• 한국고분자학회:학술대회논문집
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• 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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• pp.323-323
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• 2006

Multi-vinyl monomer, which contains many vinyl groups in a molecule, was prepared by esterification of hydroxyl groups of poly(2-hydroxyethyl methacrylate) with methacryloyl chloride. Then, copper-mediated atom transfer radical polymerization was carried out as a template polymerization. The propagation of polymerization was investigated by kinetic analysis.

• 월간포장계
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• 통권94호
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• pp.127-133
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• 2001

• 월간산업보건
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• 통권101호
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• pp.50-51
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• 1996

• 한국섬유공학회:학술대회논문집
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• 한국섬유공학회 1990년도 제2차 학술발표초록집
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• pp.15-15
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• 1990

• 분석과학
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• 제28권1호
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• pp.8-16
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• 2015

We prepared a novel electrochemical gas sensor (EG sensor) based on interdigitated electrode (IDE) coated with vinyl ionic liquids (ILs) as electrolyte and Pt-Ru-Mo/MWNT electrocatalysts for occurring redox-active of CNCl gas. The vinyl ILs such as 1-butyl-3-(vinylbenzyl)imidazolium chloride, $[BVBI]^+Cl^-$, and 3-hexyl-1-vinylimidazolium bromide, $[HVI]^+Br^-$, were synthesized by $SN_2$ reaction in order to use electrolyte. The Pt-Ru-Mo/MWNT electrocatalysts were also prepared by one-step radiation-induced reduction of metal ions in the presence of MWNTs as supports. The fabricated EG sensor with vinyl ILs electrolyte was evaluated through optical microscopy (OM), scanning electron microscopy (SEM), and atomic force microscopy (AFM). The prepared EG sensor is clearly detected over 2.0 ppm CNCl gas and is exhibited a liner relationship between current and concentration over a region of 10-100 ppm.

• 폴리머
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• 제35권5호
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• pp.409-418
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• 2011

A novel silicone (Si) containing vinylic monomer, N-(3-(triethoxysilyl)propyl) methacrylamide (TESPMA), based on 3-aminopropyltriethoxysilane (APTES) and methacryloyl chloride (MCl) has been synthesized for formulation of waterborne polyurethane (WPU). Two types of vinyl group containing Si, methacryloxypropyltriethoxysilane (MPTES) and triethoxyvinylsilane (TEVS), have been used as coupling reagents for comparison of the effects of Si kinds with TESPMA on the WPU. A series of new siliconized WPU, vinyl acetate/vinyl ester of versatic acid (VAc-Veova), TESPMA, MPTES and TEVS hybrid latexes have been successfully prepared by emulsion polymerization in the presence of WPU dispersion.

• Bulletin of the Korean Chemical Society
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• 제8권4호
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• pp.246-250
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• 1987

The reaction of aryl iodides or bromides with olefins in the presence of 1 mol % of $PdCl_2(PPh_3)_2$ and 3 equiv. of $n-Bu_3N\; at\; 100^{\circ}C$ in carbon monoxide atmosphere gave the corresponding aryl vinyl ketones in good yields with small amount of vinylated 1-aryl olefins. But, when the reaction was proceeded under the 10 atm of carbon monoxide, aryl vinyl ${\alpha}$-diketones and aryl vinyl ketones were obtained in moderate to good yields. The reaction was tolerant of a wide variety of functional groups on either the aryl halides or olefin compounds. Reactivity of aryl halide decrease in the order; aryl iodide > aryl bromide ${\gg}$aryl chloride. In general, the reaction proceeded well and gave good yields of aryl vinyl ketones and aryl vinyl ${\alpha}$-diketones when reactants are substituted with electron withdrawing groups.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2001년도 춘계학술대회논문집D
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• pp.697-702
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• 2001

Numerical simulations of 1,2 dichloroethane(EDC) pyrolysis are conducted to understand the process on the production of the vinyl chloride monomer(VCM) and by-products. A chemical kinetic mechanism is developed, the adopted scheme involving 44 gas-phase species and 260 elementary forward and backward reactions. Detailed sensitivity analyses and the rates of production analysis are performed on each of the reactions and the various species, respectively. The concentrations of EDC, VCM, and HCI predicted by this mechanism are in good agreement with those deduced from experiments of commercial and laboratory scale. The mechanism is found to accurately predict the VCM yield and the production of by-products by varying the ranges of pyrolysis temperature, residence time, and pressure which impact on the pyrolysis of 1,2 dichloroethane. The influence of reactions related to H atom on the relative sensitivity of EDC becomes important as the residence time increases. The pyrolysis of EDC mainly occurs through $C_{2}H_{4}Cl_{2}+Cl=CH_{2}ClCHCl$.

• Journal of Mechanical Science and Technology
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• 제16권1호
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• pp.102-108
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• 2002

Numerical simulations of 1, 2 dichloroethane(EDC) pyrolyisis are conducted to understand the process in the production of the vinyl chloride monomer (VCM) and by-products. A chemical kinetic mechanism Is developed, with the adopted scheme involving 44 gas-phase species and 260 elementary forward and backward reactions. Detailed sensitivity analyses and the rates of production analysis are performed on each of the reactions and the various species, respectively. The concentrations of EDC, VCM, and HCI predicted by this mechanism are in good agreement with those deduced from experiments of commercial and laboratory scale. The mechanism is found to accurately predict the EDC yield an(1 the production of by-products by varying the ranges of pyrolysis temperature, residence time, and pressure which impact on the pyrolysis of 1, 2 dichloroethane. The influence of reactions related to H atom on the relative sensitivity of EDC becomes important as the residence time increases. The pyrolysis of EDC mainly occurs through C$_2$H$_4$Cl$_2$+Cl=CH$_2$CICHI+HCI.

• 보존과학연구
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• 통권14호
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• pp.35-44
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• 1993

The way of prevention for the continuous corrosion progress in iron antiquities after excavation and conservation treatment have been studied. The corrosion occuring have been found the oxidation of ferrous ions in the presence of chloride. The consideration to control the activity of chloride is important of controling relative humidity for the stable environment of the storage. One of the method that keeps archeological iron antiquities recommend the storage of special vinyl film(poly-vinyl alcohol film) with silica gel to control the relative humidity. Although this method is not permanent, it's very well efficiency of economy and convenience at present.