• Title/Summary/Keyword: transparent composite

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Structures and Electro-optical Properties of Liquid Crystal-Polymer Composite Films (액정-고분자 복합막의 구조와 전기광학특성)

  • 남수용
    • Journal of the Korean Graphic Arts Communication Society
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    • v.13 no.2
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    • pp.19-32
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    • 1995
  • Liquid crystal-polymer composite(LCPC) films are promising new materials for both projection displays and vision products. LCPC films consist of a continuous liquid crystal phase embedded in a three- dimensional network of polymer matrix. The liquid crystal in these LC phases can be electrically switched giving rise to an opaque scattering off-state and a transparent, non- scattering on-state. In this work, a premixture is composed of LC, UV-curable monomer and photonitiator. LCPC films are formed by photopolymerization induced phase separation from this premixture. In conclusion, structure and electro-optical properties of LCPC films strongly depends on the selection of monomer, LC content and curing rate.

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In-situ Crack Propagation Observation of a Particle Reinforced Polymer Composite Using the Double Cleavage Drilled Compression Specimens

  • Lee Yeon-Soo;Yoon Young-Ki;Jeong Bo-Young;Yoon Hi-Seak
    • Journal of Mechanical Science and Technology
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    • v.20 no.3
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    • pp.310-318
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    • 2006
  • In this study, we investigate the feasibility of in-situ crack propagation by using a double cleavage drilled compression (DCDC) specimen showing a slow crack velocity down to 0.03 mm/s under 0.01 mm/s of displacement control. Finite element analysis predicted that the DCDC specimens would show at least 4.3 fold delayed crack initiation time than conventional tensile fracture specimens under a constant loading speed. Using DCDC specimens, we were able to observe the in-situ crack propagation process in a particle reinforced transparent polymer composite. Our results confirmed that the DCDC specimen would be a good candidate for the in-situ observation of the behavior of particle reinforced composites with slow crack velocity, such as the self-healing process of micro-particle reinforced composites.

Thin composite film passivation through RF sputtering method For Large-sized Organic Display Devices

  • Lee, Joo-Won;Kim, Young-Min;Park, Jung-Soo;Bea, Sung-Jin;Kim, Na-Rae;Kim, Jai-Kyeong;Jang, Jin;Ju, Byeong-Kwon
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1480-1483
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    • 2005
  • Transparent thin composite films (TCFs) were deposited on OLED devices by means of RF sputtering method and their passivation-properties were evaluated by comparing to the e-beam evaporating method. This composite film formed by mixed ratio of MgO (3wt %): $SiO_2$ (1wt %) was developed from pallet as a source of e-beam evaporator to 6-inch size target for sputtering in order to apply for large-sized organic display devices. Water Vapor Transmission Rates (WVTR) of the deposited films were measured as a function of thickness to assess the effectiveness of this film as a passivation layer and it applied to real devices. From this study, we can confirm that the passivation layer formed by TCFs using RF sputtering method sufficiently shows the potentiality of application to passivation layer for organic display devices.

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Study on the Development of Photoelastic Experiment of Orthotropic Material (I) (직교 이방성의 광탄성 실험법 개발에 관한 연구 I)

  • 최선호;황재석
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.12 no.1
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    • pp.8-18
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    • 1988
  • In the composite structures or the concrete structures, to analyze stress concentration factor, stress distributions and fracture mechanics of them under forces by photoelastic experiment, it is natural that to develope photoelastic model material for them is surely necessary. Thus, the orthotropic photoelastic model material for the transparent type photoelastic device was developed in the paper, it is called Copper Fiber Epoxy Composite and abbreviated as E.F.E.C. It was found that C.F.E.C. developed in this paper was satisfied with the properties of photoelastic model material that the photoelastic model material should have and that C.F.E.C. had completely properties of composite material. It is thought that C.F.E.C. can be applied to both medical engineering for modeling biological tissue and to the aerospace industry as orthotropic photoelastic material.

Solution-Processed Anti Reflective Transparent Conducting Electrode for Cu(In,Ga)Se2 Thin Film Solar Cells (CIGS 박막태양전지를 위한 반사방지특성을 가진 용액공정 투명전극)

  • Park, Sewoong;Park, Taejun;Lee, Sangyeob;Chung, Choong-Heui
    • Korean Journal of Materials Research
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    • v.30 no.3
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    • pp.131-135
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    • 2020
  • Silver nanowire (AgNW) networks have been adopted as a front electrode in Cu(In,Ga)Se2 (CIGS) thin film solar cells due to their low cost and compatibility with the solution process. When an AgNW network is applied to a CIGS thin film solar cell, reflection loss can increase because the CdS layer, with a relatively high refractive index (n ~ 2.5 at 550 nm), is exposed to air. To resolve the issue, we apply solution-processed ZnO nanorods to the AgNW network as an anti-reflective coating. To obtain high performance of the optical and electrical properties of the ZnO nanorod and AgNW network composite, we optimize the process parameters - the spin coating of AgNWs and the concentration of zinc nitrate and hexamethylene tetramine (HMT - to fabricate ZnO nanorods. We verify that 10 mM of zinc nitrate and HMT show the lowest reflectance and 10% cell efficiency increase when applied to CIGS thin film solar cells.

Electrical Property of Electrospun PCL/MWCNTs Nanofiber with Additive Silver Thin Film (은 박막이 첨가된 전기방사법으로 제작한 PCL/MWCNTs 나노섬유의 전기적 특성)

  • Kim, Jin Un;Kim, Kyong Min;Park, Kyoung Wan;Sok, Jung Hyun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.31 no.4
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    • pp.238-243
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    • 2018
  • A nanofiber was fabricated with carbon nanotubes for transparent electrodes. It was prepared with a composite solution of bio-molecules polycaprolactone (PCL) and multiwalled carbon nanotubes (MWCNTs) by electrospinning on a glass substrate, following which its electrical characteristics were investigated. The content of MWCNTs was varied during electrospinning, while that of PCL was fixed. Further, a nanometer-thick thin film of silver was deposited on the nanofiber layer using a thermal evaporator to improve the electrical characteristics; the sheet resistance significantly reduced after this deposition. The results showed that this carbon nanotube nanofiber has potential applications in biotechnology and as a flexible transparent display material.

Synthesis of Core-shell Copper nanowire with Reducible Copper Lactate Shell and its Application

  • Hwnag, Hyewon;Kim, Areum;Zhong, Zhaoyang;Kwon, Hyeokchan;Moon, Jooho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.430.1-430.1
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    • 2016
  • We present the concept of reducible fugitive material that conformally surrounds core Cu nanowire (NW) to fabricate transparent conducting electrode (TCE). Reducing atmosphere can corrodes/erodes the underlying/surrounding layers and might cause undesirable reactions such impurity doing and contamination, so that hydrogen-/forming gas based annealing is impractical to make device. In this regards, we introduce novel reducible shell conformally surrounding indivial CuNW to provide a protection against the oxidation when exposed to both air and solvent. Uniform copper lactate shell formation is readily achievable by injecting lactic acid to the CuNW dispersion as the acid reacts with the surface oxide/hydroxide or pure copper. Cu lactate shell prevents the core CuNW from the oxidation during the storage and/or film formation, so that the core-shell CuNW maintains without signficant oxidation for long time. Upon simple thermal annealing under vacuum or in nitrogen atmosphere, the Cu lactate shell is easily decomposed to pure Cu, providing an effective way to produce pure CuNW network TCE with typically sheet resistance of $19.8{\Omega}/sq$ and optical transmittance of 85.5% at 550 nm. Our reducible copper lactate core-shell Cu nanowires have the great advantage in fabrication of device such as composite transparent electrodes or solar cells.

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Transparent Conductive Films Composite with Copper Nanoparticle/Graphene Oxide Fabricated by dip Process and Electrospinning

  • Kim, Jin-Un;Kim, Gyeong-Min;Kim, Yong-Ho;Kim, Su-Yong;Jo, Su-Ji;Lee, Eung-Sang;Seok, Jung-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.382.2-382.2
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    • 2014
  • We explain a method to fabricate multi-layered transparent conductive films (TCF) using graphene oxide (GO), copper powder and polyurethane (PU) solution. The flexible graphene nanosheets (GNSs) serve as nanoscale connection between conductive copper nanoparticles (CuNps) and PU nanofibers, resulting in a highly flexible TCF. To fabricate conductive films with high transmittance, polyurethane (PU) nanofibers were used for a conductive network consisting of CuNps and GNSs (CuNps-GNSs). In this experiment, copper powder and graphene oxides were mixed in deionized water with the ultrasonication for 2 h. NaBH4 solution is used as a reduction agents of CuNps and GNSs (CuNps-GNSs) under a nitrogen atmosphere in the oil bath at 100% for 24 h to mixed. The purified and dispersed CuNp-GNS were obtained in deionized water, and diluted to a 10wt.% based on the contents of GNSs. Polyurethane (PU) nanofibers on a PET substrate were formed by electrospinning method. PET slides coated with the PU nanofibers were immersed into CuNp-GNS solution for several second, rinsed briefly in deionized water, and dried to obtain self-assembled CuNp-GNS/PU films. The morphology of the multi-layered films were characterized with a field emission scanning electron microscope (FE-SEM, Hitachi S-4700) and atomic force microscope (AFM, PSIA XE-100). The electrical property was analysed by the I-V measurement system and the optical property was measured by the UV/VIS spectroscopy.

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Optical, Mechanical and Tribological Properties of Boronnitride Dispersed Silicon Nitride Ceramics

  • Joshi, Bhupendra;Fu, Zhengyi;Niihara, Koichi;Lee, Soo-Wohn
    • Korean Journal of Materials Research
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    • v.20 no.8
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    • pp.444-449
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    • 2010
  • Transparent ceramics are used in new technology because of their excellent mechanical properties over glasses. Transparent ceramics are nowadays widely used in armor, laser windows, and in high temperature applications. Silicon nitride ceramics have excellent mechanical properties and if transparent silicon nitride is fabricated, it can be widely used. h-BN has a lubricating property and is ductile. Therefore, adding h-BN to silicon nitride ceramics gives a lubricating property and is also machinable. Translucent silicon nitride was fabricated by hot-press sintering (HPS) and 57% transmittance was observed in the near infrared region. A higher wt. % of h-BN in silicon nitride ceramics does not favor transparency. The optical, mechanical, and tribological properties of BN dispersed polycrystalline $Si_3N_4$ ceramics were affected by the density, ${\alpha}:{\beta}$-phase ratio, and content of h-BN in sintered ceramics. The hot pressed samples were prepared from the mixture of $\alpha-Si_3N_4$, AlN, MgO, and h-BN at $1850^{\circ}C$. The composite contained from 0.25 to 2 wt. % BN powder with sintering aids (9% AlN + 3% MgO). A maximum transmittance of 57% was achieved for the 0.25 wt. % BN doped $Si_3N_4$ ceramics. Fracture toughness increased and wear volume and the friction coefficient decreased with an increase in BN content. The properties such as transmittance, density, hardness, and flexural strength decreased with an increase in content of h-BN in silicon nitride ceramics.

Development of harmful ultraviolet blocking transparent flexible device using TiO2-x thin film process (TiO2-x 산화물 박막공정을 이용한 유해자외선차단 투명유연소재개발)

  • Kim, Geug Tae
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.3
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    • pp.123-131
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    • 2019
  • In this study, the development of transparent UV blocking material using $TiO_{2-x}$ oxide thin film process was developed. A process technology is related to a process technology for making a sample with ultraviolet-shielding property of visible light transmittance of 78 % or more (total light transmittance at 550 nm) and of a UV cut-off characteristic of more than 95 % at 315 nm in ultraviolet wavelength band. In this study, it is possible to establish a flexible device process condition of high performance ultraviolet (UV) shielding thin film, to design mixed type of transparent flexible device with heterogeneous characteristics and to formulate composite deposition technology, according to various market demands. Establishment of actual roll-to-roll continuous process and equipment and process technology will affect related industries greatly.