• 통합자연과학논문집
• /
• 제5권4호
• /
• pp.237-240
• /
• 2012

In this study, PEDOT thin films polymerized with Iron(III)tosylate ($Fe(PTS)_3$) and grown on atomically smooth and highly dense 3-aminopropyltriethoxysilane self-assembled monolayer (APS-SAM) surfaces by VPP method have been investigated. PEDOT thin films were synthesized on APS self-assembled $SiO_2$ wafer surface at two different concentrations (20 wt% and 40 wt%) and growth time (3 and 30 minutes), and then their sheet resistance were measured and compared. PEDOT thin films grown with 20 wt% $Fe(PTS)_3$ oxidant are highly conductive when compared with the film grown with 40 wt% $Fe(PTS)_3$, as ascertained by the measured sheet resistance values down to 0.06 ${\Omega}/cm$. It clearly suggests that 20 wt% is more effective oxidant concentration for VPP than 40 wt% even though the film grown with 40 wt% oxidant has better quality than the film with 20 wt% $Fe(PTS)_3$ does.

• 한국전산유체공학회지
• /
• 제15권3호
• /
• pp.24-31
• /
• 2010

boiling flow in vertical tube. The multiphase flow model used in this CFD analysis is the two-fluid model in which liquid(water) and gas(vapour) are considered as continuous and dispersed fluids, respectively. A wall boiling model is also used to simulate the subcooled boiling heat transfer at the heated wall boundary. The diameter and heated length of tube are 0.0154 m and 2 m, respectively. The system pressure in tube is 4.5 MPa and the inlet subcooling is 60 K. The near-wall grid size in the non-dimensional wall unit for lqiuid phase ($y^+_{w,l}$) was examined from 101 to 313 at the outlet boundary. The CFD calculations predicted the void distributions as well as the liquid and wall temperatures in tube. The predicted axial variations of the void fraction and the wall temperature are compared with the measured ones. The CFD prediction of the wall temperature is shown to slightly depend on the near-wall grid size but the axial void prediction has somewhat large dependency. The CFD prediction was found to show a better agreement with the measured one for the large near-wall grid, e.g., $y^+_{w,l}$ > 300 at the tube exit.

• 한국분말재료학회지
• /
• 제14권2호
• /
• pp.108-115
• /
• 2007

Cu-Ni-P alloy nano powders were fabricated by the electrical explosion of electroless Ni plated Cu wires. The effect of applied voltage on the explosion was examined by applying pulse voltage of 6 and 28 kV, The estimated overheating factor, K, were 1.3 for 6 kV and 2.2 for 28 kV. The powders produced with pulse voltage of 6 kV were composed of Cu-rich solid solution, Ni-rich solid solution, and $Ni_3P$ phase. While, those produced with 28 kV were complete Cu-Ni-P solid solution and small amount of $Ni_3P$ phase. The initial P content of 6.5 at.% was reduced to 2-3 at.% during explosion due to its high vapour pressure.

• 통합자연과학논문집
• /
• 제4권4호
• /
• pp.311-314
• /
• 2011

Application of self-assembled monolayers (SAMs) to the fabrication of organic thin film transistor has been recently reported very often since it can help to provide ohmic contact between films as well as to form simple and effective electrode pattern. Accordingly, quality of these ultra-thin films is becoming more imperative. In this study, in order to manufacture a high quality SAM pattern, a hydrophobic alkylsilane monolayer and a hydrophilic aminosilane monolayer were selectively coated on $SiO_2$ surface through the consecutive procedures of a micro-contact printing (${\mu}CP$) and dip-coating methods under extremely dry condition. On a SAM pattern cleaned with SC1 solution immediately after ${\mu}CP$, poly(3,4-ethylenedioxythiophene) (PEDOT) source and drain electrode array were very selectively and nicely vapour phase polymerized. On the other side, on a SC1-untreated SAM pattern, PEDOT array was very poorly polymerized. It strongly suggests that the SC1 cleaning process effectively removes unwanted contaminants on SAM pattern, thereby resulting in very selective growth of PEDOT electrode pattern.

• Nuclear Engineering and Technology
• /
• 제52권1호
• /
• pp.27-36
• /
• 2020

Natural convection and thermal stratification phenomena are found in large water pools that are being used as heat sinks for decay heat removal from the reactor core using passive heat removal systems. In this study, the two-phase (water and air) natural convection and thermal stratification phenomena with conjugate heat transfer in the rectangular enclosure were investigated numerically using ANSYS Fluent 17.2 code. The transient numerical simulations of these phenomena in the full-scale computational domain of the experimental facility were performed. Generation of water vapour bubbles around the heater rod and evaporation phenomena were included in this numerical investigation. The results of numerical simulations are in good agreement with experimental measurements. This shows that the natural convection is formed in region above the heater rod and the water is thermally stratified in the region below the heater rod. The heat from higher region and from the heater rod is transferred to the lower region via conduction. The thermal stratification disappears and the water becomes well mixed, only after the water temperature reaches the saturation temperature and boiling starts. The developed modelling approach and obtained results provide guidelines for numerical investigations of thermal-hydraulic processes in the water pools for passive residual heat removal systems or spent nuclear fuel pools considering the concreate walls of the pool and main room above the pool.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1992년도 하계학술대회 논문집 B
• /
• pp.699-702
• /
• 1992

A miniature size electrostatic induction motor have been constructed and studied by applying a three phase ac power source with a maximum voltage of 5 KV and a variable frequency ranged 0.0 - 150 Hz. A maximum no load speed of the motor tested was about 7600 RPM at the applied voltage of 4330 volt and the frequency of 130 Hz for the case of the rotor surface material of polyprophylene sheet screen-printed $TiO_2$ powder on it. It is found that there are 3 different regions of the motor operation, a rotor stop region, a stable operation region and a high speed abnormal region. And it is also found that the motor speed is influenced greatly by the charge relaxation time constant of the rotor surface materials, which however was changed by the means of vapour-deposited Ti or Ni and screen-printed $TiO_2$ powder on the surface of the rotor material, polyprophylene.

• International Journal of Safety
• /
• 제3권1호
• /
• pp.20-26
• /
• 2004

The system considered in this model consists of a single, semi- transparent, diesel fuel droplet, which is immobile in the heating area and surrounded by a quiescent air. A uniform external radiation field surrounds the droplet. Results from mathematical simulation suggest that because of the higher surface temperature, the external radiative heating of the droplet can promote an earlier ignition of the fuel vapour/air mixture. The radiative heating of the droplet increases the mass transfer from the droplet to the surrounding gas-phase, thus, decreasing the heterogeneity of the fuel droplet/air system.

• Carbon letters
• /
• 제1권3_4호
• /
• pp.143-147
• /
• 2001

Under the irradiation of radiofrequency wave, the dipole materials vibrate as microwave phase changes. This causes friction between adjacent molecules and enables an unique characteristics of interior heating of the materials. Using this principle, when harmful material pass through anthracite- bed which play a role as a absorber of radiofrequency wave, the material can be easily decomposed by the microwave energy. To remove benzene vapour and other solvents in the process of industry, we examined decomposition of benzene in this manner. It was found that benzene was decomposed to the methane, ethane, propane and butane, etc. during passing through the carbon-bed under the microwave impingement and distribution of methane in the products reached about 85 vol.%. The decomposition rate of benzene was high within 5 minutes from start of reaction. For a lower concentration of benzene gas, general cases in the field of industry, almost complete decomposition of benzene is believed possible and this method is surely expected to be useful for the prevention of air pollution and improvement of ambient condition.

• 한국염색가공학회지
• /
• 제10권2호
• /
• pp.8-17
• /
• 1998

In this study we have examined electroless chemical plating on the plasma grafted poly [ethylene terephathalate］(PET) fabric in order to improve the interfacial adhesion between metal and fiber. The vapour phase of acrylic acid introduced on the PET surface and the graft polymerization was carried out by using cold plasma, resulting in the grafting yield of 0.8-1.3 wt％. The carboxyl group of the plasma grafted was identified by FT-IR-ATR spectra. The Interfacial adhesion was related to the carboxyl group. After electroless chemical plating of nickel, it showed that the more the carboxyl, the better the interfacial adhesion. Comparing to the untreated, the plasma grafted fabric showed fairly good interfacial adhesion(5B grade, ASTM D3359) . The shielding effect of electromagnetic wave showed 95dB. The shielding effect depends on the fabric structure, the surface structure, and the cross sectional shape of fibers. The dense fabric structure, the etched surface like a microcrater, and the trigonal cross sectional shape were prefered.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 1999년도 제17회 학술발표회 논문개요집
• /
• pp.121-121
• /
• 1999

Gallium nitride (GaN) semiconductor is intensively under investigation for commercialization of short wavelength light emitting devices and laser diodes. One of serious obstacles to overcome is to reduce the defect density in GaN film grown by various techniques such as MOCVD, HVPE, etc. Many research groups including SAIT are trying to improve the defect density to 106-107/cm2 from the level of 108-1010/cm2. We have investigated epitaxial growth behaviour of GaN thin and thick films under hidride vapour phase epitaxy (HVPE) condition. In this report, we present the microstructural and crystallographical characteristics of the GaN films grown on sapphire (0001) substrate which were studied by both conventional and high-resolution transmission electron microscopy (TEM). Also we present some microscopic analysis results obtained from GaN films grown by ELO(dpitzsial lateral overgrowth)-HVPE and from GaN quantum well structures grown by MOCVD. Another serious problem in growing GaN thick film by HVPE is internal micro-cracks. We also comment the origin of the micro-crack.