• Title/Summary/Keyword: uv exposure

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Photodegradation Characterization of Polyolefin Composite (폴리올레핀 복합소재의 UV 광열화 특성)

  • Weon, Jong-Il;Shin, Sei-Moon;Choi, Kil-Yeong
    • Applied Chemistry for Engineering
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    • v.20 no.5
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    • pp.511-516
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    • 2009
  • Photodegradation characteristics of polyolefin composites were studied. Thermogravimetric analysis results suggest that the polyolefin blends used in this study have different amounts of talc. The mechanical behaviors of polyolefin blends, which experienced UV-irradiation in accordance with SAE J1960, are investigated using tensile and Izod impact tests. These results show that as the UV-exposure time increases, a significant drop in the elongation at break and impact strength at a low temperature are observed. This may be explained by the decreases in elastic energy derived from the scission of polymer molecular chains and the low density of entanglement after UV- photodegradation. Scanning electron microscopy observations indicate that no crack and surface damage are observed, while the additional talc particles are exposed, on the UV-exposed surfaces. The exposure of talc particles may be responsible for the discoloration of UV-exposed polyolefin blend surface. Observation using Fourier transform infrared spectroscopy (FT-IR) confirms the presence of photodegradation on the surface of UV-exposed polyolefin blend.

Studies on the improvement of UV sterilizer for toothbrush (가정용 칫솔 UV 살균기의 성능 개선법에 관한 연구)

  • Yang, Eun-Jung;Lee, Mi-Seon;Kim, Jung-Woo
    • The Journal of Natural Sciences
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    • v.11 no.1
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    • pp.41-44
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    • 1999
  • For the purpose of improving the UV sterilization for toothbrush, the sterilizing effects by the UV light were studied. When toothbrushes were treated with the UV light for 5, 15, 30, 60 minutes, the sufficient antibacterial effect were shown after 15 minutes with 80% of bactericidal effects. To prevent the brownish stain on the sterilizer which was caused by the long exposure of UV light, no UV treatment for two hours after 15 minutes exposure were scheduled and then 3 minutes re-exposure were performed, which showed 97% of bactericidal effect. Also, the antibacterial effects of the sterilizer showed different results depending on the position of the toothbrush, it was recommended to adjust toothbrush to be exposed by the UV light directly.

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Liquid Crystal Alignment Effect on the Inorganic Thin Film by Sputtering and using Ultraviolet Exposure Mothod

  • Hwang, Jeoung-Yeon;Kang, Hyung-Ku;Seo, Dae-Shik;Oh, Byeong-Yun;Ham, Moon-Ho;Myoungr, Jae-Min
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07a
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    • pp.460-463
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    • 2005
  • We studied the nematic liquid crystal (NLC) alignment capability by the Ultraviolet (UV) alignment method on a a-C:H thin -film , and investigated electro-optical performances of the UV aligned twisted nematic (TN)- liquid crystal display (LCD) with the UV exposure on a-C:H thin film surface. A good LC alignment by UV irradiation on a a-C:H thin -film surface was achieved. Monodomain alignment of the UV aligned TN-LCD can be observed. The good electro-optical (EO)characteristics of the UV aligned TN-LCD was observed with oblique UV exposure on the a-C:H thin film surface for 1min.

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A Study on the Effect of Accelerated UV Exposure on the Polymer Membrane for Outdoor Users (옥외용 고분자 막의 촉진 자외선 노출 영향 연구)

  • Lee, Joo Hyuk;Kim, Sung Bok;Cho, Kuk Young
    • Applied Chemistry for Engineering
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    • v.26 no.3
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    • pp.326-330
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    • 2015
  • Polymeric membranes have been used in various applications and generally applied to the systems prevented from exterior exposure. However, polymer membranes for outdoor usages such as, an air quality monitoring and membrane reservoirs for the selective recovery of useful metals from seawater, have been newly developed. Thus it is required to investigate the properties of the membrane for the outdoor use and also studies of the accelerated UV exposure onto the polymeric membranes are essential to estimate their weatherability. Herein, we report on the thermal and mechanical properties, morphology changes, and color differences of the polysulfone anisotropic membranes and non-woven type polypropylene membranes with the accelerated UV exposure. Results showed that the effect of UV exposure on the membrane depend not only on the polymer used but also on the form of the membrane. This work can provide some of key informations of the membrane for outdoor use.

Aging Evaluation of Polymer Insulator Housing with UV Exposure (자외선 노출에 따른 폴리머애자 하우징의 열화특성평가)

  • 이병성;한재홍;김찬영;한용희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.05a
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    • pp.214-217
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    • 1999
  • Polymeric composite insulators have been in use for outdoor insulation. However, our knowledge about their long-term performance in a outdoor environment is still very limited. Especially, these insulator are subjected to the environmental stress such as ultraviolet radiation. Hence, in this paper. the influence of UV radiation on the aging of the shed materials was evaluated. For the aging evaluation, these insulators studied by experiment methods such as contact angle measurement. oxidation induced time. SEM/EDX, FTRI-ATR, tracking test for the different insulator samples. With the increased UV exposure time, samples are shown to exhibit degradation comparable to those of new ones

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The Effect of Anti-UV Agents on UV Shielding and Photolytic Aging of Paper

  • Park Saung Bae;Hyun Byung Doo;Eom Tae Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.5 s.108
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    • pp.36-43
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    • 2004
  • The behaviors of deterioration in the mechanical and optical properties of paper during sunlight exposure are mainly attributed to UV irradiation. The effect of different additives (anti-UV agents) on paper properties during exposure was studied. The results showed negligible changes in the mechanical properties of samples prepared with two different ways, whereas the shielding ability was increased when the additives were applied to the surface of hand sheets. Also, the paper which is treated with anti UV agents can keep freshness more effectively of agricultural products from UV irradiation.

Electro-optical characteristics of photo-aligned VA-LCD using a new photo-polymer (새로운 광 폴리머를 이용한 광배향 VA-LCD의 전기 광학 특성)

  • Hwang, Jeoung-Yeon;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.04a
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    • pp.181-184
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    • 2000
  • A new photo-alignment material, copoly (PM4Ch-ChMA), copoly (poly (4-methacryloyloxy) chalcone-chalconemethacryl) was synthesized and the electro-optical (EO) characteristics for the photo-aligned vertically aligned (VA)-LC display (LCD) were investigated. The monodomain alignment of the NLC for the photo-aligned VA-LCD by linearly polarized UV exposure on the photo-dimerized copoly (PM4Ch-ChMA) surfaces was observed. Excellent voltage-transmittance characteristics for the photo-aligned VA-LCD by UV exposure for 1 min. on the copoly (PM4Ch-ChMA) surfaces were achieved. The response time of the photo-aligned VA-LCD by UV exposure on for 1 min. the copoly (PM4Ch-ChMA) surfaces was about 39.3 ms. The response time for the photo-aligned VA-LCD decreased with increasing UV exposure time.

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Evaluation on Physical and Mechanical Properties of Wood Plastic Composites Treated under Ultraviolet Irradiation (자외선을 처리한 목재 플라스틱 복합재의 물리 및 역학적 성질 평가)

  • Lee, Jong-Shin;Kim, Soung-Joon
    • Journal of the Korea Furniture Society
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    • v.26 no.4
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    • pp.428-434
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    • 2015
  • In this study, we received each wood plastic composites (WPC) from three manufacturers. These WPCs were evaluated regarding their physical and mechanical properties of both before and after accelerated weathering by ultraviolet (UV) irradiation. The total time of exposure of the WPCs to UV irradiation was 1800 h. The water absorption, volumetric swelling and shrinkage of WPCs did not affected by UV irradiation. Among the mechanical properties, there was no significant differences in bending strength and screw withdrawal resistance of UV treated WPCs compared with those of reference WPCs. However, surface hardness of WPCs showed decrease under UV irradiation. Stereoscopic microscopy observation revealed deterioration of the surface layer polymer in all weathered WPCs by UV. Exposure of the WPCs to UV irradiation caused decomposition and disappearance of the polymer layer. From this result, we can estimate that damage of polymer by UV led to a decrease in the surface hardness of the WPCs. The wood flours retained original shape after accelerated weathering by UV irradiation.

Improving UV-cut Ability of Natural Dyed Fabrics - Focused on Cellulose Fabrics Dyed with Safflower Yellow Colorants - (천연염색 직물의 자외선 차단 성능 증진 연구 - 홍화 황색소 염색 셀룰로오스 직물을 중심으로 -)

  • Shin, Youn-Sook;Choi, Seung-Youn
    • Journal of the Korean Home Economics Association
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    • v.45 no.10
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    • pp.73-81
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    • 2007
  • The purpose of this study was to increase the ultraviolet-light (UV)-cut ability of cellulose fabrics (cotton, ramie, and rayon) dyed with safflower yellow colorants. For this purpose, samples treated with UV-cut agent and tannic-acid were compared with the untreated samples after UV exposure in terms of K/S value, color changes(${\Delta}E$), SEM, and strength retention. The K/S value rapidly decreased after 28 days exposure, whereas the K/S value of the samples treated with both UV-cut agent and tannic-acid decreased to less than that of the untreated samples. In color changes, $L^*$ increased while $a^*$ and $b^*$ decreased, indicating less red and yellow character in color. This induced a change in the hue, value and chroma values. However the color change(${\Delta}E$) of the samples treated with both UV-cut agent and tannic-acid was less than that of the untreated samples. Scanning electron microscopy (SEM) pictures showed a severe degradation by exposure in all samples. Tensile strength rapidly decreased after 28 days for cotton and rayon, and after 21 days for ramie. However, the strength retention of the samples treated with UV-cut agent and tannic-acid was higher than that of the untreated samples.

Characterization of Photovoltaic Module Encapsulant According to UV Irradiation Dose (자외선 조사량에 따른 태양전지 모듈 봉지재의 특성 분석)

  • Lee, Song-Eun;Bae, Joon-Hak;Shin, Jae-Won;Jeon, Chan-Wook
    • Current Photovoltaic Research
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    • v.6 no.3
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    • pp.81-85
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    • 2018
  • The photovoltaic modules installed in the actual field are affected by various external environments and the electrical performance output value is generally lowered compared to initial output value. The most of photovoltaic modules consists of low iron glass, encapsulant (EVA), back sheet, frame and junction box assembly based on the solar cells. In this paper, the characteristics of encapsulant which is an important constituent material of photovoltaic module were verified by maximum power determination, electro luminescence images, yellowness index measurement, and gel content measurement after ultraviolet (UV) irradiation exposure. The most commonly installed 72 cells crystalline photovoltaic modules were tested after various UV exposure of 0, 15, 30, and $60kWh/m^2$ and compared with the reference module. After UV exposure of $15kWh/m^2$, which is the current international test condition, a small amount of change was observed in yellowness index and electroluminescence, while a gell content rapidly increased. At a cumulative dose of $60kWh/m^2$, which will be a new international test condition in the near future, however, the yellowness index increased sharply and showed the greatest output power drop.