• Title/Summary/Keyword: triethanolamine(TEA)

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Preparation of PZT Fibers Using Triethanolamine Complexed Sol (Triethanolamine 착체졸을 이용한 PZT 섬유의 제조)

  • 박용일;이해욱;최용수;이종혁;김승현;김창은
    • Journal of the Korean Ceramic Society
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    • v.33 no.7
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    • pp.755-760
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    • 1996
  • Sol-gel processing was used to prepare PZT fibers. Titanium isopropoxide Zirconium n-butoxide and lead acetate trihydrate were used as starting materials and TEA(triethanolamine) was added to form stabilized Pb-Ti-Zr complex alkoxide, Effects of catalysts and various solvents on the state of precursor sol gelation reaction fiber spinnability pyrolysis and crystallization were also investiated.

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Stability and Characterization of Triethanolamine Type Cation Surfactants (트리에탄올아민형 양이온 계면활성제의 안정성 및 특성 연구)

  • Kim, Byeong-Jo;Kim, Hyeong-Gyu;Lee, Jong-Ki;Moon, Surk-Sik
    • Applied Chemistry for Engineering
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    • v.20 no.2
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    • pp.140-144
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    • 2009
  • Triethanolamine-type cationic surfactants were synthesized and their applications were established. The production of mono-, di-, and tri-TEA-EQ (triethanol-amine-esterquater) were dependent on the molar ratio of fatty acid and triethanolamine under the controlled reaction temperature. The structures were elucidated by $H^{1}$ NMR. Long-term stability was dependent on the amount of mono- and tri-TEA-EQ. When the amount of mono-TEA-EQ was increased, long-term stability was increased. However, the more tri-TEA-EQ made long-term stability decreased. Softening was dependent on the amount of saturated fatty acid, and re-wettability was counted on the amount of unsaturated fatty acid. Softening was measured by the method of sense estimation e.g. touching to home-towel. Absorption was determined to calculate the height of water on a towel after treatment.

A Study on the Electrochemical Characterization of Stainless Steel in Triethanolamine Solution (트리에탄올아민용액에서 스테인리스강의 전기 화학적 특성)

  • Park, Jin-Hyeog;Lee, Jong-Ho;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.275-280
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    • 2015
  • In this study, the current-voltage curves for stainless steel in the triethanolamine(TEA) solution was measured using the conventional three electrodes of cyclic voltammetry. Stainless steel as working electrode, Ag/AgCl electrode as reference electrode and Pt wire as counter electrode were used respectively. As a result, the C-V characteristics of stainless steel were to be for an irreversible process due to the oxidation current from cyclic voltammogram, using triethanolamine solutions. Effective diffusivity of corrosion inhibitors was decreased with increasing concentration. And the concentration of 0.5 N $NaClO_4$, $2.5{\times}10^{-3}M$ TEA solution when the corrosion inhibition effect is most great, and 1.5 N $NaClO_4$, $1.0{\times}10^{-3}M$ TEA solution, the lowest corrosion inhibition effect.

Formaldehyde-Free Durable Flame-Retardant Finish of Cotton Using Hexachlorocyclophosphazene and Triethanolamine (Hexachlorocyclophosphazene과 Triethanolamine을 이용한 면섬유의 포름알데히드-프리 내구성 방염가공)

  • Kim, Jeong-Hwan;Jang, Jinho
    • Textile Coloration and Finishing
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    • v.32 no.3
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    • pp.150-157
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    • 2020
  • Hexachloro-cyclophosphazene(HCCP), a formaldehyde-free flame retardant (FR), was steam-cured with triethanol amine(TEA) to impart durable flame-retardancy to cotton fabrics. While the HCCP treatment alone showed very limited resistance to repeated laundering cycles, the addition of TEA substantially improved the laundering durability of the FR cotton up to twenty laundering cycles. The extended washing resistance was accomplished by the increased nucleophilic substitution of unreacted P-Cl groups in HCCP by the TEA resulting in the more densely crosslinked FR networks. With increasing molar ratio of TEA to the HCCP up to 2, the flame retarding effectivity and the synergistic effectiveness improved to 2.8 and 1.8 respectively. TGA and microscale combustion calorimetry verified the pyrolysis and combustion behaviors of the FR-cotton, which showed lower maximum pyrolysis and combustion temperatures together with substantially decreased peak pyrolysis and heat release rate, synergistically yielding larger amounts of carbonaceous chars. The formaldehyde-free HCCP and TEA can be a durable FR finishing agents for cotton fabrics acting through a solid-phase flame-retarding mechanism.

Effect of TEA on Acceleration Shotcrete (숏크리트용 급결제에 미치는 트리에탄올아민의 영향)

  • Chun, Yong-Jin;Cho, Suk-Hyeong;Hong, Young-Ho;Lee, Gun-Jik
    • Applied Chemistry for Engineering
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    • v.10 no.8
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    • pp.1124-1128
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    • 1999
  • In this study the effect of organic additive, triethanolamine(TEA), and temperature change of accelerator for shotcrete was studied. Then the amount of accelerator, temperature and W/C were experimentally investigated. Effects of hydration time and hydration heat of concrete on organic additive amount were analysed by DSC, SEM and XRD. We found that the hydration heat was increased and hydration time was decreased with TEA(<5 wt %). The order of hydration rate of potassium accelerator was PA < PC-3 < PC-5 < PC-8.

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Problem-solving approach for salbutamol analysis by HPLC during pharmaceutical assay

  • Gholizadeh-Hashjin, Aiesheh;Hamishehkar, Hamed;Monajjemzadeh, Farnaz
    • Analytical Science and Technology
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    • v.35 no.5
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    • pp.189-196
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    • 2022
  • When cationic basic compounds are chromatographed using hydro-organic mobile phase, the presence of anionic free silanols in the silica-based stationary phases results in broad and asymmetrical peaks. The addition of an ionic reagent to the mobile phase prevents analytes from accessing free silanols, improving peak shape. In this study, the chromatographic behavior of salbutamol sulfate as a basic compound was investigated under various conditions, including the use of different columns, mobile phases, and ion-pair reagents such as triethanolamine (TEA) and sodium heptane sulfonate (SHS). The retention and peak shape of chromatograms were both evaluated. The results show that pre-conditioning the column with TEA and including it in the mobile phase can prevent cationic analytes from accessing anionic silanols, resulting in improved peak shape. Furthermore, buffering the mobile phase is an important factor in keeping the pH constant throughout the process. The chosen method was validated in part. This study could be helpful for researchers and analyst to solve such problems with cationic basic components.

Analysis on Chemical Ingredients with Anti-microbial Activity in Water-based Metalworking Fluids

  • Park, Dong-Uk;Kim, Bok-Hwan;Lee, Kwon-Sup
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.06a
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    • pp.217-222
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    • 2004
  • This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) ‘A’ can cause anti-microbial activity and health effect. Three water-based MWF products (‘A’, ‘B’, and ‘C’) were studied every week for two months. Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF ‘A’ was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF ‘A’ were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF ‘A’ are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically. To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

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Analysis on Chemical Ingredients with Anti-microbial Activity in Water-based Metalworking Fluids

  • Park, Donguk;Lee, Jonghang;Lee, Kwonsup
    • KSTLE International Journal
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    • v.4 no.2
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    • pp.52-55
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    • 2003
  • This study was conducted to estimate if the level of several chemical ingredients including alkanolamines or ethanolamines (EA) examined in the specific synthetic metalworking fluid (MWF) "A" can cause anti-microbial activity and health effect. Three water-based MWF products ("A", "B", and "C") were studied every week for two months (from June 1, 2002 to July 30, 2002). Chemical ingredients such as formaldehyde, boron, EA, and copper were examined. In the sump where MWF "A" was used, not only the total level of EA, monoethanolamine(MEA), diethanolamine(DEA) and triethanolamine(TEA), but also boron level were significantly higher than those of the other MWFs. ANOVA statistical tests indicated that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF "A" were significantly higher than those in other MWF types. Correlation tests also found that levels of pH, alkalinity, boron, MEA, DEA and TEA in MWF "A" are significantly correlated. We suggested the assumptions that excessive concentrations of EA, and borate at a high pH level, may cause anti-microbial resistance synergically. To demonstrate this assumption, additional study is needed to examine the relationship between the levels of microbes and excessive concentrations of EA, and borate at a high pH level.

Chemical Absorption of Carbon Dioxide into Non-Newtonian Polyacrylamide Solution (Polyacrylamide 비뉴튼액체에서의 이산화탄소의 화학흡수)

  • Hwang, Byung-Jin;Park, Sang-Wook
    • Clean Technology
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    • v.14 no.4
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    • pp.281-286
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    • 2008
  • Absorption rate of carbon dioxide was measured in the aqueous polyacrylamide (PAA) solution containing triethanolamine (TEA) of $0{\sim}2.0\;kg\;mol/m^3$ in a flat-stirred vessel with an impeller of 0.05 m and agitation speed of 50 rpm at $25^{\circ}C$ and 101.3 kPa. The chemical absorption rate of $CO_2$ was estimated by mass transfer mechanism based on the film theory using the physicochemical properties containing the liquid-side mass transfer coefficient of $CO_2$ and the kinetics of reaction between $CO_2$ and TEA to compare with the measured rate. The aqueous PAA solution acted as a reducing agent by viscoelastic property of non-Newtonian liquid based on the same viscosity of the solution.

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A Study on the Inhibiting Corrosion of Triethanolamine for the SCM440 Steel (CM440 강에 대한 트리에탄올아민의 부식억제에 관한 연구)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.56-61
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    • 2015
  • In this study, the current-voltage curves for the SCM440 steel by the addition of an organic corrosion inhibitor triethanolamine(TEA) was measured using the conventional three electrodes of cyclic voltammetry. As a result, the C-V characteristics of SCM440 steel were to be for an irreversible process due to the oxidation current from the cyclic voltammetry. Diffusion coefficient according to the twice increasing the concentration of TEA in the corrosion inhibitor from $2.5{\times}10^{-4}M$ to $5.0{\times}10^{-4}M$, the diffusion coefficient was found to be a good corrosion-inhibiting effect is reduced by 1.5 times, so for each $2.561{\times}10^{-6}cm^2s^{-1}$ to $1.707{\times}10^{-6}cm^2s^{-1}$. When according to the electrolyte concentration and the effect is to increase the electrolyte concentration to 1.0 N at 0.5 N, the diffusion coefficient is $2.56{\times}10^{-6}cm^2s^{-1}$ to $5.12{\times}10^{-6}cm^2s^{-1}$, each 2 times decrease in the use of the electrolyte of 1.0 N, because this was more appropriate.