• Elastomers and Composites
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• v.54 no.3
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• pp.225-231
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• 2019

Bio-based polyester polyol was synthesized via esterification between azelaic acid and isosorbide. After esterification, bio-based polyurethanes were synthesized using polyester polyol, 1,3-propanediol as the chain extender, and 4,4'-diphenylmethane diisocyanate, in mixing ratios of 1:1:1.5, 1:1:1.8, 1:1:2, and 1:1:2.3. The bio TPU (Thermoplastic Polyurethane) samples were characterized by using FT-IR (Fourier Transform Infrared Spectroscopy), TGA (Thermal Gravimetric Analysis), DSC (Differential Scanning Calorimetry), and GPC (Gel Permeation Chromatography). The mechanical properties (tensile stress and hardness) were obtained by using UTM, a Shore A tester, and a Taber abrasion tester. The viscoelastic properties were tested by an Rubber Processing Analyzer in dynamic strain sweep and dynamic frequency test modes. The chemical resistance was tested with methanol by using the swelling test method. Based on these results, the bio TPU synthesized with the ratio of 1:1:2.3, referred to as TPU 4, showed the highest thermal decomposition temperature, the largest molecular weight, and most compact matrix structure due to the highest ratio of the hard segment in the molecular structure. It also presented the highest tensile strength, the largest elongation, and the best viscoelastic properties among the different bio TPUs synthesized herein.

• Korea-Australia Rheology Journal
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• v.13 no.2
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• pp.67-81
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• 2001

The development of new techniques for the dynamic measurement of linear viscoelastic properties is an active area of rheometry, and this paper surveys some novel deformation geometries which have been recently reported e.g. oscillating probe-type devices which are imbedded in or placed on the surface of the sample. Small amplitude band-limited pseudorandom noise is used for the displacement signal, with Fourier analysis of the complex waveform of the resistance force yielding the frequency dependent viscoelastic material functions (e.g. storage and loss moduli G", G"). Theoretical calculations of the fundamental equations relating force to displacement and instrument geometry, were carried out with the aid of the correspondence principle of linear viscoelasticity. The rapidity of the tests and flexibility in terms of sample preparation and stiffness mean that this basic technique should find many applications in rheometry. Three examples of oscillatory tests are presented in detail squeeze flow, imbedded needle and concentric sliding cylinder geometries.eometries.

• Structural Engineering and Mechanics
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• v.70 no.2
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• pp.179-197
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• 2019

In this article, the effect of different geometrical, materials and load parameters on the transient response of axisymmetric viscoelastic functionally graded annular plates with different boundary conditions are studied. The behavior of the plate is assumed the elastic in bulk and viscoelastic in shear with the standard linear solid model. Also, the graded properties vary through the thickness according to a power law function. Three types of mostly applied transient loading, i.e., step, impulse, and harmonic with different load distribution respect to radius coordinate are examined. The motion equations and the corresponding boundary conditions are extracted by applying the first order shear deformation theory which are three coupled partial differential equations with variable coefficients. The resulting motion equations are solved analytically using the perturbation technique and the generalized Fourier series. The sensitivity of the response to the graded indexes, different transverse loads, aspect ratios, boundary conditions and the material properties are investigated too. The results are compared with the finite element analysis.

• Journal of the Society of Naval Architects of Korea
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• v.45 no.1
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• pp.73-80
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• 2008

An improved method to measure the dynamic viscoelastic properties of elastomers is proposed. The method is based on the analysis of forced oscillation of a cylindrical sample loaded with inertial mass. No special equipment or instrumentation other than the ordinary vibration measurement apparatus is required. Typical measurement of the viscoelastic properties of a silicone rubber $Silastic^{(R)}$ S2 were measured over the wide frequency range from 10 Hz to 3 kHz under the action of wide region of deformation from $10^{-4}%$ to 5%. It was shown that modulus of elasticity and loss tangent fall on the single curves when the ratio of load mass to sample mass changed from 1 to 20.

• Steel and Composite Structures
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• v.24 no.4
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• pp.499-512
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• 2017

This paper deals with nonlinear dynamic stability of embedded piezoelectric nano-composite separators conveying pulsating fluid. For presenting a realistic model, the material properties of structure are assumed viscoelastic based on Kelvin-Voigt model. The separator is reinforced with single-walled carbon nanotubes (SWCNTs) which the equivalent material properties are obtained by mixture rule. The separator is surrounded by elastic medium modeled by nonlinear orthotropic visco Pasternak foundation. The separator is subjected to 3D electric and 2D magnetic fields. For mathematical modeling of structure, three theories of classical shell theory (CST), first order shear deformation theory (FSDT) and sinusoidal shear deformation theory (SSDT) are applied. The differential quadrature method (DQM) in conjunction with Bolotin method is employed for calculating the dynamic instability region (DIR). The detailed parametric study is conducted, focusing on the combined effects of the external voltage, magnetic field, visco-Pasternak foundation, structural damping and volume percent of SWCNTs on the dynamic instability of structure. The numerical results are validated with other published works as well as comparing results obtained by three theories. Numerical results indicate that the magnetic and electric fields as well as SWCNTs as reinforcer are very important in dynamic instability analysis of structure.

• Elastomers and Composites
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• v.45 no.4
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• pp.250-255
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• 2010

From the three element non-Newtonian model of one non-Newtonian viscoelastic Maxwell elements and a elastic spring, the stress relaxation equation was derived. The various model parameters of this equation were evaluated by appling the experimental results of stress relaxation to the stress relaxation equation. The theoretical curves calculated from this model parameters agreed with the experimental stress relaxation curves. From the parameters of nonlinear viscoelastic model, the hole volume, fine structure, viscoelastic properties and mechanical properties of polymer fibers were studied. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The stress relaxation curves of the two types polyacrylonitrile-polyvinylchloride copolymer and another two types PVC monofilament fibers were obtained in air and water of various temperatures.

• Journal of the Korean Society for Precision Engineering
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• v.20 no.1
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• pp.172-178
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• 2003

Two types of bolted lap joints, one with a viscoelastic layer and the other without the viscoelastic layer were chosen to analyze the dynamic characteristics of the joints with the mechanical properties of the bolts in the joints are considered as computational variables. The finite element method was used along with the modal testing to verify the PEM model. The results in the bolted lap joints reveal that the higher the Young's modulus for the bolts we use the higher the natural frequencies we obtain fur the joints. However, the natural frequency differences in the first and second mode are not substantial but become noticeable in the higher modes. Lower natural frequencies were obtained for the bolted lap joints with the viscoelastic layer when compared with those of the bolted lap joints without the viscoelastic layer. And the differences in the natural frequencies for the two types of joints are relatively small in the first and second mode whereas in the higher mode the differences become significant. The loss factors were observed to be significant especially in the second mode for the bolted lap joints with the viscoelastic layer.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.13 no.2
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• pp.132-143
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• 2003

Viscoelastic components for vibration isolation or shock absorption in automobiles, machines and buildings are often subject to a high level of static deformation. From the dynamic design point of view, it is requisite to predict dynamic complex stiffness of viscoelastic components accurately and efficiently. To this end, a systematic procedure for complex modulus measurement of the viscoelastic material under large static deformation is often required in the industrial fields. In this paper, dynamic test conditions and procedures for the viscoelastic material under small oscillatory load superimposed on large static deformation are discussed. Various standard test methods are investigated in order to select an adequate test methodology. The influence of fixed boundary condition in the compression tests upon complex stiffness are investigated and an effective correction technique is proposed. Then the uniaxial tension and compression tests are performed and its results are compared with analysis results from conventional constitutive models.

• Proceedings of the KSME Conference
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• 2001.06b
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• pp.624-629
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• 2001

Two types of bolted lap joints, one with a viscoelastic layer and the other without the viscoelastic layer were chosen to analyze the dynamic characteristics of the joints with the mechanical properties of the bolts of the joints being taken as computational variables. The finite element method was used along with the impact hammer technique to verify the FEM model. The results in the bolted lap joints reveal that the higher the Young's Modulus for the bolts are the higher the natural frequencies results for the joints. However, the natural frequency differences in the first and second mode are not substantial but become noticeable in the higher modes. Lower natural frequencies were obtained for the bolted lap joints with the viscoelastic layer when compared with those of the bolted lap joints without the viscoelastic layer. And the differences in the natural frequencies for the two types of joints are relatively small in the first and second mode whereas in the higher mode the differences become significant. The loss factors were observed to be significant especially in the second mode for the bolted lap joints with the viscoelastic layer.

• Journal of Pharmaceutical Investigation
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• v.29 no.4
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• pp.295-307
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• 1999

Using a Rheometries Fluids Spectrometer (RFS II), the dynamic viscoelastic properties of aqueous poly(ethylene oxide) (PEO) solutions in small amplitude oscillatory shear flow fields have been measured over a wide range of angular frequencies. The angular frequency dependence of the storage and loss moduli at various molecular weights and concentrations was reported in detail, and the result was interpreted using the concept of a Deborah number De. In addition, the experimentally determined critical angular frequency at which the storage and loss moduli become equivalent was compared with the calculated characteristic time (or its inverse value), and their physical significance in analyzing the dynamic viscoelastic behavior was discussed. Finally, the relationship between steady shear flow and dynamic viscoelstic properties was examined by evaluating the applicability of some proposed models that describe the correlations between steady flow viscosity and dynamic viscosity, dynamic fluidity, and complex viscosity. Main results obtained from this study can be summarized as follows: (1) At lower angular frequencies where De<1, the loss modulus is larger than the storage modulus. However, such a relation between the two moduli is reversed at higher angular frequencies where De>l, indicating that the elastic behavior becomes dominant to the viscous behavior at frequency range higher than a critical angular frequency. (2) A critical angular frequency is decreased as an increase in concentration and/or molecular weight. Both the viscous and elastic properties show a stronger dependence on the molecular weight than on the concentration. (3) A characteristic time is increased with increasing concentration and/or molecular weight. The power-law relationship holds between the inverse value of a characteristic time and a critical angular frequency. (4) Among the previously proposed models, the Cox-Merz rule implying the equivalence between the steady flow viscosity and the magnitude of the complex viscosity has the best validity. The Osaki relation can be regarded to some extent as a suitable model. However, the DeWitt, Pao and HusebyBlyler models are not applicable to describe the correlations between steady shear flow and dynamic viscoelastic properties.