• Composites Research
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• v.19 no.3
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• pp.15-22
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• 2006

In this study, we prepared glass fiber reinforced polypropylene composites using Brabender twin-screw extruder. Compatibilizer, polypropylene-based maleic anhydride (PP-g-MAH), was used to increase the molecular interaction between polypropylene matrix and glass fiber and to enhance melt processability. We also measured the shear and uniaxial elongational behaviors of glass-fiber reinforced composites in the absence or presence of compatibilizer. The effects of compatibilizer and fiber loading on the viscoelastic behaviors were examined. It was fuund that the PP-g-MAH compatibilizer improved the fluidity and increased the molecular bonding of composite melts in shear flow. Transient elongational viscosity was increased with fiber loadings in uniaxial elongational flow However, it was decreased with increasing elongational rates because of microscale shear flow between fibers.

• Korea-Australia Rheology Journal
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• v.15 no.3
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• pp.131-150
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• 2003

A new numerical algorithm of finite element methods is presented to solve high Deborah number flow problems with geometric singularities. The steady inertialess planar 4 : 1 contraction flow is chosen for its test. As a viscoelastic constitutive equation, we have applied the globally stable (dissipative and Hadamard stable) Leonov model that can also properly accommodate important nonlinear viscoelastic phenomena. The streamline upwinding method with discrete elastic-viscous stress splitting is incorporated. New interpolation functions classified as rational interpolation, an alternative formalism to enhance numerical convergence at high Deborah number, are implemented not for the whole set of finite elements but for a few elements attached to the entrance comer, where stress singularity seems to exist. The rational interpolation scheme contains one arbitrary parameter b that controls the singular behavior of the rational functions, and its value is specified to yield the best stabilization effect. The new interpolation method raises the limit of Deborah number by 2∼5 times. Therefore on average, we can obtain convergent solution up to the Deborah number of 200 for which the comer vortex size reaches 1.6 times of the half width of the upstream reservoir. Examining spatial violation of the positive definiteness of the elastic strain tensor, we conjecture that the stabilization effect results from the peculiar behavior of rational functions identified as steep gradient on one domain boundary and linear slope on the other. Whereas the rational interpolation of both elastic strain and velocity distorts solutions significantly, it is shown that the variation of solutions incurred by rational interpolation only of the elastic strain is almost negligible. It is also verified that the rational interpolation deteriorates speed of convergence with respect to mesh refinement.

• Polymer(Korea)
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• v.34 no.3
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• pp.226-236
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• 2010

UV irradiated acrylic pressure sensitive adhesives(PSAs) are prepared to be used for thermal pad in plasma display panel(PDP). The effect of the chemical structure of side-chain in comonomer and of crosslinking agent on wet-out property of acrylic PSAs in wide temperature range were investigated. The correlationship between viscoelastic behavior and adhesion properties, such as tack and peel strength, was also studied. The experimental results supported that wet-out and adhesion properties of acrylic PSAs were enhanced inversely proportional to side-chain length of comonomer in wide temperature range. The peel energy clearly increased in acrylic PSAs prepared by using di(ethylene glycol) dimethylacrylate (DEGDMA) for crosslinking agent. The results might be due to the difference in the glass transition temperature and viscoelastic behavior of acrylic PSAs.

• Transactions of the Korean Society of Automotive Engineers
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• v.4 no.5
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• pp.206-214
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• 1996

Because of the wide variety of the composite materials, inherent variability in properties, and complex temperature and strain rate dependence, large strain behavior of these materials has not been well characterized. Large strain behavior under uniaxial tension is characterized over a range of temperatures and strain rates, and a modified simple linear viscoelastic model is fit to the observed data. Of particular importance is the strain rate and temperature dependence of these composites, and it is the primary focus of this study. The strain rate and temperature dependence is then used to predict limiting tensile strains, based on Marciniak imperfection theory. Excellent correlation was obtained between model and experiment and the results are summarized in maps of forming limit as a function of strain rate and temperature.

• Proceedings of the Korea Concrete Institute Conference
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• 2001.11a
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• pp.1097-1102
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• 2001

Seismic safety of continuous span concrete bridge can be enhanced by distributing a large seismic lateral load to each supporting pier. A new viscoelastic device called Shock Transmission Unit(STU), which is a simple cylinder-piston assembly packed with a so-called silicone putty compound, enables the lateral seismic load to be transmitted to the pier by installation of the device to movable bearings of the bridge. The seismic safety of concrete bridges having the STU depends on not only safety of the bridges globally but also safety of anchor systems which anchors the STU to concrete pier. An experimental investigation is performed to study the behavior of cast-in-place anchor and post-installed anchor subjected to shear load statically and cyclically according to different edge distance, embedment length, and anchor spacing. Finally, the experimental results are compared with results by design methods of ACI and CCD, and results by FEM analysis.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.3
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• pp.184-191
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• 2000

Properties of pad are investigated to find the relationship between the chemical mechanical polishing(CMP) results, such as material removal rate and within wafer non-uniformity(WIWNU), and its properties. Polishing pressure is considered as important factors to affect the results, so behavior of ordinary polymer is studied to define the polishing result affecting properties of pad. Experimental setup is devised to identify the behavior of pad and several different pads are used in chemical mechanical polishing experiments to verify the correlations between pad properties and polishing results. The results indicate that the viscoelastic properties of pad had relationships with the polishing results, and shows correlation between suggested properties of pad and polishing result.

• Computers and Concrete
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• v.5 no.4
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• pp.295-328
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• 2008

A previously published multiscale model for early-age cement-based materials [Pichler, et al.2007. "A multiscale micromechanics model for the autogenous-shrinkage deformation of early-age cement-based materials." Engineering Fracture Mechanics, 74, 34-58] is extended towards upscaling of viscoelastic properties. The obtained model links macroscopic behavior, i.e., creep compliance of concrete samples, to the composition of concrete at finer scales and the (supposedly) intrinsic material properties of distinct phases at these scales. Whereas finer-scale composition (and its history) is accessible through recently developed hydration models for the main clinker phases in ordinary Portland cement (OPC), viscous properties of the creep active constituent at finer scales, i.e., calcium-silicate-hydrates (CSH) are identified from macroscopic creep tests using the proposed multiscale model. The proposed multiscale model is assessed by different concrete creep tests reported in the open literature. Moreover, the model prediction is compared to a commonly used macroscopic creep model, the so-called B3 model.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.661-664
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• 2006

As polymer concrete become more widely used by design engineers, it is important that the viscoelastic mechanical behavior of these materials is properly taken into account. Also, an important consideration in the design of polymer concrete is the behavior of creep according to ages of polymer concrete. In this study, flexural creep test was performed on recycled-PET polymer concrete. An method of accelerating the flexural creep tests, called the two-point method, was developed. The two-point method uses the results of three 24-hours creep tests performed at elevated temperatures to develop a Prony series equation that predicts the long-term creep strains at room temperature. The test results demonstrated that two-point method can predict long-term creep strain with sufficient accuracy. The difference between the predicted creep compliance values from those obtained experimentally was less than 5 percent.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.11a
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• pp.137-140
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• 2005

Exfoliated nanocomposites of polypropylene/layered silicate were prepared by a melt compounding process using maleic anhydride modified polypropylene (PP-g-MAH) and organoclay. It was found that polypropylene/layered silicate nanocomposites exhibited remarkable reinforcement compared with the pure polypropylene or conventional composite filled with agglomerated organoclay. The polypropylene /layered silicate nanocomposites showed stronger and earlier shear thinning behaviors and outstanding strain hardening behavior than pure polypropylene or other conventional composites in shear and uniaxial elongational flows, respectively. We simulated rheological modeling for the pure polymer matrix and polypropylene/layered silicate nanocomposite in shear and elongational flows using K-BKZ integral constitutive equation. The two types of K-BKZequations have been examined to describe experimental results of shear and uniaxial elongational viscosities of pure polypropylene and polypropylene/layered silicate nanocomposite.

• Proceedings of the Korean Society For Composite Materials Conference
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• 1999.11a
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• pp.234-238
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• 1999

This study suggests the design of the functionally gradient composite, [0/90/0/core]$_s$ cross-ply laminate, to prevent stress concentration induced from the difference of rigidity between the bone and the artificial hip joint and to reinforce the wear property of the surface and the expectation of their mechanical properties. First, the four-point bending test is done about wet bones and dry bones to know the mechanical properties of the cortical bones. In result, the wet bone shows the viscoelastic behavior and the dry bone shows the elastic behavior. Moreover, we expect the properties of the proposed gradient composites as a function of carbon fiber volume fraction in each layer to apply Halpin-Tsai equation, CLPT(classical laminate plate theory), and Bernoulli beam theory etc. and decide the thickness ratio of each lamina in order to match Young's modulus of the anisotropic cortical bone with the proposed gradient composites.