• 한국미생물·생명공학회지
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• 제10권1호
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• pp.39-43
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• 1982

항진균성 항생물질 생산균으로 분리된 Streptomyces균 No. 297 균의 배양액으로부터 항균물질을 분리·정제하여 침상결정을 얻었다. 이 물질은 UV. IR. spectra, NMR, Mass-spectra 및 여러 화학반응시험을 통하여 t-cin-namamide로 동정되었다. 항균 spectra를 조사해본 결과 Pellicularia sasakii, Pyricularia oryzae 기타 및 병원성 진균류에 강한 항균성을 나타내며 세균류에는 항균력이 극히 약한 것이 특징이다.

• Bulletin of the Korean Chemical Society
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• 제30권5호
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• pp.1061-1066
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• 2009

Two fluoro-substituted 2-pyrazoline derivatives, 1-phenyl-3-(4-methoxyphenyl)-5-(4-fluorophenyl)-2-pyrazoline (1) and 1-phenyl-3-(4-methoxyphenyl)-5-(2-fluoro-phenyl)-2-pyrazoline (2) have been synthesized and characterized by elemental analysis, IR, UV-Vis and fluorescence spectra. The crystal structure of 1 has been determined by X-ray single crystal diffraction. For the two compounds, density functional theory (DFT) calculations of the structures and natural population atomic charge analysis (NPA) have been performed at B3LYP/6-311G** level of theory. By using TD-DFT method, electron spectra of 1 and 2 have been predicted, which are very approximate with the experimental ones. Comparative studies on 1 and 2 indicate that the location change of fluorine atom in 5-position phenyl ring of 2-pyrazoline does not make significant change of geometries and electronic transition bands, but it leads to evident change of atomic charge distributions and peak intensities of UV and fluorescence spectra.

• 한국안광학회지
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• 제7권1호
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• pp.29-34
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• 2002

Venzotriazol계를 증류수로 희석(5%)하여 만든 UV 차단 출발액을 dip 방법으로 각각 1, 2, 5, 15, 20, 30분 간격으로 유지시켜 UV 차단렌즈의 시료를 제작하였다. 각 시료에 대한 광 투과율의 spectrum은 320~450nm 영역에서 측정하였다. 그 결과 광흡수 edge는 각각 403, 408, 414, 419nm 영역이며, 각각 3.07, 3.04, 2.99, 2.96eV의 band에서 흡수 edge가 나타났다. UV 차단 렌즈 출발용액은 benzophenone계의 2-Hydroxy-4-n-octoxybenzo-phenone를 methanol에 녹여 5%, 10%을 만들고, UV 차단 렌즈는 Spray pyrolysis method로 만들었다. 등 간격으로 분무한 각 렌즈의 투과 광의 edge는 spectra에서 거의 등 간격을 보였다. 2, 4, 6분 동안 분무할 때의 광 흡수 edge는 385, 398, 417nm 영역이며, band는 각각 3.22, 3.11, 2.97eV를 이루고 있다.

• E2M - 전기 전자와 첨단 소재
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• 제8권4호
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• pp.458-463
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• 1995

The optical and electrical properties of $C_{22}$-Quinolinium(TCNQ) Langmuir-Blodgett films have been studied depending on the annealing temperatures. The optimal properties were investigated using UV/visible(300-800[nm]) absorption spectra and FTIR(Fourier-transformed- infrared) absorption measurements. The electrical properties were investigated in a frequency range of 10[Hz]-13[MHz]. The UV/visible absorption spectra at room temperature show that there are four characteristic peaks at 320, 380, 494 and 678[nm]. These absorption peaks decrease very rapidly above the annealing temperature of 180[.deg. C], which is due to a structural change of TCNQ. The FTIR absorption measurements strongly support the result of the UV/visible absorption spectra, because the absorption peak of TCNQ- at 2181[$cm^{-1}$ /] also decreases above 140[.deg. C]. The frequency-dependent dielectric constant shows that there is a dielectric dispersion near 1[MHz] which is due to an orientational polarization of the molecules inside the film. The overall frequency-dependent dielectric constant is higher near 80[.deg. C]. It may be due to a softness of the alkyl chains.s.

• 한국의류학회지
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• 제11권3호
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• pp.25-32
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• 1987

The purpose of this study is to investigate optical behaviour of coloring matter of gromwell -extracted by water, acetic acid/methanol, and the other solvents. The results were as following: UV, VIS spectra of the solution of coloring matter of gromwell extracted by water at below $80^{\circ}C$ did not reveal in the range of the visible light wavelength and coloring matter of gromwell decomposed to blue particle at $95^{\circ}C$. The solution extracted by acetic acid/methanol was tinged with reddish purple and its spectra shifted to the longer wavelength according to increase of the solvent temperature. The color of the solution extracted by water became extinct as time went by, but that extracted by acetic acid/methanol kept up original color. In case of dried gromwell, extraction by acetic acid/methanol was easier than by water, and variation of spectra did not appear but showed hypochromic shift.

• 천문학회보
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• 제36권2호
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• pp.72.1-72.1
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• 2011

We investigate the relation between AGN gas metallicity and their host galaxy stellar metallicity using a sample of local Seyfert 1 galaxies. Stellar metallicity is measured from stellar absorption lines while AGN gas metallicity is derived from the flux ratios of UV emission lines. We use a high quality spectra obtained from the Lick AGN Monitoring Project, to obtain pure host galaxy spectra based on the spectral decomposition analysis, leading to accurate measurements of the Mg2 (5175) and Fe (5270) indices. In the case of AGN gas metallicity, we measure the ratio of NV1240 to CIV1549 lines using UV spectra from the archival IUE and HST STIS data. We will present the results of metallicity measurements and comparison between AGN and stellar metallicity, and discuss the implications of the results.

• Bulletin of the Korean Chemical Society
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• 제30권7호
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• pp.1567-1572
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• 2009

Conformational change of ubiquitin variant with valine to alanine mutation at sequence position 26 was studied by varying solvent pH. Fluorescence emission spectra indicated that this variant ubiquitin has some residual structures in acidic and basic solution as compared to denaturant-induced unfolded state. Far-UV circular dichroic spectra indicated that the base-denatured state had more secondary structure than the acid-denatured state. Near-UV circular dichroic spectra indicated that the aromatic side-chains were in the relatively more rigid environment in the base-denatured state than those in the acid-denatured state. Although it appears that the more tertiary structure present in the base-denatured state, refolding reactions measured by stopped-flow fluorescence device suggest that both the acid- and base-denatured states occur before the major folding transition state. The acid- and base-denatured states are considered to reflect the early event of protein folding process.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1995년도 하계학술대회 논문집 C
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• pp.1184-1186
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• 1995

The absorption spectra of synthesis of azobenzene containing long chain fatty acids were investigated by UV spectrophotometer in chloroform solution. Also, the pressure-area isotherms of the molecules on the water-air interface were obtained and the LB films were fabricated onto a quartz slides and quartz crystals by the conventional Langmuir-Blodggett(LB) method. The UV absorption spectra of Langmuir-Blodggett(LB) films on quartz slides have been measured. From these measurements, following conclusions were obtained. Azobenzene containing long chain fatty acids show a photoisomerization by irradiation of UV light and visible light alternatively. At the pressure-area isotherms, the value of surface pressure increment were decreased when the number of $C_n$ increased. Also the LB films show a photoisomerization characteristics. So the LB film of azobenzene containing long chain fatty acid has possibility to being applied to functional molecular device such as photomemory and light switching.

• Bulletin of the Korean Chemical Society
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• 제33권2호
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• pp.597-600
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• 2012

Polyynes were formed by laser ablation of a graphite target in deionized water ($H_2O$ and $D_2O$) and various organic solvents such as acetonitrile, n-hexane, and c-hexane and were identified by analyzing ultraviolet (UV) absorption and Raman spectra. We assigned the major UV absorption peaks that coincided with the electronic transitions corresponding to linear polyyne chains. The UV absorption peak intensities of a polyyne solution decreased as the holding temperature of the solution increased. Also, the absorption spectra of polyynes obtained by laser ablation of a graphite target at different volume fractions of $H_2O$ and $D_2O$ were examined.

• E2M - 전기 전자와 첨단 소재
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• 제10권3호
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• pp.284-288
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• 1997

FT-IR and FT-Raman spectra were measured for 15Li$_{2}$O.3Al$_{2}$O$_{3}$.78SiO$_{2}$. 4K$_{2}$O glass system after UV irradiations. Optimum UV irradiation time of Li$_{2}$O.SiO$_{2}$ crystalline phase was 60 seconds and crystalline phase of Li$_{2}$O.SiO$_{2}$ was leached out on 5% HF. 977 cm$^{1}$ band of FT-Raman spectra can be attributed to two-non bridging oxygen in unit cell for 1 hour and optimum crystallization was confirmed for 3 hrs, 630.deg. C.