• Applied Chemistry for Engineering
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• v.25 no.2
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• pp.147-151
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• 2014

In many polymer processing operations, the diffusion of small molecules in polymeric materials plays an important role. The fundamental physical property required to design and optimize processing operations is the mutual diffusion coefficient. To investigate the transport properties of polymer/solvent systems at infinite dilution, capillary column inverse gas chromatography (CCIGC) is often employed. In this study, diffusion and partition coefficients of cyclic solvents in styrene/butadiene/styrene (SBS) block copolymer were measured over a wide temperature range using the CCIGC technique.

• Nuclear Engineering and Technology
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• v.47 no.1
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• pp.85-93
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• 2015

Background: $^{241}Am$, $^{243}Am$, and $^{237}Np$ isotopes are among the most radiotoxic components of spent nuclear fuel. Recently, researchers have planned different incineration scenarios for the highly radiotoxic elements of nuclear waste in critical reactors. Computational methods are widely used to predict burnup rates of such nuclear wastes that are used under fuel matrixes in critical reactors. Methods: In this work, the Monte Carlo N-particle transport code was used to calculate the neutronic behavior of a transuranic (TRU)-bearing CANada Deuterium Uranium 6 reactor. Results: The computational data showed that the 1.0% TRU-containing thorium-based fuel matrix presents higher proliferation resistance and TRU depletion rate than the other investigated fuel Matrixes. The fuel matrix includes higher negative temperature reactivity coefficients as well. Conclusion: The investigated thorium-based fuel matrix can be successfully used to decrease the production of highly radiotoxic isotopes.

• Environmental Engineering Research
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• v.25 no.3
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• pp.281-289
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• 2020

Environmental fate of ionizable organic pollutants such as perfluoroalkyl acids (PFAAs) are of increasing interest but has not been well understood because of uncertain values for parameters related with atmospheric interphase partitioning behavior. In the present study, not only the values for air-water partition coefficient (K_AW) and dissociation constant (pKa) of PFAAs were induced by adjusting to in situ measurements of air-water distribution coefficient between vapor phase and rainwater but also gas-particle partition coefficients were also estimated using three-phase partitioning model of ionizable organic pollutants, in situ measurements of PFAAs in aerosol and air vapor phase, and obtained parameter values. The pKa values of PFAAs we obtained were close to the minimum values suggested in literature except for perfluorooctane sulfonic acids, and COSMOtherm-modeled K_AW values were assessed to more appropriate among suggested values. When applying parameter values we obtained, it was predicted that air particle-associated fate and transport of PFAAs could be negligible and PFAAs could distribute ubiquitously along the transection from urban to rural region by pH-dependent phase transfer in air. Our study is expected to have some implications in prediction of the environmental redistribution of other ionizable organic compounds.

• Journal of Environmental Science International
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• v.16 no.10
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• pp.1147-1155
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• 2007

The applicability of in situ biobarrier or microbial filter technology for the remediation of groundwater contaminated with chlorinated solvent was investigated through column study. In this study, the effect of packing materials on the reductive dechlorination of PCE was investigated using Canadian peat, Pahokee peat, peat moss and vermicompost (or worm casting) as a biobarrier medium. Optimal conditions previously determined from a batch microcosm study was applied in this column study. Lactate/benzoate was amended as electron donors to stimulate reductive dechlorination of PCE. Hydraulic conductivity was approximately $6{\times}10^{-5}-8{\times}10^{-5}\;cm/sec$ and no difference was found among the packing materials. The transport and dispersion coefficients determined from the curve-fitting of the breakthrough curves of $Br^-$ using CXTFIT 2.1 showed no difference between single-region and two-region models. The reductive dechlorination of PCE was efficiently occurred in all columns. Among the columns, especially the column packed with vermicompost exhibited the highest reductive dechlorination efficiency. The results of this study showed the promising potential of in situ biobarrier technology using peat and vermicompost for the remediation of groundwater contaminated with chlorinated solvents.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.64 no.4
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• pp.560-566
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• 2015

The self-consistent simulation based on the drift-diffusion approximation with anisotropic transport coefficients was performed. The RHCP-wave propagation was observed in MICP and this wave was refracted toward the high-density region. The calculated impedance seen from the antenna terminal shows that resistance component of MICP is a higher than that of ordinary ICP. Because of a higher resistance, the power transfer efficiency was improved to 95%. This property is practically important for large-size, low-pressure plasma sources because high resistance corresponds to high power-transfer efficiency and stable impedance matching characteristics.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.7
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• pp.879-886
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• 2004

A numerical optimization has been carried out to determine the shape of the three-dimensional channel with oblique ribs attached on both walls to enhance turbulent heat transfer. The response surface based optimization is used as an optimization technique with Reynolds-averaged Navier-Stokes analysis of fluid flow and heat transfer. Shear stress transport (SST) turbulence model is used as a turbulence closure. Numerical results fur heat transfer rate show good agreements with experimental data. four dimensionless variables such as, rib pitch-to-rib height ratio, rib height-to-channel height ratio, streamwise rib distance on opposite wall to rib pitch ratio, and the attack angle of the rib are chosen as design variables. The objective function is defined as a linear combination of heat-transfer and friction-loss related coefficients with a weighting factor. D-optimal method is used to determine the training points as a means of design of experiment. Sensitivity of the objective parameters to each design variable has been analyzed. And, optimal values of the design variables have been obtained in a range of the weighting factor.

• Proceedings of the SAREK Conference
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• 2008.11a
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• pp.630-635
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• 2008

A dynamic model has been developed to investigate the operability of a single and double-effect solar energy assisted parallel type absorption chiller. In the study, main components and fluid transport mechanism have been modeled. Flow discharge coefficients of the valves and the pumps were optimized for the double-effect mode with solar-heated water circulated. The model was run for the single mode with solar energy supply only and the solar/gas driving double effect mode. And the cases of the double mode with and without the solar energy were compared. From the simulation results, it was found that the present configuration of the chiller is not capable of regulating solution flow rates according to variable solar energy input. And the single mode utilizing the solar energy only is not practical. It is suggested to operate the system in the double mode and the flow rate control system adaptive to variable solar energy input has to be developed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1998.04a
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• pp.13-13
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• 1998

A simple model of the tip leakage flow models of the rotor downstream flow is developed, based on Lakshminarayana's theoretical concept on the tip clearance flow and the experimental data published in open literature. And new spanwise distribution models of deviation angle and pressure loss coefficient due to the tip leakage flow are formulated for use in association with the streamline curvature method as a through flow analysis. Combining these new models and previous deviation and loss models due to secondary flow, a robust streamline curvature method is established for flow analysis of single-stage, subsonic axial turbines with wide ranges of turning angle, aspect ratio and blading type. At the exit from rotor rows, the flow variables are mixed radially according to a spanwise transport equation. The proposed streamline curvature method is tested against a forced vortex type turbine as well as a free vortex type one. The results show that the spanwise variations of flow angle, axial velocity and loss coefficients at rotor exit are predicted with good accuracy, being comparable to a steady three-dimensional Navier-Stokes analysis. This simple and fast flow analysis is found to be very useful for the turbine design at the initial design phase.

• Nuclear Engineering and Technology
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• v.25 no.1
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• pp.102-109
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• 1993

A PC-computer program RADAP has been developed in this study to perform a quick real-time analysis of dose assessment following an accident in a nuclear facility. RADAP uses an interactive LKagrangian puff model in simulating the transport and diffusion of radioactive plume in the atmosphere. For real-time analysis, RADAP treats one or multiple puffs of ground-level releases, simultaneously. It is assumed to maintain a Gaussian distribution within the puff and the diffusion coefficients are computed using the USNRC's normal sigma curve method. The program, however, does not consider the spatial variations but the temporal variations in wind conditions. Whole body and thyroid doses for 3$\times$31 grid are directed to output files, and they are also displayed through computer graphics on VGA or EGA color monitor. The results show that RADAP can be an excellent tool for quick estimation of accidental doses.

• Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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• 2004.05a
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• pp.281-284
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• 2004

Mean energy of electrons in $SF_6-Ar$ Mixtures Gas used by MCS-BEq algorithm has been analysed over the E/N range $30{\sim}300[Td]$ by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6-Ar$, 0.1[%] and 5.0[%], $SF_6-Ar$ mixtures were measured by time-of-flight(TOF) method. The transport Coefficients for electrons in (100[%])$SF_6$. (100[%])Ar, (0.2[%])$SF_6-Ar$ and (0.5[%]) $SF_6-Ar$, (5.0[%]) $SF_6-Ar$, (0.1[%])$SF_6-Ar$ mixtures were measured by time-of-flight method, and the electron energy distribution function and the parameters of the velocity and the diffusion were determined by the variation of the collision cross-sections with energy. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.