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Synthesis and Photopolymerization of Vinyl Ether and Epoxy-Functionalized Silicones  

Pyun, Sang-Yong (Department of Chemistry, Pukyung National University)
Kim, Whan-Gi (Department of Applied Chemistry, Konkuk University)
Publication Information
Macromolecular Research / v.11, no.3, 2003 , pp. 202-205 More about this Journal
Abstract
The reactive precursors, vinyl ethers, and epoxy-silicones, were synthesized. The vinyl ether monomers were prepared from primary alcohol and ethyl vinyl ether with mercury (II) acetate. The epoxy-functionalized silicones have been achieved by the controlled, rhodium-catalyzed, chemoselective hydrosilation of vinyl ether with siloxanes or silane. It was shown that the hydrosilation proceeds exclusively at the vinyl ether group of alkenyl vinyl ether without participation at the alkenyl group. The photoinduced cationic polymerization of these monomers was studied and found to be all highly reactive.
Keywords
cationic polymerization; siloxane; silicone; uv-curing; vinyl ether; epoxy; hydrosilation.;
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Times Cited By Web Of Science : 6  (Related Records In Web of Science)
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1 /
[ R. Malik;J. V. Crivello ] / J. Macromol. Sci.-Pure and Applied Chem.
2 /
[ J. P. Fouassier;J. F. Rabek ] / Radiation Curing in Polymer Scince and Technology
3 /
[ J. V. Crivello;B. Yang;W. G. Kim ] / J. Macromol. Sci. Pure and Applied Chem.
4 /
[ J. C. Crivello;B. Yang;W. G. Kim ] / J. Polym. Sci. Part A: Polym. Chem.   ScienceOn
5 /
[ J. V. Crivello ] / J. Polym. Sci. Part A: Polym. Chem.   ScienceOn
6 /
[ R. P. Eckberg;R. W. LaRochelle ] / US Pat. 4279717(Chem Abstr 94:158502)
7 /
[ J. L. Dektar;N. P. Hacker ] / J. Org. Chem.
8 /
[ S. K. Rajaraman;W. A. Mowers;J. V. Crivello ] / J. Polym. Sci. Part A: Polym. Chem.   ScienceOn
9 /
[ M. L. Brook ] / Silicon in Organic, Organometallic, and Polymer Chemistry
10 /
[ J. Park ] / Korea Polym. J.
11 /
[ J. V. Crivello;D. Bi ] / J. Polym. Sci. Part A: Polym. Chem.   ScienceOn
12 /
[ T. Furzono;K. Seki;A. Kishida;T. Ohshige;K. Waki;I. Maruyama;M. Akashi ] / J. Appl. Polym. Sci.
13 /
[ H. R. Kricheldorf ] / Silicon in Polymer Synthesis
14 /
[ J. K. Lee;Y. Choi;J.-R. Lee;J. Park ] / Macromol. Res.   ScienceOn
15 /
[ F. Loshe;H. Zweifel ] / Adv. Polym. Sci.
16 /
[ N. Yasuda;S. Yamamoto;Y. Wada;S. Yanagida ] / J. Polym. Sci. Part A: Polym. Chem.   ScienceOn
17 /
[ T.Okuyama;T. Fueno;J. Furukawa ] / J. Polym. Sci., Polym. Chem. Ed.
18 /
[ S. P. Pappas ] / Radiation Curing in Scince and Technology
19 /
[ R. K. Guy;R. A. Dipietro ] / Synthetic Communication
20 /
[ J. V. Crivello;J. L. Lee ] / J. Polym. Sci. Part A: Polym. Chem.