• 한국의류학회지
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• 제18권1호
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• pp.113-120
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• 1994

The Purpose of this study was to improve the moisture related properties of viscose rayon fibers. Viscose rayon filament yarns were partially etherified to make CMC fibers. CMC fibers were converted to the sodium, calcium, and ferric salt forms by an ion exchange method. The property changes of ion exchanged CMC fibers were examined. Cation contents of fibers were varied depending on the degree of substitution of CMC fibers. The strength of Na, Ca, Fe-CMC was higher than H-CMC owing to the plasticization by moisture sorption and the crosslinking by cations. The moisture regain was increased by carboxymethylation and that of Fe-CMC showed the highest value. The degree of swelling determined by the water retention value was observed to be Na-CMC > Ca-CMC > H-CMC > Fe-CMC. The solution retention value was decreased in the order . Ca-CMC > Na-CMC > H-CMC > Fe-CMC.

• 한국염색가공학회지
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• 제10권6호
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• pp.20-26
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• 1998

100％ viscose rayon fabric was treated with 1,2,3,4-butanetetracarboxylic acid (BTCA) by pad-dry-cure process in the presence of various catalysts. The dimensional stability, mechanical properties and hand values of fabric treated with BTCA were investigated. The ester-crosslinking reaction was influenced by the concentration of BTCA and type of catalyst. The fabric treated with BTCA was comparable or superior to that treated with conventional crosslinking agents such as dimethyloldihydroxyethyleneurea and 4,5-dihydroxy-1,3-dimethyl-2-imidazolidinone in respect of wrinkle recovery, shrinkproof property, retention of strength, and hand values. But in yellowing of fabric, the fabric treated with BTCA was inferior to that treated with conventional crosslinking agents. The fabric treated with BTCA/sodium formate was inferior to that treated with BTCA/sodium hypophosphite in respect of WRA, but had better strength retention and whiteness.

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1998년도 봄 학술발표회 논문집
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• pp.315-319
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• 1998

셀룰로오스 용매계는 크게 직접용매계와 간접용매계로 나뉠 수 있으며, 잘 알려진 "비스코스 레이온(viscose rayon)"공정은 공정 중간단계에 이황화탄소(CS$_2$)를 사용하여 셀룰로오스 크산테이트 유도체를 만들고 이를 다시 수산화나트륨에 용해시키는 간접용매계에 속한다. 수산화나트륨 수용액에 용해된 비스코스 용액은 응고 욕내에서 황산과 반응하여 셀룰로오스로 재생이 되는데 비스코스 용액의 재생과정에서 발생하는 이황화탄소는 그 자체가 독성이 심한 가연성 액체일 뿐만 아니라 부반응을 통하여 삼황화소다(sodium trithiocarbonate) 및 황화수소(H$_2$S)를 발생한다.(중략)

• Fibers and Polymers
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• 제5권1호
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• pp.44-51
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• 2004

Three bi-functional reactive dyes such as Bis(vinylsulphone) type, Bis(monochlorotriazine) type and Bis(mononicotinotriazine) type were applied to regular viscose rayon and new regenerated cellulosic fiber ($enVix^ⓡ$) which was prepared from cellulose acetate fiber by the hydrolysis of acetyl groups, and their dyeing properties and fastness properties were compared. enVix exhibited better dyeability and fastness than regular viscose rayon and these results were also explained by the differences in the supramolecular structure of these two fibers.

• Journal of the Korean Wood Science and Technology
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• 제25권4호
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• pp.45-50
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• 1997

This research was studied for dissolving pulp preparation as the raw material of viscose rayon from woody biomass by solvolysis pretreatment. In the change of pulp characteristic after solvolysis pretreatment, the following results were obtained. In the case of solvolysis pretreatment, we have obtained pulp that high purity cellulose, and degree of polymerization was inclined to decrease less than 440 on the phosphoric acid as catalyst. Comparing phosphoric acid and formic acid as catalyst in the solvolysis pretreatment, using on formic acid catalyst is superior to phosphoric acid catalyst for making dissolving pulp.

• 한국의류학회지
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• 제29권3_4호
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• pp.470-477
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• 2005

This study was carried out to evaluate the biodegradability of viscose rayon and lyocell fibers, employing soil burial test, activated sludge test and enzymatic hydrolysis. Using X-ray analysis, crystallinity and morphology change was investigated. External changes after degradation were also observed by SEM and digital photographs. Vscose rayon fibers exhibited higher biodegadation than lyocell fibers, indicating that lower crystallinity favored the biodegradation. Among the biodegradability of lyocell fibers there was a tendency that fibers with lower crystallinity and higher moisture regain had higher values. When external changes after degradation being observed, it was shown that there were microorganisms growing on the surfaces of samples accompanying lading and weakening. From these results it was concluded that biodegradability of the specimens was most closely correlated to the moisture regain and crystallinity of fibers which reflects hydrophilicity and internal structure.

• 패션비즈니스
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• 제24권3호
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• pp.30-39
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• 2020

This study was conducted to identify problems in domestic flame-retardant performance specifications. Currently, the domestic wallcovering anti-inflammatory regulations are not prepared for damage caused by smoke, with the carbonized area as the main function. In particular, given that smoke is the main cause of human casualties and injuries in a fire, it is reasonable that the flame density and toxicity of the wallcovering should also be the main performance indicators. The scope and method of research in this study were as follows. First, a prior study related to fire on various wallcoverings was considered. Second, it raised questions about the effects of smoke in the event of a fire and domestic anti-inflammatory performance tests. Third, textile wallcovering samples were manufactured with viscose rayon for experimental verification of the problems and tested by Korean and EU standards without flame retardant processing to analyze the differences between each regulation. Fourth, the performance of flame retardant wallcovering according to Korean standards was evaluated using smoke density and harmful gas testing methods. The results of each test were as follows. Non-fire retardant wallcovering was rejected by Korea standards. However, B-s1.d0 in Europe. Smoke density testing and harmful gas by domestic combustion processing on the same sample showed that the smoke density increased about 4.3 times more than before, and the harmful gas test showed that the suspension of the post-processing sample slowed earlier than the non-processed sample.

• 패션비즈니스
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• 제12권1호
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• pp.120-128
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• 2008

Rayon fiber as clothing material has silk-like property which relates to other synthetic fibers. It has many advantages that is required to women's clothes. However rayon has many shortcomings. Therefore this research is to spin rayon-like polyester which has high contraction property to be synthesized by previous research to solve those shortcomings and to maintain advantages of rayon. The contraction ratio of regular polyester is 30% and the contraction ratio of this synthesized polyester is over 60%. The spinning temperature of regular polyester ranges from $285^{\circ}C$ to $300^{\circ}C$. However, this copolymer is set range from $270^{\circ}C$ to $290^{\circ}C$, which is $10^{\circ}C$ less than regular polyester due to decreasing melting temperature. The spinning velocity effects the tensile strength and elongation of yarn magnificently. The high velocity of spinning makes yarn highly oriented, increases the tensile strength and decreases the elongation. This research defines the condition as following; draw ratio 2.734, First roller temperature $85^{\circ}C$, Slit heater temperature $175^{\circ}C$.

• 청정기술
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• 제11권2호
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• pp.105-116
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• 2005

본 연구는 NaOH 용액에 의한 머서화(mercerization) 반응과 모노클로로아세트산에 의한 에테르화 반응에 의해 carboxymethylcellulose(CMC)를 제조하고 각 제조단계에서의 반응시간, 시약 농도, 온도 등을 변수로 설정하여 결과물에 대한 영향을 고찰하였다. 제조된 샘플을 용해도와 카르복실기의 치환도를 통해 분석하였으며 부직포로서의 응용을 위해 제조된 수용성 섬유의 인장강도를 알아보았다. 섬유의 표면 변화는 SEM(scanning electron microscope) 사진을 통해 알아보았다. 제조된 섬유는 30분 이내에 80% 이상 용해되었으며 반응시간이나 반응 온도보다 시약의 농도에 의한 영향이 더욱 컸다. 또한 용해도가 80% 이상이었던 시편은 0.6 ~ 0.7의 치환도를 보였으며 모노클로로아세트산의 농도의 영향이 가장 크며 용해도가 증가할수록 치환도가 증가하는 경향을 보였다.

• 한국염색가공학회:학술대회논문집
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• 한국염색가공학회 2011년도 제44차 학술발표회
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• pp.101-101
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• 2011

재생 셀룰로스 섬유의 원료로 사용되는 셀룰로스는 면, 마, 목재 등 고등식물의 주성분으로 매년 수십억톤이 광합성에 의하여 생산되어지고 있다. 따라서 석유류와 같은 화석연료의 가격 변동에 영향을 받지 않고 안정적으로 수입되고 있다. 또한, 셀룰로스에는 면이나 마류 등과 같이 간단한 정제 처리에 의해 의류용 섬유로서 사용될 수 있는 것과 목재 섬유와 같이 펄프화하여 종이, 인견섬유, 필름 등으로 사용되어지는 것이 있으며, 셀룰로스 유도체도 제조할 수 있다. 현재까지 개발된 섬유들 중 대표적인 셀룰로스계 재생섬유인 비스코스 레이온(Viscose rayon)은 그 제조 방법이 환경적으로 치명적인 문제를 안고 있으나 고유의 우수한 드레이프성, 흡습성, 독특한 광택, 시원한 촉감 등을 가지고 있어 그 소비는 꾸준한 상황이다. 이러한 Viscose rayon을 대체하기 위하여 친환경적인 공법을 이용하여 개발된 Lyocell 제품이 각광을 받고 있다. 면 셀룰로스 재생섬유는 기존의 Lyocell섬유에 비해 신도는 높고 모듈러스가 낮아 Modal과 같은 촉감을 가지고, 피브릴 발생이 없어 방사공정에서 가교반응이 필요치 않는 것으로 기대된다. 친환경 공법인 Lyocell 공법으로 개발된 면 린터 원료를 이용하여 면 린터 셀룰로스 재생섬유 제조기술을 개발하고자 한다. 따라서 본 연구에서는 면 린터 셀룰로스 재생섬유의 기술적인 신뢰성을 검증하기 위해 면 린터 셀룰로스 재생섬유소재 피브릴화 정도의 표준화 시험법을 연구하고자 한다. 사용원단으로 Tencel A-100, Tencel standard, Modal, Lyocell LF, 면 린터 섬유를 사용하였으며, 세탁, 염색, 알칼리조건 처리에 따른 물성 변화를 알아보았다. 물성 변화는 전자현미경으로 측정하였다.