• 대한화학회지
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• 제45권6호
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• pp.507-512
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• 2001

1,2-Bis(4-pyridyl)ethane 존재 하에서, $La(NO_3)_3{\cdot}6H_2O$와 benzene-1,3-dicarboxylic acid($H_2$BDC)가 수열반응하여 〔$La_4$$(BDC)_6$$($H_2$O)_5$〕($H_2$O) (1) 실험식을 갖는 2차원 lanthanum-BDC 배위 고분자가 합성되었다. 화합물의 1의 구조 분석 결과, 이 고분자는 분명히 구별되는 4개의 La금속들을 함유하고 있었다. 3개의 La금속들은 7-배위를 하고 있으며, 이들은 "모자 씌운(capped)"삼각 프리즘, "모자 씌운" 정팔면체, 그리고 오각쌍뿔등의 다른 구조들을 가지고 있다. 나머지 La금속은 8-배위, 사각 반프리즘 (antiprismatic)구조를 가지고 있다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2008년도 추계 학술발표회 제20권2호
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• pp.835-838
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• 2008

이 연구에서는 FRP(fiber reinforced polymer)로 전단보강된 철근콘크리트(RC) 보의 전단거동을 예측하기 위하여 비선형 유한요소해석을 수행한다. FRP로 전단보강된 RC 보의 유한요소해석을 위하여 이 논문에서는 FRP에 대한 모델링 개념을 소개하며, RC 보와 FRP, 그리고 콘크리트와 FRP 사이의부착 특성을 나타낼 수 있는 수치해석기법을 사용한다. 제안된 모델링 기법에 따라, DSFM에 바탕을둔 2차원 비선형 유한요소해석 프로그램인 VecTor2를 이용하여 유한요소해석을 수행한다. 또한 FRP 로 전단보강된 RC 보의 거동에 대한 DSFM의 적용성을 검증하기 위하여 수치해석결과와 실험결과를 상세히 비교한다.

• Macromolecular Research
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• 제17권9호
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• pp.709-713
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• 2009

The aim of this study was to develop novel intestinal specific drug delivery systems with pH sensitive swelling and drug release properties. The carboxyl group of ibuprofen was converted to a vinyl ester group by reacting ibuprofen and vinyl acetate as an acylating agent in the presence of catalyst. The glucose-6-acrylate-1, 2, 3, 4-tetraacetate (GATA) monomer was prepared under mild conditions. Cubane-1, 4-dicarboxylic acid (CDA) linked to two 2-hydroxyethyl methacrylate (HEMA) group was used as the crosslinking agent (CA). Methacrylic-type polymeric prodrugs were synthesized by the free radical copolymerization of methacrylic acid, vinyl ester derivative of ibuprofen (VIP) and GATA in the presence of cubane cross linking agent. The structure of VIP was characterized and confirmed by FTIR, $^1H$ NMR and $^{13}C$ NMR spectroscopy. The composition of the cross-linked three-dimensional polymers was determined by FTIR spectroscopy. The hydrolysis of drug polymer conjugates was carried out in cel-lophane membrane dialysis bags, and the in vitro release profiles were established separately in enzyme-free simulated gastric and intestinal fluids (SGF, pH 1 and SIF, pH 7.4). The detection of a hydrolysis solution by UV spectroscopy at selected intervals showed that the drug can be released by hydrolysis of the ester bond between the drug and polymer backbone at a low rate. Drug release studies showed that increasing the MAA content in the copolymer enhances the rate of hydrolysis in SIP. These results suggest that these polymeric prodrugs can be useful for the release of ibuprofen in controlled release systems.

• 접착 및 계면
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• 제22권4호
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• pp.153-157
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• 2021

이차원 탄소 동소체인 그래핀은 기존 재료보다 우수한 기계적, 전기적 특성을 지니고 있다. 특히, 그래핀의 전하이동도는 실리콘 대비 100배가량 높다고 알려져 차세대 전자소자의 핵심재료로 각광을 받고 있다. 하지만, 그래핀은 외부 환경의 변화에 매우 민감하여 수분 혹은 산소에 취약하여 그래핀 기반 전자소자의 안정성이 취약하다는 단점이 존재하기에 이를 해결하기 위해 다양한 시도가 이뤄지고 있다. 본 연구에서는 그래핀 전계효과 트랜지스터의 절연막을 전사시에 사용되는 고분자 층의 표면 에너지를 조절하여 안정성을 크게 향상시키는 연구를 수행하였다. 절연층으로 쓰인 고분자의 표면 에너지가 낮아짐에 따라 물 분자 혹은 산소와 같은 대기중의 불순물 흡착을 효과적으로 제어함으로써, 안정성을 향상시킬 수 있었다.

• Computers and Concrete
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• 제31권3호
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• pp.173-184
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• 2023

In this study, the flexural behaviors of one- and two-way reinforced concrete (RC) slabs strengthened with carbon-fiber-reinforced polymer (CFRP) strips under impact loads were investigated. The flexural strengthening of RC slabs under simulated static monotonic loads has been comprehensively studied. However, the flexural behavior of RC slabs strengthened with CFRP strips has not been investigated extensively, particularly those conducted numerically. Nonlinear three-dimensional finite element models were developed, executed, and verified against previous experimental results, producing satisfactory models with approximately 4% error. The models were extended to a parametric study, considering three geometric parameters: the slab rectangularity ratio, CFRP strip width, and CFRP strip configuration. Finally, the main results were used to derive a new formula for predicting the total deflection of RC slabs strengthened with CFRP strips under impact loads with an error of approximately 10%. The proposed equation reflected the slab rectangularity, CFRP strip width, equivalent slab stiffness, and dropped weight. Results indicated that the use of CFRP strips enhanced the overall impact performance, the wider the CFRP width, the better the enhancement. Moreover, the application of diagonally oriented CFRP strips diminished the cracking zone compared to straight strips. Additionally, the diagonal orientation of CFRP strips was more efficient for two-way slabs while the vertical orientation was found to be better in the case of one-way slabs.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2004년도 학술대회지
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• pp.780-783
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• 2004

The two-dimensional modeling of the non-stationary thermal state and voltage responsivity of the sensitive elements usually used in solid-state pyroelectric focal plane arrays are presented. Temperature distributions under periodical thermal excitation and the response of the thermal imaging device, which is composed of the pyroelectric sensitive elements mounted on a single silicon substrate, are numerically calculated. The sensitive element consists of a covering metal layer, infrared polymer absorber, front metal contact, sensitive pyroelectric element, the interconnecting column and the bulk silicon readout. The results of the numerical modeling show that the thermal crosstalk between sensitive elements to be critical especially at low frequency (f < 10Hz) of periodically modulated light. It is also shown that the use of our models gives the possibility to improve the design, operating regimes and sensitivity of the device.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.1034-1037
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• 2003

In this work, Integral photography with variable focusing lens arrays is proposed. We fabricate two-dimensional liquid crystal lens arrays using cohesion of UV curable polymer and lithography. Applied voltage to the cell alters the effective refractive index of the liquid crystal layer and results in a change of the focal length. By adjusting the focal length, synchronized elemental image array for real or virtual mode is integrated in front of or behind the lens array.

• Bulletin of the Korean Chemical Society
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• 제32권12호
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• pp.4195-4198
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• 2011

Intramolecular ${\pi}-{\pi}$ and ${\sigma}-{\pi}$ interactions are omnipresent for numerous energetic and structural phenomena in nature, and the exact description of these nonbonding interactions plays an important role in the accurate prediction of the three-dimensional structures for numerous interesting molecular systems such as protein folding and polymer shaping. We have selected two prototype molecular systems for benchmarking calculations of intramolecular ${\pi}-{\pi}$ and ${\sigma}-{\pi}$ interactions. Accurately describing conformational energy of such systems requires highly elaborate but very expensive ab initio methods such as coupled cluster singles, doubles, and (triples) (CCSD(T)). Our calculations reveal a double hybrid density functional incorporating dispersion correction (B2PLYP-D) that agrees excellently with the CCSD(T) results, indicating that B2PLYP-D can serve as a practical method of choice.

• Current Optics and Photonics
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• 제3권6호
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• pp.566-570
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• 2019

To investigate dependence of the sensitivity of THz metamaterials on the position of target dielectric materials, we functionalized the metamaterial gap with an adhesive polymer. A shift in resonance frequency occurs when polystyrene microbeads are deposited in the gap of the metamaterial's metal resonator pattern, while little change is observed when they are deposited on other areas of the metasurface. A two-dimensional mapping of the sensitivity, with a grid size of 1 ㎛, is obtained from a finite-difference time-domain simulation: The frequency shift is displayed as a function of the position of a target dielectric cube. The resulting sensitivity distribution clearly reveals the crucial role of the gap in sensing with metamaterials, which is consistent with the electric field distribution near the gap.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2004년도 추계학술대회논문집
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• pp.284-289
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• 2004

Since polymer materials at elevated temperatures are usually rate-sensitive, the analysis of RTP process requires considering the effect of the rate-dependent. The material behavior that exhibits rate-sensitivity is called visco-plastic. A two-dimensional visco-plastic finite element formulation which constitutive equation is based on the formulation proposed by Perzyna is presented. This Paper is purposed to calcuate pressure distribution on PMMA in compression process and to predict the relationship with defects after demolding process. This paper analyzes, both analytically and numerically, the pressure distributions on the surface of PMMA during open-die RTP process. In this research, PMMA is used to be simulated at $110^{\circ}C$ near the transition temperature.