• Title/Summary/Keyword: two-column

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Temperature Controllable HPLC Column for Preparative Fractionation of Polymers

  • Im, Kyu-Hyun;Park, Hae-Woong;Kim, Young-Tak;Chang, Tai-Hyun
    • Macromolecular Research
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    • v.16 no.6
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    • pp.544-548
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    • 2008
  • An HPLC column with a self-contained temperature control device was constructed for preparative temperature programmed interaction chromatography. Two Peltier plates were attached to a large bore column ($120{\times}22\;mm$ i.d.) and the column temperature was controlled by PID mode feed back control. At a flow rate of 1.5 mL/min, the column temperature could be increased and decreased at a rate as high as $50^{\circ}C/min$ and $10^{\circ}C/min$, respectively, which is much faster than using a column jacket and bath/circulator. The rapid heating and cooling rates allows a high repetition rate of chromatographic fractionation. The performance of the temperature controllable column was demonstrated successfully by the fractionation of homo-polymer precursors from diblock copolymers.

ADINA/FSI Analysis of Petrochemical Plant Column Mixer (화학 플랜트용 칼럼믹서의 ADINA/FSI 해석)

  • Lee, Won-Suk;Jung, Goo-Choong;Choi, Yeon-Sun
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.17 no.3 s.120
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    • pp.213-219
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    • 2007
  • Column mixer Is one of the facilities to mix fluids at petrochemical plants. The vibration of column mixer is usually caused by pumps for fluid inflow and mixing of inside fluids. This fluid induced nitration is mainly responsible for the reduction of column life. Measurements were performed for understanding the vibration characteristics of the column. First measurement results showed the need of stiffness reinforcement. After the reinforcement work, second measurement confirmed the difference between two results. Modal analysis was also performed to investigate the resonance of the column vibration and the damage of the rib plate. To confirm fluid induced vibration at the column mixer fluid structure interaction analysis using ADINA/FSI was performed, which showed the necessity of the modification of the rotary valve.

Evaluation of Seismic Performance for an Internally Confined Hollow CFT Column (내부 구속 중공 CFT 기둥의 내진 성능 평가)

  • Han, Taek Hee;Kim, Sung Nam;Kang, Young Jong
    • Journal of Korean Society of Steel Construction
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    • v.19 no.1
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    • pp.53-65
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    • 2007
  • Column tests were performed for a new type of column, the internally confined hollow concrete filled tube column (ICH CFT column), to evaluate its seismic performance. The seismic performances for two types of ICH CFT columns and a general solid RC column were evaluated and compared by quasi-static tests. The displacements and the lateral loads of column specimens were measured during tests. Ductilities, absorbed energy, equivalent damping ratios, damage indices were calculated from recorded data. From the test results, the ICH CFT column shows superior seismic performances with double moment capacity and larger energy absorbing capacity over that of a solid RC column.

Transformation Characteristics of Chlorinated Aliphatic Hydrocarbon (CAH) Mixtures in a Two-Stage Column: 1st Chemical Column Packed with Zinc Natural Ore and 2nd Biological Column Stimulated with Propane-Oxidizing Microorganisms (아연 광석과 프로판산화 미생물을 이용한 이단 고정상 반응기에서의 염소계 지방족 탄화수소 혼합물 분해 특성)

  • Son, Bong-han;Kim, Nam-hee;Hong, Kwang-pyo;Yun, Jun-ki;Lee, Chae-young;Kwon, Soo-youl;Kim, Young
    • Journal of Korean Society on Water Environment
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    • v.23 no.5
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    • pp.723-730
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    • 2007
  • This study was conducted to develop a combined method for remediating a Chlorinated Aliphatic Hydrocarbons (CAHs) mixtures-contaminated aquifer. The process is consist of two processes. A chemical process (1st) using natural zinc ores for reducing higher concentrations of CAH mixtures to the level at which biological process is feasible; and A biological process (2nd) using aerobic cometabolism for treating lower concentration of CAH mixtures (less than 1 mg/L). Natural zinc ore showed relatively high transformation capacity, average dehalogenation percentage, and the best economic efficiency in previously our study. To evaluate the feasibility of the process, we operated two columns in series (that is, chemical and biological columns). In the first column filled with natural zinc ore and sand, CAH mixtures were effectively transformed with more than 95% efficiency, the efficiency depends on the Empty Bed Contact Time (EBCT) and the mass of zinc ore packed. Scanning Electron Microscope (SEM), X-Ray Diffraction (XRD) analysis were performed to make sure whether natural zinc ore played an key role in the dechlorination of the CAH mixtures. The characteristics of zinc metal surface changed after exposure to CAHs due to oxidation of $Zn^0$ to $Zn^{2+}$. In the biological column injecting propane, DO and effluent of the chemical column, only 1,1,1-TCA was cometabolically transformed. Consequently, the combined process would be effective to remediate an aquifer contaminated with high concentrations of CAH mixtures.

THE RELATION BETWEEN MOLECULE AND VISUAL EXTINCTION IN DARK CLOUDS

  • Minn, Y.K.
    • Journal of The Korean Astronomical Society
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    • v.24 no.2
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    • pp.191-215
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    • 1991
  • We have compared the column densities of $H_2CO$, $^{13}CO$, $C^{18}O$, $^{12}CO$, CS, and $HCO^+$ to the visual extinctions derived from star counts in eight dark clouds, L1317, B1, L1551, L1535, L1544, L134, L134N, and B335. We examined the degree of correlation between molecules and extinctions. The contours of $^{13}CO$, $H_2CO$, and CS distributions show an excellent coincidence with those of the visual extinction. Even though the plots of molecule brightness temperature or column density as a function of the visual extinction show a considerable scatter, a good correlation is found between the two quantities. The turnover of the ratios of $^{13}CO$ and $H_2CO$ column densities to the visual extinction at high extinctions observed in several clouds is not apparent in this work. The ratios seem to maintain constant values within the range of $A_V$ we studied. The slopes of the relations between the molecule column density and extinction, and the threshold values of extinction for detection of molecules are comparable to the other works. The cause of the slope difference is discussed. We derived, for the first time, the relations of CS and $HCO^+$ column densities and the visual extinction. The ratio of CS column density to extinction is at least two orders of magnitude lower than the mean value for $^{13}CO$, but the threshold for detection of CS is comparable to that of $^{13}CO$. The ratio of the $HCO^+$ column density to extinction is one to two orders of magnitude lower than the mean ratio for $H_2CO$.

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A new model for T-shaped combined footings part II: Mathematical model for design

  • Luevanos-Rojas, Arnulfo;Lopez-Chavarria, Sandra;Medina-Elizondo, Manuel
    • Geomechanics and Engineering
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    • v.14 no.1
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    • pp.61-69
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    • 2018
  • The first part shows the optimal contact surface for T-shaped combined footings to obtain the most economical dimensioning on the soil (optimal area). This paper presents the second part of a new model for T-shaped combined footings, this part shows a the mathematical model for design of such foundations subject to axial load and moments in two directions to each column considering the soil real pressure acting on the contact surface of the footing with one or two property lines restricted, the pressure is presented in terms of an axial load, moment around the axis "X" and moment around the axis "Y" to each column, and the methodology is developed using the principle that the derived of the moment is the shear force. The classic model considers an axial load and a moment around the axis "X" (transverse axis) applied to each column, i.e., the resultant force from the applied loads is located on the axis "Y" (longitudinal axis), and its position must match with the geometric center of the footing, and when the axial load and moments in two directions are presented, the maximum pressure and uniform applied throughout the contact surface of the footing is considered the same. To illustrate the validity of the new model, a numerical example is presented to obtain the design for T-shaped combined footings subjected to an axial load and moments in two directions applied to each column. The mathematical approach suggested in this paper produces results that have a tangible accuracy for all problems.

Development of a Novel Bioreactor System for the Treatment of Gaseous Benzene

  • Yeom, Sung-Ho;Daugulis, Andrew J.;Yoo, Young-Je
    • 한국생물공학회:학술대회논문집
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    • 2000.11a
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    • pp.73-76
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    • 2000
  • A novel, continuous bioreactor system combining a bubble column (absorption section) and a two-phase bioreactor (degradation section) has been designed to treat a gas stream containing benzene. The bubble column contained hexadecane as an absorbent for benzene, and was systemically chosen considering physical, biological, environmental, operational and economic factors. This solvent has infinite solubility for benzene and very low volatility. After absorbing benzene in the bubble column, the hexadecane served as the organic phase of the two-phase partitioning bioreactor, transferring benzene into the aqueous phase where it was degraded by Alcaligenes xylosoxidans Y234. The hexadecane was then continuously recirculated back to the absorber section for the removal of additional benzene. All mass transfer and biodegradation characteristics in this system were investigated prior to operation of the integrated unit, and these included: the mass transfer rate of benzene in the absorption column, the mass transfer rate of benzene from the organic phase into the aqueous phase in the two-phase bioreactor, the stripping rate of benzene out of the two-phase bioreactor, etc. All of these parameters were incorporated into model equations, which were used to investigate the effects of operating conditions on the performance of the system. Several experiments were conducted to show the feasibility of this system. This process is believed to be very practical for the treatment of high concentrations of gaseous pollutants.

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Seismic repair of exterior R/C beam-to-column joints using two-sided and three-sided jackets

  • Tsonos, Alexander G.
    • Structural Engineering and Mechanics
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    • v.13 no.1
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    • pp.17-34
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    • 2002
  • The use of local two-sided and three-sided jacketing for the repair and strengthening of reinforced concrete beam-column joints damaged by severe earthquakes is investigated experimentally and analytically. Two exterior beam-column joint specimens ($O_1$ and $O_2$) were submitted to a series of cyclic lateral loads to simulate severe earthquake damage. The specimens were typical of existing older structures built in the 1960s and 1970s. The specimens were then repaired and strengthened by local two-sided or three-sided jacketing according to UNIDO Manual guidelines. The strengthened specimens ($RO_1$ and $RO_2$) were then subjected to the same displacement history as that imposed on the original specimens. The repaired and strengthened specimens exhibited significantly higher strength, stiffness and better energy dissipation capacity than the original specimens.

Seismic Performance of Beam-to-Column Joints with Wedge Connectors (쐐기형 강재 접합장치를 사용한 보-기둥 접합부의 내진성능)

  • Park, Jong Won;Kang, Seoung Min;Hwang, In Kyu
    • Journal of Korean Society of Steel Construction
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    • v.19 no.6
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    • pp.655-661
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    • 2007
  • A new steel connection method using wedges known as Self-Locking Connector has been developed. In this study, experimental investigation was conducted to verify the seismic performance of steel beam-to-column joints with Self-Locking Connectors. Cyclic-loading tests were performed on two beam-to-column joints with Self-Locking Connectors. The two beam-to-column joint specimens were of the cantilever-type and had the same details. Test results showed that beam-to-column joints with Self-Locking Connectors were able to developa total rotation capacity of 0.06 radian, which is greater than the 0.04 radian required for Special Moment Frames. Moreover, their energy absorption capacity was much greater than that of conventional joints.

Confinement of Columns using Headed Bars (Headed Bars를 활용한 기둥의 구속효과에 대한 연구)

  • 김영훈;윤영수;데니스미첼
    • Proceedings of the Korea Concrete Institute Conference
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    • 2002.05a
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    • pp.929-934
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    • 2002
  • Eight full-scale columns were constructed and tested under monotonic axial compression loading to investigate the influence of headed bars on the confinement of the concrete. One column represented a column with no transverse reinforcement and another column had poor detailing and little confinement. A third column contained seismic hoops and crossties, which represented current detailing practice for significant confinement. A fourth column test is conducted to investigate the response with the seismic crossties replaced by headed bars. Two column specimens were constructed and tested with all of the transverse reinforcement provided by headed bars. These six specimens enabled an assesment of the effectiveness of headed bars in confining the concrete. It was found that the use of headed bars improved the confinement of the columns. Two additional specimens were constructed without any transverse reinforcement. These columns were later retrofitted, by drilling horizontal holes in the columns, adding special headed bars (one head fixed and the other head threaded) and then filling the drilled holes with epoxy. These retrofitted specimens with these added headed bars provided insight into the rehabilitation of older structures containing poorly detailed columns. All of the test specimens were instrumented to determine strain localization during failure and to monitor the strain in the longitudinal and transverse reinforcement.

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