flour for their abilities to produce exopolysaccharides and to inhibit the microbial spoilage of rice cakes. After 24 hr of fermentation at $25^{\circ}C$, viable cell counts in rice dough increased from $10^6$ CFU/g to $10^8$ CFU/g and total titratable acidity increased from 0.05% to 0.20%, whereas pH decreased from 6.5 to 5.1. Fermented rice flour showed significantly lower peak, trough, and final viscosities as well as breakdown and setback viscosities measured by rapid viscoanalyzer. Both lactic acid bacteria showed in vitro antifungal activity against Penicillium crustosum isolated from rice cakes. The antifungal activity remained constant after the treatments with heat, proteinase K and trypsin, but fell significantly by increase of pH. Rice cakes made of fermented rice flour were found to retard mycelial growth of P. crustosum. The degree of retrogradation as measured by the hardness of the rice cake was significantly reduced by the use of fermented rice flour. The results suggest that use of fermented rice flour has a beneficial role in retarding starch retrogradation and in preventing fungal growth, hence extending the shelf-life of rice cakes.