• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.3 no.1
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• pp.91-98
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• 1993

This study was carried out to investigate characteristic of vinyl chloride emissioned from poly vinyl chloride extrusion process and to evaluate the efficiency of local exhaust ventilation system. Before local ventilation facility was constructed in poly vinyl chloride extrusion process, the average worker exposure to vinyl chloride was 3.15 ppm, which exceeded Threshold Limit Value of American Conference of Gorvernmental Industrial Hygienists (ACGIH-TLV), 1 ppm. lt is possible that vinyl chloride residues in the poly vinyl chloride resin was released or degased due to extrusion heat. The larger the width of vinyl tube become, the higher worker exposure to vinyl chloride was. It is estimated that vinyl chloride from vinyl chloride resin increased as amount of poly vinyl chloride resin extruded in the extrusion process increased. Canopy hood was an appropriate type for poly vinyl chloride resin extrusion process. This local exhaust ventilation has fan static pressure of 7.65 inch wg($190mmH_2O$, total volumetric flowlate of 4,796 CFM ($135.8m^3$/min) and fan power requirement of 12 hp (8.952 Kw). After this local exhaust ventilation was constructed there, the average concentration of worker exposure to vinyl chloride was reduced to be 0.46 ppm, which was below the Threshold Limit Value, 1 ppm. Also, the removal efficiency rate of vinyl chloride attained by local exhaust ventilation was 85.3%. It was a statistically significant (p<0.01).

• Journal of the Korean Society of Safety
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• v.34 no.5
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• pp.72-77
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• 2019

Vinyl house consists of main rafter, lateral member, clamps and polyethylene film. Many vinyl houses are used to grow fruits, flowers and vegetables in the countryside. Due to climate change, vinyl houses are often destroyed by strong winds or typhoons in summer. Many farmers suffer great economic damage from the collapse of vinyl houses. So it is very important to build a safe vinyl house and find a method to withstand this heavy wind load. In this study, a structural analysis was performed on four types of vinyl houses(10-single-4, 10-single-6, 10-single-7, 10-single-10). In addition, axial force and flexural moment are obtained from the structural analysis of four types of vinyl house. For these four types of vinyl house, structural safety was reviewed by obtaining the combined stress ratio by the strength design method. This structural review showed that the specifications for the vinyl house proposed in the design are not safe. Especially, the result of structural analysis for four types of vinyl house showed that the vinyl house structure constructed as a standard was a very dangerous structure. Therefore, it is necessary to devise diverse methods in order to make vinyl houses structurally safe for heavy wind load in the future. Also a variety of manual development is needed to prevent the collapse of vinyl houses at heavy wind load.

• Journal of the Korean Society of Safety
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• v.34 no.2
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• pp.34-39
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• 2019

Vinyl house consists of main rafter, lateral member, clamps and polyethylene film. Many vinyl houses are used in the countryside to grow vegetables. These vinyl houses have occasionally been collapsed due to heavy snowfall in winter. Many farmers get a lot of economical damages, if vinyl houses are collapsed. So it is most important to built a safe vinyl house that can withstand heavy snowfall. In this study, a structural analysis was performed on three types of vinyl houses(07-single-01, 10-single-04, 12-single-01). In addition, the structural analysis of the three types of vinyl houses provided axial forces, flexural moment, and combined stress. For these three types of vinyl houses, structural safety was reviewed by obtaining the combined stress ratio by the strength design method. This structural review showed that the specifications for the vinyl house proposed in the design are not safe. Especially, the result of increasing the design snow load by 15 percent and 30 percent showed that the vinyl house structure constructed as a standard for vinyl house was a more dangerous structure. Therefore, it is necessary to revise regulations such as increasing the thickness of rafters or widening the gap in order to make vinyl houses structurally safe for heavy snowfall in the future, and to devise diverse methods to make vinyl houses that are structurally safe.

• Macromolecular Research
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• v.11 no.3
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• pp.202-205
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• 2003

The reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.

• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.85-92
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• 1999

The complete catalytic oxidation of vinyl chloride was investigated over chromium oxide supported ${\gamma}$-alumina using a fixed bed micro-reactor at temperature between 240 and $300^{\circ}C$ and concentration between 600 and 3500 ppm. The oxidation of vinyl chloride was nonlinear in the concentration of vinyl chloride and zeroth order in the concentration of oxygen. The addition of HCl and $H_2O$ as products to the feed stream didn't influence the conversion of vinyl chloride. Several kinetic rate model were tested to describe the data over the range of condition investigated, and developed a model which provide the best correlation of experimental data. The resulting model of kinetic rate was derived by assuming that the reacting occurred via adsorption and subsequent decomposition of the vinyl chloride onto the oxygen covered chromium oxide surface, with the reaction being inhibited by the adsorption of vinyl chloride. The percent standard deviation between the predicted and experimental was about 5.2%, and the activation energy was 18.9 kcal/mol.

• Journal of the Korean Applied Science and Technology
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• v.13 no.2
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• pp.77-84
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• 1996

Poly(vinyl acetate)와 poly(vinyl acetate-co-2-ethylhexyl acrylate)를 여러 조건에서 semicontinuous emulsion 중합으로 합성하였다. Overall conversion, emulsion 입자크기, pH, 점도 등을 합성한 두 emulsion polymer에 대해 측정하였다. Vinyl acetate monomer에 2-ethylhexyl acrylate를 도입함으로서 emulsion 입도, 점도, 중합 속도, 유리 전이 속도가 감소함을 확인하였다.

• Proceedings of the Korean Fiber Society Conference
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• 1998.04a
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• pp.130-134
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• 1998

The physical properties of poly(vinyl alcohol) (PVA) are highly dependent on the degree of syndiotacticity, which is determined primarily by the choice of the vinyl ester monomer precursor. Efforts to produce more syndiotactic PVAs, as well to increase the molecular weight, have centered on the polymerization of vinyl trifluoroacetate,$^1$ vinyl trichloroacetate,$^2$ and vinyl pivalate (VPi).(omitted)

• Korean Chemical Engineering Research
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• v.49 no.1
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• pp.56-61
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• 2011

Alkyl vinyl ethers such as methyl vinyl ether, propyl vinyl ether, isopropyl vinyl ether, butyl vinyl ether and isobutyl vinyl ether are usually used as industrial solvents and chemical intermediates in the chemical or pharmaceutical industry. Recently, they are popularly used as raw materials for polymer electrolyte membrane fuel cells and as cellulose dyeing assistants. However, very few investigations about process design and operation data were reported for alkyl vinyl ether compounds and there are no data for propyl vinyl ether(PVE) systems as far as we know. In this work, the isothermal VLE data are reported at 333.15 K for the ternary systems of {PVE + ethanol + benzene} by using headspace gas chromatography(HSGC) and these VLE data were correlated using Wilson, NRTL and UNIQUAC equations. The excess volumes($V^E$) and deviations in molar refractivity(${\Delta}R$) data are also reported for the sub binary systems {PVE + ethanol}, {ethanol + benzene} and {PVE + benzene} at 303.15 K. These data were correlated with Redlich-Kister equation. In addition, isoclines of $V^E$ and DR for ternary system {PVE + ethanol + benzene} were also calculated from Radojkovi equation.

• Macromolecular Research
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• v.10 no.6
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• pp.339-344
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• 2002

Poly(vinyl alcohol-b-styrene) (poly(VA-b-St)) diblock copolymer containing high syndiotactic poly (vinyl alcohol) (PVA) was synthesized by the saponification of poly(vinyl pivalate-b-styrene) (poly(VPi-b-St)). For the block copolymer, poly(vinyl pivalate) (PVPi) with trichloromethyl end group was obtained via telomerization of vinyl pivalate with carbon tetrachloride as a telogen and 2,2-azobisisobutyronitrile (AIBN) as an initiator. Then resulting poly(vinyl pivalate) with trichloromethyl end group was used as an effient macroinitiator for the synthesis of poly(VPi-b-St) using atom transfer radical polymerization (ATRP) in the presence of CuCl/2,2'-bipyridine at 130 $^{\circ}C$. The poly(vinyl pivalate) macroinitiator, poly(VPi-b-St), poly(VA-b-St) were characterized by GPC, FT-IR and $^1$H-NMR. And the analysis showed that integrity of the block copolymer was maintained during saponification reaction.

• Journal of Sericultural and Entomological Science
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• v.16 no.2
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• pp.141-146
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• 1974

This study was carried out to observe the possibility of special rearing of young silkworm for a simple cooperative rearing in the indoor vinyl house. The results of this study are as follows. 1. Temperature and humidity were regulated reasonably in the indoor vinyl house in comparison with general rearing and covered rearing with damp-proof and all workings in it were more convenient. 2. Duration of silkworm life was same in the covered rearing with damp-proof and indoor vinyl house, but general rearing was longer spring rearing silkworm period, 5 hours and autumn young silkworm period. 6 hours than indoor vinyl house. 3. In the mortality ratio, missing larvae of general rearing was more than any other treatments in spring and autumn. There was no difference between covered rearing with damp-proof and indoor vinyl house rearing, but missing larvae seemed to be a little indoor vinyl house. 4. In the individual cocoon ratio there was no significance in spring and autumn, but best cocoon ratio was high in the special rearing and good and low cocoon ratio was high in the general rearing. 5. In the cocoon weight of 10,000 3rd moulted silkworm. cocoon weight of general rearing was less than any other treatments in spring rearing season, and that of covered rearing with damp-proof and indoor vinyl house rearing It was same result. 6. There was no significance in the cocoon layer ratio in spring and autumn, but that of covered rearing with damp-proof and indoor vinyl house was high in comparison with general rearing. 7. As showed above, it is considered that the rearing of indoor vinyl house is worth as special rearing of young silkworm for simple cooperative rearing because it showed good records with three times feedings a day in comparison with general rearing and covered rearing with damp-proof.