• 제목/요약/키워드: value gap

검색결과 1,039건 처리시간 0.029초

NTC 서미스터로 응용을 위한 Ni-Mn-Co 산화물의 미세구조와 전기적 특성 (The Microstructural and Electrical Properties of Ni-Mn-Co Oxide for the Application of NTC Thermistors)

  • 김경민;이성갑;권민수;김영곤
    • 한국전기전자재료학회논문지
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    • 제30권6호
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    • pp.361-365
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    • 2017
  • In this paper, we investigated the effect of Co content on the microstructural and electrical properties of $Ni_{0.79}Mn_{2.21-x}Co_xO_4$ (x=0 to 0.25) specimens. Solid-state reaction was used to prepare the bulk specimens. XRD (X-ray diffraction) patterns showed that all compositions had a cubic spinel phase. As a result of the microstructural properties, FE-SEM(field-emission scanning electron microscopy) analysis showed a dense structure, and the mean grain size increased from $5.24{\mu}m$ to $7.33{\mu}m$ with an increase of Co content from x=0 to 0.25. All specimens exhibited the typical NTC thermistor characteristics as the electrical resistance exponentially decreased with increasing temperature. The resistivity and the B-value of $Ni_{0.79}Mn_{1.96}Co_{0.25}O_4$ were $2959{\Omega}{\cdot}cm$ and 3719, respectively.

Photoactivities of Nanostructured α-Fe2O3 Anodes Prepared by Pulsed Electrodeposition

  • Lee, Mi Gyoung;Jang, Ho Won
    • 한국세라믹학회지
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    • 제53권4호
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    • pp.400-405
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    • 2016
  • Ferric oxide (${\alpha}-Fe_2O_3$, hematite) is an n-type semiconductor; due to its narrow band gap ($E_g=2.1eV$), it is a highly attractive and desirable material for use in solar hydrogenation by water oxidation. However, the actual conversion efficiency achieved with $Fe_2O_3$ is considerably lower than the theoretical values because the considerably short diffusion length (2-4 nm) of holes in $Fe_2O_3$ induces excessive charge recombination and low absorption. This is a significant hurdle that must be overcome in order to obtain high solar-to-hydrogen conversion efficiency. In consideration of this, it is thought that elemental doping, which may make it possible to enhance the charge transfer at the interface, will have a marked effect in terms of improving the photoactivities of ${\alpha}-Fe_2O_3$ photoanodes. Herein, we report on the synthesis by pulsed electrodeposition of ${\alpha}-Fe_2O_3$-based anodes; we also report on the resulting photoelectrochemical (PEC) properties. We attempted Ti-doping to enhance the PEC properties of ${\alpha}-Fe_2O_3$ anodes. It is revealed that the photocurrent density of a bare ${\alpha}-Fe_2O_3$ anode can be dramatically changed by controlling the condition of the electrodeposition and the concentration of $TiCl_3$. Under optimum conditions, a modified ${\alpha}-Fe_2O_3$ anode exhibits a maximum photocurrent density of $0.4mA/cm^2$ at 1.23 V vs. reversible hydrogen electrode (RHE) under 1.5 G simulated sunlight illumination; this photocurrent density value is about 3 times greater than that of unmodified ${\alpha}-Fe_2O_3$ anodes.

요양병원 근무 한의사의 지위와 역할에 관한 연구 (A Study on the Position and Role of Korean Medicine Doctors Working at Long-Term Care Hospitals)

  • 강태리;이상룡
    • 대한예방한의학회지
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    • 제19권3호
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    • pp.77-90
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    • 2015
  • Objective : The purpose of this study is to discuss the role and ways to improve the position and rights of Korean Medicine Doctors (KMDs) working at long-term care hospitals (LTCHs) through survey analysis. Method : (1) The legal and institutional position of KMDs is studied using current law and related papers. (2) The online survey was conducted through KMD community websites, targeted at KMDs working at LTCHs. Results : (1) Whereas there is perceived added benefit for the eight specializations for a specialist of Western medicine at LTCHs, in the case of a specialist of Korean Medicine, their value is not institutionally recognized at all. (2) A Western inpatient's medical fee is more than a Korean inpatient's medical fee, and the individual fee for the same medical treatment is also higher in Western hospitalization. So, Korean medical hospitalization actually cannot be made. Because of that, Korean Medicine Doctors find it difficult to be primary care physicians. (3) Musculoskeletal diseases and the aftereffects of cerebrovascular diseases were the most common chief complaints addressed in Korean medical consultations. Conclusion : This study shows that KMDs working at LTCHs have suffered many kinds of inequality. That is because of the limited medical scope of the current medical system and real constraints from the gap in Korean-Western medical fees by the National Health Insurance Corporation. Therefore, it is necessary to eliminate these variations along with revising the statute with continuous research.

카오스, 프랙탈의 창조적 속성과 환경디자인에의 적용가능성에 관한 연구 (A Study on the Anterior Creative Attributes of Chaos and Fratals and Their Applicability to Environmental Design)

  • 김주미
    • 디자인학연구
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    • 제13권
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    • pp.235-255
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    • 1996
  • 어느 시대나 사회의 세계관이란, 우주의 질서와 원리를 표명하는 당대의 시대 정신응ㄹ 그대로 반영하는 것이라 생각한다. 또한 디자이너의 가치관은 디자인 행위 및 그 결과로 함축되어 나타난다. 최근 디자인 학 연구에 있어 종래의 환원 적, 유클리트 적 디자인의 한계를 인식하고 그에 대응하는 새로운 사고와 방법을 모색하고 있으며, 새로운 패러다임을 지향해야 함이 강조되고 있다. 이러한 시점에서 본 연구는 새로운 과학 이론으로서의 카오스, 프랙탈 이론을 연구를 위한 준거의 틀로 삼고 있다. 연구결과 창조적 디자이너의 사고와 환경디자인 과정은 혼돈 속에 내재된 질서와 많은 개연성 중에서 가능성을 선택하는 일련의 혼돈 스런 개방시스템으로 설명되었다. 또한 과학, 예술의 상보적 관계 속에서 프랙탈 기하학은 자연인식과 디자인 사고에 새로운 개념과 언어를 제공하고 있으며, 환경디자인 방법에 무한한 조형적 가능성을 제시하고 있음을 확인할 수 있었다. 결국 본 연구는 변화된 세계관과 패러다임을 지향하는 사고방식을 강조하였으며, 환경디자인에 있어 창조적 폭을 넓히는 데 기여하고자 하였다.

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GaAs MMIC상에서 주기적으로 천공된 홀을 가지는 접지 금속막 구조를 이용한 전송선로 특성연구 및 코프레너 선로를 이용한 온칩 초소형 임피던스 변환기에의 응용 (A Study on Characteristics of the Transmission Line Employing Periodically Perforated Ground Metal on GaAs MMIC and Its Application to Highly Miniaturized On-chip Impedance Transformer Employing Coplanar Waveguide)

  • 윤영
    • Journal of Advanced Marine Engineering and Technology
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    • 제32권8호
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    • pp.1248-1256
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    • 2008
  • In this paper, basic characteristics of transmission line employing PPGM (periodically perforated ground metal) were investigated using theoretical and experimental analysis.According to the results, unlike the conventional PBG (photonic band gap) structures, the characteristic impedance of the transmission line employing PPGM structure showed a real value, which exhibited a very small dependency on frequency. The transmission line employing PPGM structure showed a loss (per quarter wave length) higher by $0.1{\sim}0.2\;dB$ than the conventional microstrip line. According to the investigation of the dependency of RF characteristic on ground condition, the RF characteristic of the transmission line employing PPGM structure was hardly affected by the ground condition in the frequency lower than Ku band, but fairly affected in the frequency higher than Ku band, which indicated that coplanar waveguide employing PPGM structure was optimal for RF characteristic and reduction of size. Considering above results, impedance transformer was developed using coplanar waveguide with PPGM structure for the first time, and good RF characteristics were observed from the impedance transformer. In case that {\lambda}/4$ impedance transformer with a center frequency of 9 GHz was fabricated for a impedance transformation from 20 to10 {\Omega}$, the line width and length were 20 and $500\;{\mu}m$, respectively, and its size was only 0.64 % of the impedance transformer fabricated with conventional microstrip lines. Above results indicate that the transmission line employing PPGM is a promising candidate for a development of matching and passive elements on MMIC.

임플란트 보철물의 연결 여부에 따른 유한요소응력분석 (Finite Element Analysis on the Supporting Bone according to the Connection Condition of Implant Prosthesis)

  • 강재석;정제옥;이승훈
    • 구강회복응용과학지
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    • 제23권1호
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    • pp.31-42
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    • 2007
  • The purpose of this study was to compare the stress distribution according to the splinting condition and non-splinting conditions on the finite element models of the two units implant prostheses. The finite element model was designed with the parallel placement of two fixtures ($4.0mm{\times}11.5mm$) on the mandibular 1st and 2nd molars. A cemented abutment and gold screw were used for superstructures. A FEA models assumed a state of optimal osseointegration, as the bone quality, inner cancellous bone and outer 2 mm compact bone was designed. This concluded that the cortical and trabecular bone were assumed to be perfectly bonded to the implant. Splinting condition had 2 mm contact surface and non-splinting condition had $8{\mu}m$ gap between two implant prosthesis. Two group (Splinting and non-splinting) were loaded with 200 N magnitude in vertical axis direction and were divided with subdivision group. Subdivision group was composed of three loading point; Center of central fossa, the 2 mm and 4 mm buccal offset point from the central fossa. Von Mises stress value were recorded and compared in the fixture-bone interface and bucco-lingual sections. The results were as follows; 1. In the vertical loading condition of central fossa, splinting condition had shown a different von Mises stress pattern compared to the non-splinting condition, while the maximum von Mises stress was similar. 2. Stresses around abutment screw were more concentrated in the splinting condition than the non-splinting condition. As the distance from central fossa increased, the stress concentration increased around abutment screw. 3. The magnitude of the stress in the cortical bone, fixture, abutment and gold screw were greater with the 4 mm buccal offset loading of the vertical axis than with the central loading.

치환 Phenyl N,N-diethyl-P-benzylphosphonamidates의 염기성 가수분해 반응에 대한 속도론적 연구 (Kinetic Study on the Alkaline Hydrolysis of the Substituted Phenyl N,N-diethyl-P-benzylphosphonamidates)

  • 손경화;신갑철
    • 대한화학회지
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    • 제43권1호
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    • pp.85-91
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    • 1999
  • Phenyl N,N-diethyl-P-benzylphonamidate 및 그 유도체들의 염기성 가수분해 반응속도 상수를 분광 광도법으로 측정하였다. 속도 상수로부터 열역학적 파라메타(Ea, ${\Delta}H^{\neq}$,${\Delta}S^{\neq}$)를 구하였고, 이탈기의 치환기 효과는 Hammett 식을 이용하여 얻었다. 이들 실험 자료에 의하면 가수분해 반응은 활성화 엔트로피가 양의 값이나 작은 음의 값을 갖고 카르보음이온 생성이 수반되는 해리반응 보다는 이중피라미드 중간체 또는 전이 상태를 경유하는 회합 메카니즘을 강력히 암시하고 있다. 반응속도론적 연구 결과에 의하면 치환 pheny N,N-diethyl-P-benzylphosphonamidates의 가수분해 반응은 회합성 메카니즘으로 진행됨을 알 수 있었다.

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Non-thermal Plasma Process for simultaneous removal of SO2/NOx from a Sintering Plant of Steel Works

  • 남창모;목영선;권기홍;서유덕;조병락
    • 한국산업융합학회 논문집
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    • 제6권1호
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    • pp.81-86
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    • 2003
  • For the simultaneous removal of $SO_2$/NOx from an iron-ore sintering plant, industrial plasma experiments have been conducted with a flue gas flow rate of $5,000Nm^3/hr$. The maximum 40kW power using the magnetic pulse compression (MPC) system generates a peak value of 100-150kV pulse voltage with its risetime of 200nsec and full width at half maximum (FWHM) of 500nsec, and with a frequency <300Hz. The plasma reactor module adopts a wire-plate structure with a gap of 200-400mm ID between plates. Initial concentrations of $SO_2$ and NOx were around 100-150ppm, respectively in the presence of 15% $O_2$ and <10% $H_2O$. Various reaction parameters such as specific energy ($Whr/Nm^3$), $NH_3$ injection with corona discharge, flow rate and injection of hydrocarbons were investigated for $SO_2$/NOx removal characteristics. About 90/65% of $SO_2$/NOx were simultaneously removed with a specific energy of $3.0Whr/Nm^3$ when both $NH_3$ and hydrocarbons were injected. Practical implications that the pilot-scale plasma results provide are further discussed.

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박판 연속 주조과정에 있어서 회전 로울러의 열변형에 관한 연구 (The study on the thermal deformation of the rotating rollers in strip continuous casting process)

  • 백남주;이상매
    • 대한기계학회논문집
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    • 제11권6호
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    • pp.913-922
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    • 1987
  • 본 연구에서는 Sn-15% Pb 재료에 대하여 실험에 의한 쌍 로울식 연속 주조의 주조특성을 구하고 로울러 열팽창과 열응력에 대한 유한요소해석을 통하여 제품 두께 와 로울러 변형과의 관계를 밝히고자 한다.

$MnO_2$ 첨가량에 따른 비납계 (Na,K,Li)(Nb,Sb,Ta)$O_3$ 세라믹스의 전기적특성 (Electrical properties of lead free (Na,K,Li)(Nb,Sb,Ta)$O_3$ ceramics with $MnO_2$ addition)

  • 이승환;남성필;이성갑;신동진;이영희
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2011년도 제42회 하계학술대회
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    • pp.1487-1488
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    • 2011
  • Electrical properties and microstructure were investigated on the effects of $MnO_2$ and the lead-free $(Na_{0.44}K_{0.52}Li_{0.04})(Nb_{0.83}Sb_{0.07}Ta_{0.1})O_3$ ceramics with the addition of $MnO_2$ were fabricated by a conventional mixed oxide method. A gradual change in the crystal and microstructure was observed with the increase of $MnO_2$ addition. For the NKN-LST-xmol%$MnO_2$ sintered at $1100^{\circ}C$, bulk density increased with the addition of $MnO_2$ and showed maximum value at addition 1.0mol% of $MnO_2$. Curie temperature of the NKN-LST ceramics slightly decreased with adding $MnO_2$. The dielectric constant, piezoelectric constant ($d_{33}$) and electromechanical coupling factor ($k_p$) increased below 0.25mol% of $MnO_2$ addition, which might be due to the increase in density. The high piezoelectric properties = 145 pC/N, electromechanical coupling factor = 0.421 and dielectric constant = 2883 were obtained for the NKN-LST-0.25mol%$MnO_2$ sintered at $1100^{\circ}C$ for 4h.

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