• Macromolecular Research
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• 제12권1호
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• pp.11-21
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• 2004

Toughening of epoxy resins for improvement of crack resistance has been the subject of intense research interest during the last two decades. Epoxy resins are successfully toughened by blending with a suitable liquid rubber, which initially remains miscible with epoxy and undergoes a phase separation in the course of curing that leads to the formation of a two-phase microstructure, or by directly blending preformed rubbery particle. Unlike the situation for thermoplastics, physical blending is not successful for toughening epoxy resins. Recent advances in the development of various functionalized liquid rubber-based toughening agents and core-shell particles are discussed critically in this review.

• 소성∙가공
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• 제31권5호
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• pp.267-272
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• 2022

A dual-phase structure refers to a material with two different phases of components or crystal structures. In this study, we analyze the stress distributions for harmonic and composite structured materials which are a kind of dual-phase structure materials. The finite element method (FEM) was used to progress compression test to analyze the strain distribution, and rather than constituted of a fully dense material, a dual-phase structure was designed to make a lightweight structure that has different shapes and volumes of vacancy in each case. As a result of each case, the dual-phase structured materials showed different stress distribution patterns and based on this, the cause was identified through the research.

• 한국재료학회지
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• 제21권3호
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• pp.168-173
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• 2011

Precipitation of the ordered icosahedral quasicrystal in Mg-6wt%Zn-1wt%Y alloy has been characterized by transmission electron microscopy observations. The lamellar-type icosahedral qusicrystal phases (I-phase) with the face-centered icosahedral (FCI) structure are observed in alloy after solution treatment at $550^{\circ}C$. In the alloy annealed at $400^{\circ}C$, polygon-shaped I-phases are observed in the ${\alpha}$-Mg matrix. The interfaces of the I-phase with the matrix are facetted and the facets are on five-fold and two- fold plane of the I-phase. The orientation relationship of the I-phase with the matrix is determined to be $[I5]_I//[001]_{Mg}$, $(2f)_I//(2\overline{1}0)_{Mg}$ and $[I2]_I//[311]_{Mg}$, $(5f)_I//(0\overline{1}1)_{Mg}$. The icosahedral grains are occasionally found to be twinned with one of the five-fold axis as the twin axis. The twin boundaries appear to be fairly straight and perpendicular to the fivefold twin axis. The icosahedral twin can be expressed as a rotation of $63.4^{\circ}$ or $116.62^{\circ}$ around two fold zone axis.

• 한국재료학회지
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• 제24권8호
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• pp.429-433
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• 2014

As the fabrication technology used in FPDs(flat-panel displays) advances, the size of these panels is increasing and the pattern size is decreasing to the um range. Accordingly, a cleaning process during the FPD fabrication process is becoming more important to prevent yield reductions. The purpose of this study is to develop a FPD cleaning system and a cleaning process using a two-phase flow. The FPD cleaning system consists of two parts, one being a cleaning part which includes a two-phase flow nozzle, and the other being a drying part which includes an air-knife and a halogen lamp. To evaluate the particle removal efficiency by means of two-phase flow cleaning, silica particles $1.5{\mu}m$ in size were contaminated onto a six-inch silicon wafer and a four-inch glass wafer. We conducted cleaning processes under various conditions, i.e., DI water and nitrogen gas at different pressures, using a two-phase-flow nozzle with a gap distance between the nozzle and the substrate. The drying efficiency was also tested using the air-knife with a change in the gap distance between the air-knife and the substrate to remove the DI water which remained on the substrate after the two-phase-flow cleaning process. We obtained high efficiency in terms of particle removal as well as good drying efficiency through the optimized conditions of the two-phase-flow cleaning and air-knife processes.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2001년도 춘계학술대회 논문집
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• pp.124-128
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• 2001

Two-dimensional solidification analysis during rheology forming process of semi-solid aluminum ahoy has been studied Two-phase fluid flow model to investigate the velocity field and temperature distribution is proposed. The unposed mathematical model is applied to the die shape of the two type. To calculate the velocities and temperature fields during rheology forming process, the each governing equation correspondent to the liquid and solid region are adapted. Theoretical model on the basis of the two-phase flow model is the mixture rule of solid and liquid phases. This approach is based on the liquid and solid viscosity.

• 한국세라믹학회지
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• 제53권3호
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• pp.288-294
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• 2016

The densification process during liquid-phase sintering was simulated by Monte Carlo simulation. The Potts model, which had been applied to coarsening during liquid-phase sintering, was modified to include vapor particles. The results of two- and threedimensional simulations showed a temporal decrease in porosity, in other words, densification, and an increase in the average size of pores. The results also showed growth of solid grains and the effect of wetting angle on microstructure.

• 한국재료학회지
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• 제13권11호
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• pp.756-760
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• 2003

Two dimensional computer simulations were conducted on percolative structure in which second phases with various short diameter were arranged in matrix phase. In case of prohibiting the overlap among the second phases, the maximum area fraction of second phase arranged in matrix was increased with higher short diameter. In case of allowing the overlap among the second phases, the critical area fraction was increased with higher short diameter and the total number of distributed second phase was decreased. This results represented that thickness variation of short diameter by grain growth on the production processes affect significantly forming the completion path.

• 한국재료학회지
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• 제2권6호
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• pp.389-397
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• 1992

Li의 양과 Al의 양을 달리한 $\alpha$(HCP) 단상 및 $\alpha$(HCP)+${\beta}$ (BCC) 2상 조직인 Mg-Li-Al합금을 시료로 하여 이 합금의 가공성과 시효경화륵성을 조사한 결과 $\alpha$단상보다는 $\alpha$+${\beta}$ 2상 조이,$\alpha$+${\beta}$ 2상조직에서는 Al양이 많을수록 가궁성이 증가하였으며 Mg-8.08Li-4.26Al의 경우 가공한계값은 62%였다. 이와같이 가공성이 증가한 이유는 basal plane뿐만 아니라 pyramidal plane과 prism plane에서도 슬립이 일어났기 때문이다. $\alpha$단상의 경우 MgL$i_2$ Al(${\theta}$)의 석출이 일어나지 않았으나 $\alpha$+${\beta}$ 2상 조직의 곁우 ${\beta}$상 내에서 ${\theta}$의 석출에 의한 피크경도같이 나타났으며, 2상 조직의 경우 경도값은 Al양이 많을수록 증가하였는데 이것은 Al양의 증가에 따른 Al Partition에 의한$\alpha$ 상의 강화와 ${\beta}$상에서의 석출물 증가에 의한 것으로 생각된다.

• 한국주조공학회지
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• 제28권6호
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• pp.261-267
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• 2008

In-situ quasicrystalline icosahedral (I) phase reinforced Ti-based bulk metallic glass (BMG) matrix composites have been successfully fabricated by using two distinct thermal histories for BMG forming alloy. The BMG composite containing micron-scale Iphase has been introduced by controlling cooling rate during solidification, whereas nano-scale I-phase reinforced BMG composite has been produced by partial crystallization of BMG. For mechanical properties, micron-scale I-phase distributed BMG composite exhibited lower strength and plasticity compared to the monolithic BMG. On the other hand, nano-scale icosahedral phase embedded BMG composite showed enhanced strength and plasticity. These improved mechanical properties were attributed to the multiplication of shear bands and blocking of the shear band propagation in terms of isolation and homogeneous distribution of nanosize icosahdral phases in the glassy matrix, followed by stabilizing the mechanical and deformation instabilities.

• Macromolecular Research
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• 제10권1호
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• pp.18-23
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• 2002

We theoretically consider blends of two monodisperse one-end-functionalized homopolymers (denoted by A and B) capable of forming clusters between functional groups (stickers) using weak segregation theory. In this model system resulting molecular architectures via clustering resemble star copolymers having many A- and B-arms. Minimizing the total free energy with respect the cluster distribution, the equilibrium distribution of clusters is obtained and used for RPA (Random Phase Approximation) equations as input. For the case that polymers are functionalized by only one kind of sticker, the phase diagrams show that the associations promote the macrophase separation. When there is strong affinity between stickers belonging to the different polymer species, on the other hand, the phase diagram show a suppression of the macrophase separation at the range of high temperature regime, as well as the phase coexistence between a disordered and a mesoscopic phase at the relatively lower temperatures.