• Title/Summary/Keyword: urea method

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Nickel Supported Adsorbent for Removing Carbon Monoxide (일산화탄소 제거를 위한 니켈 담지 흡착제 제조)

  • Son, Jung-hwa;Kim, Young-ho;Yoon, Songhun;Park, Yong-Ki;Lee, Chul Wee
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.868-874
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    • 2008
  • The Ni based adsorbent was prepared by co-precipitation method and its performance for removing carbon monoxide was investigated. Here, silica, aluminium silicate and ${\gamma}$-alumina were used for carriers of catalyst. $Ni(NO_3)_2{\cdot}6H_2O$ and $Ni(CH_3COO)_2{\cdot}4H_2O$ were utilized for Ni precursors. Precipitants were urea and citric acid. After precipitation of Ni salt on the carrier and following reduction using $H_2$ gas, adsorbent was prepared and its performance was analyzed based on EDS, TPR and XRD experiments. In accordance with change of precipitation agents, Ni salts on carrier, carriers and reduction condition. Adsorbent performance for removing carbon monoxide was investigated. The adsorbent with 54.8 wt% Ni prepared using urea precipitant under reduction condition at $500^{\circ}C$ for 3 h exhibited the best CO removal performance.

Growth Inhibition of Helicobacter pylori by Ingestion of Fermented Soybean Paste (된장 섭취에 의한 Helicobacter pylori의 생장 억제)

  • Kim, Hyung-Rak;Kim, Young-Hyu;Park, Seong-Chan;Kim, Mi-Sun;Baik, Keun-Sik;Cho, Hyun-Wook;Seong, Chi-Nam
    • Journal of Life Science
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    • v.17 no.12
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    • pp.1695-1700
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    • 2007
  • The aim of this study was to estimate the ingestion effect of fermented soybean paste on the growth inhibition of Helicobacter pylori. Anti-H. pylori effect of the aqueous extract of soybean paste and cell-free supernatant of the isolates from soybean paste were determined using agar diffusion method. Soybean paste and the isolates inhibited the growth of H. pylori. Effect of soybean paste ingestion was estimated using urea breath test against infected volunteers showing no symptom of gastric disease. When 10 g of soybean paste was ingested 3 times a day for 6 weeks, average value of $P={\Delta}^{13}C(T_1-T_0)$ decreased from P=58 to P=28. This result indicated that fermented soybean paste was effective to inhibit the growth of H. pylori in gastric tissue.

Evaluation of NH3 emissions in accordance with the pH of biochar

  • Yun-Gu, Kang;Jae-Han, Lee;Jin-Hyuk, Chun;Yeo-Uk, Yun;Taek-Keun, Oh;Jwa-Kyung, Sung
    • Korean Journal of Agricultural Science
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    • v.48 no.4
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    • pp.787-796
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    • 2021
  • Nitrogen (N) is the most important element during the process of plant growth, and the quality of crops varies depending on the amount of nitrogen present. Most of the nitrogen is used for plant growth, but approximately 10 - 20% of Nitrogen is carried away by the wind in the form of NH3. This volatilized NH3 reacts with various oxides in the atmosphere to generate secondary particulate matter. To address this, the present study attempts to reduce NH3 occurring in the soil using biochar at a specific pH. Biochar was used as a treatment with 1% (w·w-1) of the soil, and urea was applied at different levels of 160, 320, and 640 kg·N·ha-1. NH3 generated in the soil was collected using a dynamic column and analyzed using the indophenol blue method. NH3 showed the maximum emission within 4 - 7 days after the fertilizer treatment, decreasing sharply afterward. NH3 emission levels were reduced with the biochar treatment in all cases. Among them, the best reduction efficiency was found to be approximately 25% for the 320 kg·ha-1 + pH 6.7 biochar treatment. Consequently, in order to reduce the amount of NH3 generated in the soil, it is most effective to use pH 6.7 biochar and a standard amount (320 kg·N·ha-1) of urea.

Effects of different nitrogen fertilizer applications on growth of Chinese cabbage (Brassica rapa L. ssp. pekinensis)

  • Jin-Hyuk Chun;Yun-Gu Kang;Yong-Jun Yu;Jae-Han Lee;Yeo-Uk Yun;Taek-Keun Oh
    • Korean Journal of Agricultural Science
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    • v.49 no.4
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    • pp.709-718
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    • 2022
  • Nitrogen (N) is a vital element in growing crops and is essential for improving the yield and quality of crops. Thus, N fertilizer is the most widely used fertilizer and the primary N input source in soil-crop systems. Inorganic fertilizers such as urea are known to improve crop productivity and increase soil fertility. However, application with excessive amounts can interfere with crop growth and accelerate soil acidification. For these reasons, the use of organic fertilizers, which mainly contain organic nitrogen, has gradually increased worldwide. Therefore, this study evaluated the effects of N fertilizer on the growth of Chinese cabbage including its functional compounds glucosinolates (GSLs). For the cultivation of Chinse cabbage, inorganic fertilizer was used for urea, and organic fertilizers were divided into conventional and biochar-based fertilizers. The growth parameters of Chinese cabbage treated by organic fertilizers was better than those of the inorganic fertilizers. Additionally, it was found that their co-application was more efficient. However, their GSL contents were lower with the application of the organic fertilizers. The characteristics of the experimental soil also changed according to the type, amounts and co-application of fertilizers. Therefore, this study presents the basis for an eco-friendly method that can increase the functionality and productivity of Chinese cabbage compared to conventional cultivations.

Studies on the Influence of the Time of Nitrogen Top-dressing and Top dressing Method to the Yields and the Various Factors concerned with Yields in Wheat (질소의 추비기 및 추비방법이 소맥의 수량 및 수량요인에 미치는 영향)

  • Jae-Young Cho;Dong-Woo Lee;Chang-Hwan Cho;Byong-Hee Hong
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.7 no.1
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    • pp.103-115
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    • 1969
  • A study has been made on the time of nitrogen top-dressing and the method of top-dressing to establish the higher yielding cultural method for wheat at Suwon. In this experiment, it was observed that the application of nitrogen top-dressing with urea leaf spray as spike fertilizer increased the yield by 4~6 percent over nitrogen top-dressing of equal quantity only. Considering the yield and various factors concerned, it is reasonable to apply top-dressing on mid and late of March in Suwon area.

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Synthesis and Characterization of Anatase TiO2 Powder using a Homogeneous Precipitation Method (균일침전법을 이용한 아나타제형 TiO2 분말의 제조 및 특성 평가)

  • Choi, Soon Ok;Cho, Jee Hee;Lim, Sung Hwan;Chung, Eun Young
    • Korean Journal of Metals and Materials
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    • v.49 no.5
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    • pp.367-373
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    • 2011
  • This paper studies the experimental method that uses the homogeneous precipitation method to prepare mica flakes coated with anatase-type titania pearlescent pigment with urea as precipitant. The optimum technology parameters, the chemical composition, the microstructure, and the color property of resulting pigments are discussed. The coating principle of mica coated titania with various coating thickness is analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy(TEM) and tested by spectrophotometer analysis. The colored nanocrystalline pigments with different morphology and coating thickness 45-170 nm were prepared by homogeneous precipitation treatment of $TiOSO_4$(titanum oxysulfate) aqueous solutions. Characterizations on the pigments show that the pearlescent effects of the pigments depend mainly on mica size, thickness of the metal oxide deposit, its chemical composition, and crystal structure.

Nutritional Studies for Improvement of Feeding on Korean Native Goat - Absorption of Nutrients in Rumen - (한국재래산양(韓國在來山羊)의 사양개선(飼養改善)에 관(關)한 연구(硏究) - 제일위((第一胃)에서의 영양소(營養素) 흡수(吸收)에 대(對)하여 -)

  • Kwon, Soon Ki
    • Korean Journal of Agricultural Science
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    • v.9 no.1
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    • pp.284-302
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    • 1982
  • Development of protein resources as food has been a big issue especially in Southeast Asia region, and intake of protein is also insufficient in Korea. To cope with this shortage of protein resources and its improvement together with increased production of high nutritive animal protein, studies were carried out on feeding of Korean native goats. In the experiments were made absorption of carbohydrate and volatile fatty acid in miniature rumen, and absorption of amino acid in rumen as in vivo were conducted as part of studies on nutritional absorption in rumen. Those nutritional for improvement of feeding and management as described above are summarized as following. 1. According to the result of test on the nutritional absorption of native goat by means of miniature rumen method, absorption ratio of VFA measured at 0.5, 1 and 2 hours after injection of nutrition showed propionic acid 70-86%, acetic acid 74-87%, and lactic acid 76-89%. In the absorption of organic substances, ethyl alcohol of 0.5% showed 29-87% and lactic acid of 0.1M showed 12-27% of absorption ratio. 2. Result of absorption measurement in rumen from L-type free amino acid injection in the content of rumen vein showed lower rate at menthionine-free group compared to whole-egg amino acid injection in the content of rumen vein showed lower rate at methioine-free group compared to whole-egg amino acid group, and high absorption ratio was observed at methionine 3 times group and urea added group. Deficiency of methionine caused no change of the content in mucous membranes. 3. Absorption of amino acid in rumen muscular layer showed equal tendency as in the mucous membrane without exerting any influence of methionine deficiency. At the methionine3-times group, content of methionine and glutamine were increased by 14.7 and 4.4 times as compared to whole-egg amino acid group, an absorption ratio of glutamine, proline and valine were increased at urea added group. 4. In general, concentration of amino acid in rumen vein plasma was lower than in rumen mucous membrane and muscular layer. Absorption ratio of amino acid is decreased due to methionine deficiency, and tripling of methionine or urea adding caused increment of amino acid. Absorption pattern is thus varied depending on the composition of amino acid. 5. At the urea added group, content of ammonia-N, amino-N and urea were increased in rumen muscular layer. As the inside of goat's rumen was unable to clean thoroughly, investigation was made on remaining bacteria, however, variation of ammonia-N was affected by these bacterial content. 6. Variation in rumen structure by differential absorption of amino acid was observed by general microscope and fluorescent microscope. According to the result of observation in the methionine 3 times group, single cylinder epithelium of mucous membrane showed rather thin, and it was thick at urea added group though no significant differences existed among test groups in submucous membrane and muscular layer.

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One-Pot and Green Procedure for the Synthesis of 3,4-Dihydropyrimidin-2(1H)-(thio)ones Using ZnO Nanoparticles as a Solid Acid Catalyst

  • Hassanpour, Akbar;Abolhasani, Jafar;Khanmiri, Rahim Hosseinzadeh
    • Journal of the Korean Chemical Society
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    • v.58 no.5
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    • pp.445-449
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    • 2014
  • A convenient and efficient method has been developed for the one-pot synthesis of dihydropyrimidinones (DHPMs) compounds. Dihydropyrimidinone derivatives were synthesized in good yields using ethyl acetoacetate, aldehyde (aromatic and aliphatic) and urea or thiourea in the presence of ZnO nanoparticles as a catalyst in $H_2O$ as solvent at $80^{\circ}C$. This green chemistry procedure applied to the Biginelli reaction using ZnO nanoparticles as catalyst and illustrated as a rapid preparation of DHPMs in water as solvent. The products were identified by physical data (mp) by comparison with those reported in the literatures.

Production of Polyclonal Antibodies against the Tegument of Sparganum (Plerocercoid of Spirometra mansoni) and Its Immunolocalization

  • Yang, Hyun-Jong
    • Parasites, Hosts and Diseases
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    • v.48 no.2
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    • pp.183-185
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    • 2010
  • In a previous study, the author developed a method for separation of the tegument of spargana (plerocercoids of Spirometra mansoni) from the parenchyme using urea. The present study, as a next step, was performed to evaluate which molecules are present in the outer tegument. Two major proteins, 180 and 200 kDa, are present in the tegument and we could make polyclonal antibodies against these molecules. Their immunolocalization was processed and the outermost layer of the spargana showed strong positive staining. Conclusively, we could confirm that the 180 and 200 kDa molecules might be tightly bound membrane proteins in the tegument of spargana.

Application of Photocatalytic Decomposition of Methylene Blue on N-doped TiO2 (질소 도핑 TiO2의 Methylene Blue 광분해 제거에의 적용)

  • Baek, Mi-Hwa;Choi, Su-A;Kim, Dong-Su
    • Journal of Korean Society on Water Environment
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    • v.26 no.4
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    • pp.707-712
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    • 2010
  • Nitrogen-doped $TiO_2$ particles have been successfully prepared using titanium tetraisopropoxide as the Ti source and urea as the nitrogen source. As-prepared nitrogen-doped $TiO_2$ was characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller method (BET) and ultraviolet-visible light (UV-vis) absorption spectra techniques. Photocatalytic degradation of Methylene Blue (MB) has been carried out in both solar light (UV-vis) and the visible region (${\lambda}=420nm$). Nitrogen-doped $TiO_2$ exhibits higher activity than the commercial $TiO_2$ photocalyst, particularly under visible-light irradiation because bandgap of nitrogen-doped $TiO_2$ becomes remarkably decreased.