• Title/Summary/Keyword: under-dispersion

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Vapor Bubble Nucleation : A Microscopic Phenomenon

  • Kwak, Ho-Young
    • Journal of Mechanical Science and Technology
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    • v.18 no.8
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    • pp.1271-1287
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    • 2004
  • In this article, vapor bubble nucleation in liquid and the evaporation process of a liquid droplet at its superheat limit were discussed from the viewpoint of molecular clustering (molecular cluster model for bubble nucleation). For the vapor bubble formation, the energy barrier against bubble nucleation was estimated by the molecular interaction due to the London dispersion force. Bubble nucleation by quantum tunneling in liquid helium under negative pressure near the absolute zero temperature and bubble nucleation on cavity free micro heaters were also presented as the homogenous nucleation processes.

Robustness for Omnibus Tests using Trimmed Means under Violated Assumptions

  • Hyunchul Kim
    • Communications for Statistical Applications and Methods
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    • v.4 no.2
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    • pp.581-588
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    • 1997
  • Univariate F test is based on the multisample sphericity assumption. Robustness for tests of a main effect of the within-subjects factor was investigated when the assumptions of the onmibus F tests are violated in a split-plot design with one between-subjects factor using untrimmed data and trimmed data. The results indicate that when sample sizes are unbalanced and dispersion matrices are heterogeneous, the CIGA and the $CIGA_T$ tests better control Type I error rates than do the $F_T$test and the$\widetilde{\xi_T}$test.

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A Study on the Improvement of Atmospheric Dispersion Modelling in Coastal Areas under Low Wind Conditions (임해지역 저풍속 조건에서의 대기확산모델링 개선을 위한 연구)

  • 박옥현;이상훈;천성남
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.172-174
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    • 1999
  • 이전의 연구에서는 중정도에서 강한 풍속까지의 대기경계층 난류구조는 잘 해석하였으나, 저풍속 안정한 대기조건일 때 난류구조에 대해서는 아직까지 잘 알려져 있지 않다. 또한 육지와 거대한 수계의 열적 특성차이를 갖는 임해지역에서의 확산은 Praire지역을 비롯한 내륙지역과는 다른 특성을 갖는다. 임해지역에서는 오염원으로부터 중단거리에서 저풍속시에 지표상에 고농도가 발생하는 오염물질확산현상이 잘 발생한다.(중략)

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Recent Trends in Numerical Simulation of Liquid Sprays (분무 해석 시뮬레이션 기술의 최근 동향)

  • Huh, K.Y.
    • Journal of ILASS-Korea
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    • v.5 no.4
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    • pp.12-32
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    • 2000
  • The recent trends in numerical simulation of various spray phenomena are reviewed in this article. Major subtopics are atomization/breakup, collision/coalescence, wall collision, interfacial transfer, droplet dispersion, two-phase injection and spray combustion. Each submodel has been under continuous refinement and validation against more extensive data base by advanced laser diagnostic techniques. Most uncertainty in current spray simulations come from these physical submodels, not from excessive computational constraints.

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New Dispersion Function in the Rank Regression

  • Choi, Young-Hun
    • Communications for Statistical Applications and Methods
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    • v.9 no.1
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    • pp.101-113
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    • 2002
  • In this paper we introduce a new score generating (unction for the rank regression in the linear regression model. The score function compares the $\gamma$'th and s\`th power of the tail probabilities of the underlying probability distribution. We show that the rank estimate asymptotically converges to a multivariate normal. further we derive the asymptotic Pitman relative efficiencies and the most efficient values of $\gamma$ and s under the symmetric distribution such as uniform, normal, cauchy and double exponential distributions and the asymmetric distribution such as exponential and lognormal distributions respectively.

Experiments on Welding of Ceramics by Use of High Power Laser (고출력 레이저를 이용한 세라믹 재료의 용접 실험)

  • 변철웅
    • Journal of Welding and Joining
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    • v.12 no.2
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    • pp.39-48
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    • 1994
  • In comparison to the conventional brazing, laser welding of ceramics has advantages of direct bonding without filler material, which causes the thermal stress due to the differences of thermal expansion coefficients. In pulse-mode, laser welding of dispersion ceramic having high thermal resistance is possible at relatively low preheating temperature of $1300^{\circ}C$ In CW-mode, alumina can be welded at high preheating temperature $1500^{\circ}C$ under the condition of low feed rate of 500 mm/min, respectively. Further studies on developing mechanism of pores in the bead during laser welding of ceramics is required.

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Preparation and Properties of Polyorganosiloxane Modified Polyurethane Dispersion (Polyorganosiloxane 변성 Polyurethane Dispersion의 제조와 그 특성)

  • Kang, Doo Whan;Yin, Yong Nan
    • Applied Chemistry for Engineering
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    • v.21 no.1
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    • pp.46-51
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    • 2010
  • Polyorganosiloxane modified polyurethane (PDMS-PU) polymers were prepared from copolymerization of ${\alpha}$,${\omega}$-hydroxypropyl terminated polyorganosiloxane with isophorone diisocyanate (IPDI), polypropylene glycol (PPG), and 2,2-bis(hydroxymethyl) propionic acid (DMPA). Hydrophobic polyorganosiloxane was introduced in polyurethane main chain as soft segment block unit. The isocyanate groups in PDMS-PU block copolymer was blocked with 2-butanon oxime and obtained PDMS-PU dispersions in water by neutralizing with triethylamine (TEA). The deblocking temperature of PDMS-PU polymer was measured from thermal analysis. The good stability of the PDMS-PU dispersion was obtained by dispersing into water. PDMS-PU prepolymers were prepared with various contents of DMPA under [NCO]/[OH] = 1.12~1.53 equivalent ratio. Increasing DMPA from 7.2, 13.4, and 18.7 mole% in preparation of PDMS-PU polymer, particle sizes were decreased from 156, 100, 65 dnm. Also contact angle and adhesive strength were measured.

Preparation and Characterization of PEG-PLA(PLGA) Micelles for Solubilization of Pioglitazone (Pioglitazone 가용화를 위한 PEG-PLA(PLGA) 고분자 미셀의 제조 및 특성분석)

  • Im, Jeong-Hyuk;Lee, Yong-Kyu;Huh, Kang-Moo
    • Polymer(Korea)
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    • v.32 no.2
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    • pp.143-149
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    • 2008
  • We synthesized PEG-PLA (or PLGA) amphiphilic di-block copolymers, which consist of PEG as biocompatible and hydrophilic block and PLA (or PLGA) as biodegradable and hydrophobic block, by ring opening polymerization of LA in the presence of methoxy PEG as a macroinitiator. The compositions and the molecular weights of the copolymers were controlled by changing the feed ratio of LA (and GA) to PEG initiator. The di-block copolymers could self-assemble in aqueous media to form micellar structure. A hydrophobic model drug, pioglitazone, was loaded into the polymer micelle using solid dispersion and dialysis methods, and the drug-loaded micelles were characterized by AFM, DLS and HPLC measurements. The drug loading capacity and in vitro release studies were performed and evaluated under various conditions. These results indicated that the amphiphilic di-block copolymers of PEG-PLA (or PLGA) could solubilize pioglitazone by solid dispersion method and the drug release was modulated according to micellar chemical compositions.

Simulation of Transport and Transformation of Nonconservative Pollutants in Natural Streams: Storage-Transformation Model (자연하천에서 비보존성 오염물질의 이동 및 변환 모의: 저장-변환 모형)

  • Seo, Il Won;Yu, Dae Young
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.14 no.4
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    • pp.867-874
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    • 1994
  • The complex nature of low flow transport and transformation of nonconservative pollutants in natural streams has been investigated using a numerical solution of a proposed mathematical model that is based on a pair of mass balance equations describing the advection, dispersion, decay and mass exchange mechanisms in streams and in storage zones. In the present study, a mathematical model (named "Storage-Transformation Model") has been developed to predict adequately the non-Fickian nature of mixing and transformation mechanisms for decaying substances in natural streams under low flow conditions. Comparisons of the computed concentration-time curves with the measured data show that the Storage-Transformation Model yields better agreements in general shape, peak concentration and time to peak than the conventional 1-D dispersion model. The proposed model shows significant improvement over the 1-D dispersion model in predicting natural transport and transformation processes in streams through pools and riffles.

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Sonochemical Grafting of Poly(vinyl alcohol) onto Multiwall Carbon Nanotubes in Water (초음파를 이용한 PVA에 의한 다중벽 탄소나노튜브의 수상 그래프팅)

  • Kim, Yeongseon;Baeck, Sung Hyeon;Shim, Sang Eun
    • Polymer(Korea)
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    • v.38 no.3
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    • pp.378-385
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    • 2014
  • Multiwall carbon nanotubes (MWCNTs) were modified with a water soluble polymer, poly(vinyl alcohol), PVA, using a simple ultrasonic wave in water. Under the irradiation of ultrasound, PVA chains were severed as macroradicals and instantly grafted onto the surface of MWCNTs due to the radical scavenging effect of MWCNTs. To control the grafting PVA onto MWCNTs, the ultrasonication power and irradiation time were changed from 300 to 500 W and from 10 to 50 min, respectively. The grafted PVA onto MWCNTs was confirmed by FTIR, TGA, SEM, and TEM. Dispersion stability of the modified MWCNTs was monitored by Turbiscan. The amount of grafted PVA on MWCNTs increased with the increase in the sonication power and irradiation time. The grafted PVA on MWCNTs induced the improved dispersion stability of the modified MWCNTs in water. These findings exhibit that ultrasound can be readily used for the grafting polymer chains on MWCNTs.