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Synthesis of Novel Silicone Containing Vinylic Monomer and Its Uses in the Waterborne Polyurethane-Veova/Vinyl Acetate Hybrid Emulsion Copolymers  

Naghash, Hamid Javaherian (Department of Chemistry, Islamic Azad University)
Naeni, Elham Kasaeian (Department of Chemistry, Islamic Azad University)
Publication Information
Polymer(Korea) / v.35, no.5, 2011 , pp. 409-418 More about this Journal
Abstract
A novel silicone (Si) containing vinylic monomer, N-(3-(triethoxysilyl)propyl) methacrylamide (TESPMA), based on 3-aminopropyltriethoxysilane (APTES) and methacryloyl chloride (MCl) has been synthesized for formulation of waterborne polyurethane (WPU). Two types of vinyl group containing Si, methacryloxypropyltriethoxysilane (MPTES) and triethoxyvinylsilane (TEVS), have been used as coupling reagents for comparison of the effects of Si kinds with TESPMA on the WPU. A series of new siliconized WPU, vinyl acetate/vinyl ester of versatic acid (VAc-Veova), TESPMA, MPTES and TEVS hybrid latexes have been successfully prepared by emulsion polymerization in the presence of WPU dispersion.
Keywords
N-(3-(triethoxysilyl)propyl) methacrylamide; silicones; polyurethanes; polymer synthesis and characterization; glass transition; coatings;
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