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Highly Stable Photoluminescent and Magnetic Multilayers Using Nucleophilic Substitution Reaction in Organic Media

  • 조진한
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2010년도 제39회 하계학술대회 초록집
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    • pp.262-262
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    • 2010
  • We introduce a novel and efficient strategy for producing free-standing functional films via photo-crosslinking and electrostatic layer-by-layer (LbL) assembly, which can allow the buildup of hydrophilic multilayers onto hydrophobic surfaces. Hydrophobic multilayers were deposited on ionic substrates by a photo-crosslinking LbL process using photo-crosslinkable polymers. The photo-crosslinked surface was converted to an anionic surface by excess UV light irradiation. This treatment allowed also the stable adhesion between metal electrode or cationic polyelectrolyte and hydrophobic multilayers. After dissolving the ionic substrates in water, the formed free-standing films exhibited unique functionalities of inserted components within hydrophobic and/or hydrophilic multilayers.

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New Radical Allylation Reactions Using 2-Bromo-3-(phenylthio)propene and Their Application to the Synthesis of Carbocyclic Compounds

  • 유병우;Dennis P. Curran
    • Bulletin of the Korean Chemical Society
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    • 제17권11호
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    • pp.1009-1018
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    • 1996
  • A study on the application of vinyl radical cyclization via free radical allylation reaction in the synthesis of various carbocyclic compounds is described. In connection with this study, a new allyl transfer reagent, 2-bromo-3-(phenylthio)propene 1 is developed and it was shown that vinyl radical cyclization through free radical allylation reaction using reagent 1 provides a valuable approach to carbocyclic systems with a reactive exo-alkylidene moiety, which is advantageous for further transformations.

자유경계를 갖는 비등방성 판의 유한차분 안정성 해석 (Finite Difference Stability Analysis of Anisotropic Plates with Free Edge)

  • 유용민;이상열;장석윤
    • 한국강구조학회 논문집
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    • 제12권2호통권45호
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    • pp.221-230
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    • 2000
  • 자유단이 있는 비등방성 판의 안정성을 검토할 때, 기존의 해석적인 방법으로는 다양한 하중 조건 및 경계조건에 대해 좌굴하중 및 좌굴모드를 구할 수 없다. 이러한 단점을 해결하기 위해 수치해석 기법인 유한차분법을 사용하였다. 유한차분법을 적용할 때, 자유경계의 가상점 처리가 가장 난해하게 되므로 1변이 자유이고 3변이 고정인 경우와 마주보는 2변이 자유이고 다른 2변이 고정인 경우를 해석 모델로 삼아 좌굴해석을 수행하였다. 본 논문에서는 자유경계를 갖는 비등방성 판의 해석 기법으로 유한차분법을 제시하였으며, 다양한 수치해석을 통하여 자유경계의 좌굴하중 및 모드 특성을 규명하였다.

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Buckling and free vibration analyses of nanobeams with surface effects via various higher-order shear deformation theories

  • Rahmani, Omid;Asemani, S. Samane
    • Structural Engineering and Mechanics
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    • 제74권2호
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    • pp.175-187
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    • 2020
  • The theories having been developed thus far account for higher-order variation of transverse shear strain through the depth of the beam and satisfy the stress-free boundary conditions on the top and bottom surfaces of the beam. A shear correction factor, therefore, is not required. In this paper, the effect of surface on the axial buckling and free vibration of nanobeams is studied using various refined higher-order shear deformation beam theories. Furthermore, these theories have strong similarities with Euler-Bernoulli beam theory in aspects such as equations of motion, boundary conditions, and expressions of the resultant stress. The equations of motion and boundary conditions were derived from Hamilton's principle. The resultant system of ordinary differential equations was solved analytically. The effects of the nanobeam length-to-thickness ratio, thickness, and modes on the buckling and free vibration of the nanobeams were also investigated. Finally, it was found that the buckling and free vibration behavior of a nanobeam is size-dependent and that surface effects and surface energy produce significant effects by increasing the ratio of surface area to bulk at nano-scale. The results indicated that surface effects influence the buckling and free vibration performance of nanobeams and that increasing the length-to-thickness increases the buckling and free vibration in various higher-order shear deformation beam theories. This study can assist in measuring the mechanical properties of nanobeams accurately and designing nanobeam-based devices and systems.

ℂ-VALUED FREE PROBABILITY ON A GRAPH VON NEUMANN ALGEBRA

  • Cho, Il-Woo
    • 대한수학회지
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    • 제47권3호
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    • pp.601-631
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    • 2010
  • In [6] and [7], we introduced graph von Neumann algebras which are the (groupoid) crossed product algebras of von Neumann algebras and graph groupoids via groupoid actions. We showed that such crossed product algebras have the graph-depending amalgamated reduced free probabilistic properties. In this paper, we will consider a scalar-valued $W^*$-probability on a given graph von Neumann algebra. We show that a diagonal graph $W^*$-probability space (as a scalar-valued $W^*$-probability space) and a graph W¤-probability space (as an amalgamated $W^*$-probability space) are compatible. By this compatibility, we can find the relation between amalgamated free distributions and scalar-valued free distributions on a graph von Neumann algebra. Under this compatibility, we observe the scalar-valued freeness on a graph von Neumann algebra.

Improvements of the luminous efficiency of mercury-free fluorescent lamps via structural and complex gas mixture changes

  • Oh, Byung-Joo;Jung, Jae-Chul;Seo, In-Woo;Kim, Hyuk;Whang, Ki-Woong
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.809-812
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    • 2008
  • Structural parameter variation effects (changing the coplanar gap under different discharge dimensions) and use of complex gas mixtures (He, Ne, Ar and Xe) in mercury-free fluorescent lamps are studied in this paper. Pure Neon gas is the best buffer gas for obtaining high luminous efficiency in mercury-free fluorescent lamps. It is shown that with a shorter coplanar gap (30mm), a high luminous efficiency can be obtained at low operating voltage, as well as high luminance uniformity and stable discharge with a Ne-Xe 20% gas mixture.

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PEDOT Polymer Film Based Counter Electrodes for Pt-free Dye-Sensitized Solar Cells

  • Kwon, Jeong;Park, Jong Hyeok
    • Journal of Electrochemical Science and Technology
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    • 제4권3호
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    • pp.89-92
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    • 2013
  • Poly (3,4-ethylenedioxythiophene) (PEDOT) polymers with different electric conductivities were synthesized directly on a FTO substrate via a chemical polymerization method and applied as a platinum (Pt)-free counter electrode for dye-sensitized solar cells (DSSCs). The catalytic properties of the PEDOT as a function of electrical conductivity were studied using cyclic voltammograms, J-V measurements and impedance spectroscopy. The PEDOT counter electrode with around 340 S/cm conductivity exhibited the best performance as a counter electrode for tri-iodide reduction. The ability to modulate catalytic activity of PEDOT with changes in conductivity shows one of promising routes for developing new counter electrode of Pt-free DSSCs.

3 축 CNC 를 이용한 5 축 자유곡면 가공 (Five-Axis Machining with Three-Axis CNC Machine)

  • 이정재;서석환
    • 대한산업공학회지
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    • 제21권2호
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    • pp.217-237
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    • 1995
  • One of the most distinguished advantages of five-axis machining is that complex free surfaces(such as impeller) can be machined by one setup. Five-axis CNC machine, however, is very expensive so that its usage is restricted to a few large companies. As an economical approach to five-axis machining, this paper presents a method for machining the five-axis free surfaces(using ball-end mill) on a three-axis CNC machine with an index table. The method developed consists of: a) determining the minimum number of part setups and their interference-free and collision-free potential machining area, b) calculating actual machining area for each setup, and c) generating 3-axis cutter path for each part setup. The method has been successfully tested via computer simulations for several complex surfaces including impeller.

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휴대폰 통화기록 기반의 소셜 컨택 네트워크 구성 및 Scale-free 특성에 관한 분석 (Constructing a Social Contact Network based on Cellphone Call Records and Analysis of its Scale-free Property)

  • 이진호
    • 대한산업공학회지
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    • 제40권1호
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    • pp.1-7
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    • 2014
  • We consider a human contact social network that has connections through cellphone addresses. To construct such a social network, we use real call records provided by a large carrier, and connect to each other if there exists a call record between any two cellphone users. Due to its huge amount of data, we down-sample it in a way that the smallest-degree nodes are removed, in turn, from the network. For a moderate size of the networks we show that the degree distribution of the network follows a power-law distribution via linear regression analysis, implying the so-called scale-free property. We finally suggest some alternative measures to analyze a social network.