• Korea-Australia Rheology Journal
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• v.14 no.3
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• pp.129-138
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• 2002

A cationic surfactant, cetyltrimethylammonium $\rho$-toluenesufonate (CTA$\rho$TS), forms long threadlike micelles in aqueous solution. The threadlike micelles make concentrated entanglement networks, so that the solution shows pronounced viscoelastic behavior as concentrated polymer systems do. However, a mechanism for a process responsible for the longest relaxation time of the threadlike micellar system is different from that of semi-dilute to concentrated polymer systems. The threadlike micellar system exhibits unique viscoelasticity described by a Maxwell model. The longest relaxation time of the threadlike micellar system is not a function of the concentration of CTA$\rho$TS, but changes with that of $\rho$-toluenesufonate ($\rho$$TS^{-}$) ions in the bulk aqueous phase supplied by adding sodium $\rho$-toluenesulfonate (NapTS). The rates of molecular motions in the threadlike micelles are not influenced by the concentration of $\rho$$TS^{-}$ anions, therefore, molecular motions in the threadlike micelles (micro-dynamics) are independent of the longest relaxation mechanism (macro-dynamics). A nonionic surfactant, oleyldimethylamineoxide (ODAO), forms long threadlike micelles in aqueous solution without any additives. The aqueous threadlike micellar system of ODAO also shows Maxwell type viscoelastic behavior. However, the relaxation mechanism for the longest relaxation process in the system should be different from that in the threadlike micellar systems of CTA$\rho$TS, since the system of ODAO does not contain additive anions. Because increase in the average degree of protonation of head groups of ODAO molecules in micelles due to adding hydrogen bromide causes the relaxation time remarkably longer, changes in micro-structure and micro-dynamics in the threadlike micelle are closely related to macro-dynamics in contrast with the threadlike micellar system of CTA$\rho$TS.

• International Journal of Fluid Machinery and Systems
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• v.2 no.4
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• pp.269-277
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• 2009

The current paper focuses on the analysis of transient cavitating flow in pressurised polyethylene pipes, which are characterized by viscoelastic rheological behaviour. A hydraulic transient solver that describes fluid transients in plastic pipes has been developed. This solver incorporates the description of dynamic effects related to the energy dissipation (unsteady friction), the rheological mechanical behaviour of the viscoelastic pipe and the cavitating pipe flow. The Discrete Vapour Cavity Model (DVCM) and the Discrete Gas Cavity Model (DGCM) have been used to describe transient cavitating flow. Such models assume that discrete air cavities are formed in fixed sections of the pipeline and consider a constant wave speed in pipe reaches between these cavities. The cavity dimension (and pressure) is allowed to grow and collapse according to the mass conservation principle. An extensive experimental programme has been carried out in an experimental set-up composed of high-density polyethylene (HDPE) pipes, assembled at Instituto Superior T$\acute{e}$cnico of Lisbon, Portugal. The experimental facility is composed of a single pipeline with a total length of 203 m and inner diameter of 44 mm. The creep function of HDPE pipes was determined by using an inverse model based on transient pressure data collected during experimental runs without cavitating flow. Transient tests were carried out by the fast closure of the ball valves located at downstream end of the pipeline for the non-cavitating flow and at upstream for the cavitating flow. Once the rheological behaviour of HDPE pipes were known, computational simulations have been run in order to describe the hydraulic behaviour of the system for the cavitating pipe flow. The calibrated transient solver is capable of accurately describing the attenuation, dispersion and shape of observed transient pressures. The effects related to the viscoelasticity of HDPE pipes and to the occurrence of vapour pressures during the transient event are discussed.

• Applied Chemistry for Engineering
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• v.24 no.1
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• pp.24-30
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• 2013

The adsorption characteristics of cationic starches and starch-oligomers were investigated using the quartz crystal microbalance with dissipation monitoring (QCM-D). The adsorbed amount of modified starches was higher than that of cationic surfactants such as $C_{12{\sim}16}$ trimethylammonium bromide. Cationic starches did not show the tendency depending on the degree of cationic substitution and molecular weight. On the other hand, the softness of the adsorption layer increased with the molecular weight of cationic starches in a viscoelasticity terms. During the adsorption/desorption steps, the amount of adsorbed cationic surfactants was 4~9 times. On the other hand, the difference in the amount of adsorption of all the $C_1$ grafted cationic starches was just 0~50%. In addition, the rigidity of the adsorption layer of cationic surfactant in the desorption step decreased, while, that of cationic starches increased at the same condition.

• Polymer(Korea)
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• v.25 no.4
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• pp.536-544
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• 2001

We investigate, in the viewpoint of mathematical stability, the validity of the time-strain separability hypothesis employed in polymer viscoelasticity on the basis of experimental results. There have been suggested two distinct stability criteria such as Hadamard related to quick response and dissipative stability conditions, and in the limit of high deformation rate we have proved that separable constitutive equations are either Hadamard or dissipative unstable. The fact that the separability is not valid in the short time region in stress relaxation experiments exactly coincides with the results of our analysis. Therefore, since the application of the separability hypothesis incurs thermodynamic inconsistency as well as mathematical instability, such application should be avoided in the formulation of constitutive equations. In addition, careful attention should be paid to the limit of its validity even in experiments. It is also proved that there is neither theoretical nor physical validity of using the damping function.

• Journal of the East Asian Society of Dietary Life
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• v.18 no.1
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• pp.80-86
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• 2008

Both hand-made and machine-made Chinese noodles are popular in Korea. In this study, each type was evaluated in terms of its physical properties to rigorously determine for consumers which one has better qualities. The noodles were instrumentally measured for color, size, moisture content, density, viscoelasticity, and cutting force. The behaviors of the noodles were visually observed during cooking, and sensory evaluations were performed with the cooked noodles. The hand-made raw noodles were less dense, had higher moisture content, and generated more bubbles during cooking than the machine-made noodles. This indicated that the hand-made noodles contained more entrapped air, thereby resulting in the above physical characteristics. The change in noodle size after cooking was greater in the hand-made noodles, indicating that more entrapped air in expansion escaped during cooking and was replaced by water. The cutting force and viscoelasticity of the hand-made noodles were lower, and were controlled by viscous properties, respectively. These results agreed with the fact that the hand-made noodles had higher moisture content and lower density. In the sensory evaluation, the hand-made noodles presented lower hardness, but higher elasticity. It was inferred that the hand-made noodle dough underwent repeated processes of folding and extending, resulting in better developed of the gluten structure. Consequently, the hand-made noodles were determined to be different than the machine-made noodles in terms of instrumental measurements and sensory observations, suggesting that the hand-made noodles had superior textural properties.

• Journal of the Korean Society of Propulsion Engineers
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• v.17 no.2
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• pp.57-62
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• 2013

A crack in a solid propellant increases the area of burning surface, which leads to excessive burning that causes motor failure. Therefore, it is necessary to evaluate fracture toughness of solid propellants. However, it is very difficult to measure fracture toughness of solid propellants because of the nonlinear mechanical behavior. In this study, evaluation of fracture toughness on a solid propellant was carried out under the assumption that the solid propellant is a linear viscoelastic material. Actual displacements from fracture toughness tests using CCT specimens were converted into pseudo-elastic displacements by using stress relaxation characteristics and fracture toughness was evaluated using ASTM E399 standard. Also, effects of test temperature and speed on the fracture toughness were considered.

• Food Science of Animal Resources
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• v.42 no.3
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• pp.441-454
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• 2022

This study aimed to determine the effect of enzyme, guar gum, and pressure processing on the digestibility and physicochemical properties of age-friendly liver sausages. Liver sausages were manufactured by adding proteolytic enzyme (Bromelain) and guar gum, and pressure-cooking (0.06 MPa), with the following treatments: control, without proteolytic enzyme; T1, proteolytic enzyme; T2, proteolytic enzyme and guar gum; T3, pressure-cooking; T4, proteolytic enzyme and pressure-cooking; T5, proteolytic enzyme, guar gum, and pressure-cooking. The pH was high in the enzyme- and pressure-processed groups. The pressure-processed groups had lower apparent viscosity than other cooking groups, and it decreased during enzyme treatment. Hardness was lower in the enzyme- and pressure-processed groups than in the control, and the T4 was the lowest. Digestibility was the highest in T4 at 82.58%, and there was no significant difference with that in T5. The general cooking group with enzyme and guar gum also showed higher digestibility than the control (77.50%). As a result of the sodium dodecyl sulfate-polyacrylamide gel electrophoresis, the enzyme- and pressure-treated groups (T4, T5) were degraded more into low-molecular-weight peptides (≤37 kDa) than the control and other treatments. Viscoelasticity showed similar trends for viscous and elastic moduli. Similarly, combined pressure processing and enzymatic treatment decreased viscoelasticity, while guar gum increased elasticity but decreased viscosity. Therefore, the tenderized physical properties and improved digestibility by enzyme and pressurization treatment could be used to produce age-friendly spreadable liver sausages.

• Composites Research
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• v.36 no.3
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• pp.141-153
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• 2023

This review paper presents an introduction of contact mechanics and rubber friction theory for sliding friction of elastomer composites in contact with rough surfaces. Particularly, Klüppel & Heinrich theory considers the self-affine (or fractal) characteristic for rough surfaces to predict adhesion and hysteresis frictions of elastomers based on the contact mechanics of Greenwood & Williamson. Due to dynamic excitation process of elastomer composites while sliding in contact with multiscale surface roughness (or asperity), viscoelastic properties in a wide frequency range becomes major contributor to friction behaviors. A brief description and examples are provided to construct a viscoelastic master curve considering nonlinear viscoelasticity of elastomer composites. Finally, application of rubber friction theory to tire tread compounds in traction with road surfaces is discussed with several experimental and theoretical results.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.26 no.3A
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• pp.429-437
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• 2006

Existing basic mechanical models which are methods characterizing viscoelastic materials were first reviewed to account for viscoelastic behavior of the asphalt pavement structure in this paper. A viscoelastic mechanical model considering a single load of vehicles subsequently was suggested and an equation that indicates the time-dependant behavior of asphalt pavements was derived from the proposed model. Non-destructive tests using falling weight deflectometer(FWD) were performed for a test section to estimate the application of the model. Both deflections and strains procured by the equation were compared to testing results according to loading history. By observing field measurements and theoretical evaluations, if two results are compared by the features of deflection according to time history, it could be concluded that the proposed model is expected to be suitable for prediction of the behavior of asphalt pavements because there is hardly difference between field data and calculated data.

• Journal of applied mathematics & informatics
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• v.25 no.1_2
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• pp.51-66
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• 2007

A layer of compressible, rotating, elastica-viscous fluid heated & soluted from below is considered in the presence of vertical magnetic field to include the effect of Hall currents. Dispersion relation governing the effect of viscoelasticity, salinity gradient, rotation, magnetic field and Hall currents is derived. For the case of stationary convection, the Rivlin-Erickson fluid behaves like an ordinary Newtonian fluid. The compressibility, stable solute gradient, rotation and magnetic field postpone the onset of thermosolutal instability whereas Hall currents are found to hasten the onset of thermosolutal instability in the absence of rotation. In the presence of rotation, Hall currents postpone/hasten the onset of instability depending upon the value of wavenumbers. Again, the dispersion relation is analyzed numerically & the results depicted graphically. The stable solute gradient and magnetic field (and corresponding Hall currents) introduce oscillatory modes in the system which were non-existent in their absence. The case of overstability is discussed & sufficient conditions for non-existence of overstability are derived.