• Title/Summary/Keyword: transition path

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The Characteristics of Chalcogenide $Ge_1Se_1Te_2$ Thin Film for Nonvolatile Phase Change Memory Device (비휘발성 상변화메모리소자에 응용을 위한 칼코게나이드 $Ge_1Se_1Te_2$ 박막의 특성)

  • Lee, Jae-Min;Chung, Hong-Bay
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.55 no.6
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    • pp.297-301
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    • 2006
  • In the present work, we investigate the characteristics of new composition material, chalcogenide $Ge_1Se_1Te_2$ material in order to overcome the problems of conventional PRAM devices. The Tc of $Ge_1Se_1Te_2$ bulk was measured $231.503^{\circ}C$ with DSC analysis. For static DC test mode, at low voltage, two different resistances are observed. depending on the crystalline state of the phase-change resistor. In the first sweep, the as-deposited amorphous $Ge_1Se_1Te_2$ showed very high resistance. However when it reached the threshold voltage(about 11.8 V), the electrical resistance of device was drastically reduced through the formation of an electrically conducting path. The phase transition between the low conductive amorphous state and the high conductive crystal]me state was caused by the set and reset pulses respectively which fed through electrical signal. Set pulse has 4.3 V. 200 ns. then sample resistance is $80\sim100{\Omega}$. Reset pulse has 8.6 V 80 ns, then the sample resistance is $50{\sim}100K{\Omega}$. For such high resistance ratio of $R_{reset}/R_{set}$, we can expect high sensing margin reading the recorded data. We have confirmed that phase change properties of $Ge_1Se_1Te_2$ materials are closely related with the structure through the experiment of self-heating layers.

Elite Ant System for Solving Multicast Routing Problem (멀티캐스트 라우팅 문제 해결을 위한 엘리트 개미 시스템)

  • Lee, Seung-Gwan
    • Journal of the Korea Society of Computer and Information
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    • v.13 no.3
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    • pp.147-152
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    • 2008
  • Ant System(AS) is new meta heuristic for hard combinatorial optimization problem. It is a population based approach that uses exploitation of positive feedback as well as greedy search. It was first proposed for tackling the well known Traveling Salesman Problem. In this paper, AS is applied to the Multicast Routing Problem. Multicast Routing is modeled as the NP-complete Steiner tree problem. This is the shortest path from source node to all destination nodes. We proposed new AS to resolve this problem. The proposed method selects the neighborhood node to consider all costs of the edge and the next node in state transition rule. Also, The edges which are selected elite agents are updated to additional pheromone. Simulation results of our proposed method show fast convergence and give lower total cost than original AS and $AS_{elite}$.

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Theoretical Studies on the Diels-Alder Reactions between Cyclopentadiene and Conformationally Flexible Dienophiles (시클로 펜타디엔과 구조적으로 회전이 쉬운 Dienophile간의 Diels-Alder 반응에 대한 이론적 연구)

  • Kim, Chan Kyung;Lee, In Young;Lee, Bon Su;Lee, Ik Choon;Kim, Kwan Soo;Joo, Young Hyup
    • Journal of the Korean Chemical Society
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    • v.40 no.7
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    • pp.483-491
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    • 1996
  • Dieis-Alder reaction between cyclopentadiene and 5-membered ring compounds which have exo-cyclic double bond has been studied using the PM3 method. Transition states do not show large geometrical change with the variation of dienophiles. Two isomers are possible due to the rotation of the exo-cyclic double bond of a dienophile. The reactivity for the formation of different products are explained using the FMO energy gap. The exo and endo selectivity of the reaction has been also studied from the correlation between the deformation energy and the activation barrier. Minimum energy reaction path is discussed using the Curtin-Hammett principle.

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Crack effect on the elastic buckling behavior of axially and eccentrically loaded columns

  • Zhou, L.;Huang, Y.
    • Structural Engineering and Mechanics
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    • v.22 no.2
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    • pp.169-184
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    • 2006
  • A close form solution of the maximum deflection for cracked columns with rectangular cross-sections was developed and thus the elastic buckling behavior and ultimate bearing capacity were studied analytically. First, taking into account the effect of the crack in the potential energy of elastic systems, a trigonometric series solution for the elastic deflection equation of an arbitrary crack position was derived by use of the Rayleigh-Ritz energy method and an analytical expression of the maximum deflection was obtained. By comparison with the rotational spring model (Okamura et al. 1969) and the equivalent stiffness method (Sinha et al. 2002), the advantages of the present solution are that there are few assumed conditions and the effect of axial compression on crack closure was considered. Second, based on the above solutions, the equilibrium paths of the elastic buckling were analytically described for cracked columns subjected to both axial and eccentric compressive load. Finally, as examples, the influence of crack depth, load eccentricity and column slenderness on the elastic buckling behavior was investigated in the case of a rectangular column with a single-edge crack. The relationship of the load capacity of the column with respect to crack depth and eccentricity or slenderness was also illustrated. The analytical and numerical results from the examples show that there are three kinds of collapse mechanisms for the various states of cracking, eccentricity and slenderness. These are the bifurcation for axial compression, the limit point instability for the condition of the deeper crack and lighter eccentricity and the fracture for higher eccentricity. As a result, the conception of critical transition eccentricity $(e/h)_c$, from limit-point buckling to fracture failure, was proposed and the critical values of $(e/h)_c$ were numerically determined for various eccentricities, crack depths and slenderness.

Determinants of the Socio-economic and Emotional Status of the Elderly in Korea (한국노령인구의 사회.경제적 상황의 결정요인)

  • 노공균;조소영;신동숙;이태훈
    • Korea journal of population studies
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    • v.14 no.2
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    • pp.45-70
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    • 1991
  • 1. 문제점(Setting of Problems) 산업의 급진적인 진보는 고도의 기술사회(high-tech societies)를 창출해 내었고, 이로 인해 생산양식뿐만 아니라, 가치체계 및 생활양식이 급진적으로 변화하였다. 동시에, 산업화 및 생활수준의 향상은 인구통계학적 변천(demographic transition)을 가져와, 인구의 노령화가 이루어졌다. 산업화에 의해 발생된 이러한 현상들, 즉 가치체계의 변화와 인구의 노령화가 바로 문제의 핵심인 것이다. 산업화는 효율(efficiency)에 높은 가치를 부여함으로써, 정신적인 인간관계측면의 중요성을 무시하고, 노령화란 다차원적(multi-dimensional) 문제를 일으켰다. 이러한 문제들의 해결책으로서 서구적인 가치개념은 노인들의 생활의 질(quality of life)를 향상시키지 못한 것으로 생각된다. 따라서, 물질적인 면 이외에 정신적인 면의 접근법을 필요로 하게 되는 것이다. 2. 연구의 목적(Objective of the Study) 이 연구의 목적은 한국에 있어서의 인구의 노령화의 원인과 결과에 대한 연구를 하는데 있다. 이러한 연구에 의해 노령화라는 다차원적 문제에 대한 지식을 얻으므로써, 사회, 공동체 및 가족 수준에서의 노령화 문제를 다루는데 있어 비서구적 접근법 및 정책적 전략에 관한 방안을 제시하게 되기를 희망한다. 3. 방법론(Methodology) 1) 자료 수집(Data Collection) 자료는 다음 세가지 원천으로 부터 얻어졌다. 첫째, 출판된 자료 및 회의서류 둘째, 한국보건사회연구원과의 협조로 행해진 설문지 조사 셋째, 자체 연구팀에 의해 행해진 면담 2) 자료분석(Data Analysis) 인과분석(cause-effect types of analysis)은 probit, logit, path analyses에 의해 행해졌다. 이 연구논문에는 trend analysis의 결과는 제시되지 않았는데, 이는 다양한 정부기관에 의해 출간된 분석들과 유사하기 때문이다. 4. 연구분석의 결과 첫째, 경제적 요인은 노인들의 생활상태를 결정하는데 가장 중요한 요인이라는 것을 알 수 있다. 둘째, 노인의 사회적인 통합이 강할수록 보다 행복한 생활을 영위하는 것으로 나타났다. 셋째, 성(sex), 교육정도, 주거지역 등이 노인의 고용상태 및 소득수준과 큰 관계가 있다. 넷째, 교육정도, 사회적 결합(social integration) 등이 건강상태와 밀접한 관계가 있다. 다섯째, 사회적 통합, 건강상태, 독립심 등이 노인의 정서적 상태에 큰 영향을 미친다.

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Photofragment Translational Spectroscopy of CH₂I₂ at 304 nm: Polarization Dependence and Energy Partitioning

  • 정광우;Temer S. Ahmadi;Mostafa A. El-Sayed
    • Bulletin of the Korean Chemical Society
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    • v.18 no.12
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    • pp.1274-1280
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    • 1997
  • The photodissociation dynamics of CH2I2 has been studied at 304 nm by state-selective photofragment translational spectroscopy. Velocity distributions, anisotropy parameters, and relative quantum yields are obtained for the ground I(2P3/2) and spin-orbit excited state I*(2P1/2) iodine atoms, which are produced from photodissociation of CH2I2 at this wavelength. These processes are found to occur via B1 ← A1 type electronic transitions. The quantum yield of I*(2P1/2) is determined to be 0.25, indicating that the formation of ground state iodine is clearly the favored dissociation channel in the 304 nm wavelength region. From the angular distribution of dissociation products, the anisotropy parameters are determined to be β(I)=0.4 for the I(2P3/2) and β(I*)=0.55 for the I*(2P1/2) which substantially differ from the limiting value of 1.13. The positive values of anisotropy parameter, however, show that the primary processes for I and I* formation channels proceed dominantly via a transition which is parallel to I-I axis. The above results are interpreted in terms of dual path formation of iodine atoms from two different excited states, i.e., a direct and an indirect dissociation via curve crossing between these states. The translational energy distributions of recoil fragments reveal that a large fraction of the available energy goes into the internal excitation of the CH2I photofragment; < Eint > /Eavl=0.80 and 0.82 for the I and I* formation channels, respectively. The quantitative analysis for the energy partitioning of available energy into the photofragments is used to compare the experimental results with the prediction of direct impulsive model for photodissociation dynamics.

CONSIDERATIONS REGARDING ROK SPENT NUCLEAR FUEL MANAGEMENT OPTIONS

  • Braun, Chaim;Forrest, Robert
    • Nuclear Engineering and Technology
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    • v.45 no.4
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    • pp.427-438
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    • 2013
  • In this paper we discuss spent fuel management options in the Republic of Korea (ROK) from two interrelated perspectives: Centralized dry cask storage and spent fuel pyroprocessing and burning in sodium fast reactors (SFRs). We argue that the ROK will run out of space for at-reactors spent fuel storage by about the year 2030 and will thus need to transition centralized dry cask storage. Pyroprocessing plant capacity, even if approved and successfully licensed and constructed by that time, will not suffice to handle all the spent fuel discharged annually. Hence centralized dry cask storage will be required even if the pyroprocessing option is successfully developed by 2030. Pyroprocessing is but an enabling technology on the path leading to fissile material recycling and burning in future SFRs. In this regard we discuss two SFR options under development in the U.S.: the Super Prism and the Travelling Wave Reactor (TWR). We note that the U.S. is further along in reactor development than the ROK. The ROK though has acquired more experience, recently in investigating fuel recycling options for SFRs. We thus call for two complementary joint R&D project to be conducted by U.S. and ROK scientists. One leading to the development of a demonstration centralized away-fromreactors spent fuel storage facility. The other involve further R&D on a combined SFR-fuel cycle complex based on the reactor and fuel cycle options discussed in the paper.

Effect of Cooling Conditions on Microstructures and Mechanical Properties in API X80 Linepipe Steels (API X80 라인파이프강의 미세조직과 기계적 특성에 미치는 냉각조건의 영향)

  • Han, Seung Youb;Shin, Sang Yong;Lee, Sunghak;Bae, Jin-ho;Kim, Kisoo
    • Korean Journal of Metals and Materials
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    • v.47 no.9
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    • pp.523-532
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    • 2009
  • In this study, four API X80 linepipe steel specimens were fabricated with varying cooling rates and finish cooling temperatures, and their microstructures and crystallographic orientations were analyzed to investigate the effects of cooling conditions on their tensile and Charpy impact properties. All the specimens consisted of acicular ferrite, granular bainite, and secondary phases such as martensite and martensiteaustenite constituent. The volume fraction of secondary phases increased with increasing cooling rate, and the higher finish cooling temperature resulted in the reduction in volume fraction and grain size of secondary phases. According to the crystallographic orientation analysis data, the effective grain size and unit crack path decreased as fine acicular ferrites having a large amount of high-angle grain boundaries were homogeneously formed, thereby leading to the improvement of Charpy impact properties. The specimen fabricated with the higher cooling rate and lower finish cooling temperature had the highest upper shelf energy and the lowest energy transition temperature because it contained a large amount of fine secondary phases homogeneously distributed inside fine acicular ferrites, while its tensile properties well maintained.

UML 2.0 Statechart based Modeling and Analysis of Finite State Model for Cryptographic Module Validation (암호모듈 검증을 위한 UML 2.0 상태도 기반의 유한상태모델 명세 및 분석)

  • Lee, Gang-soo;Jeong, Jae-Goo;Kou, Kab-seung
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.19 no.4
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    • pp.91-103
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    • 2009
  • A cryptographic module (CM) is an implementation of various cryptographic algorithms and functions by means of hardware or software, When a CM is validated or certified under the CM validation program(CMVP), a finite state model(FSM) of the CM should be developed and provided, However, guides or methods of modeling and analysis of a FSM is not well-known, because the guide is occasionally regarded as a proprietary know-how by developers as well as verifiers of the CM. In this paper, we propose a set of guides on modeling and analysis of a FSM, which is needed for validation of a CM under CMVP, and a transition test path generation algorithm, as well as implement a simple modeling tool (CM-Statecharter). A FSM of a CM is modeled by using the Statechart of UML 2.0, Statechart, overcoming weakness of a FSM, is a formal and easy specification model for finite state modeling of a CM.

Embedding Cobalt Into ZIF-67 to Obtain Cobalt-Nanoporous Carbon Composites as Electrode Materials for Lithium ion Battery

  • Zheng, Guoxu;Yin, Jinghua;Guo, Ziqiang;Tian, Shiyi;Yang, Xu
    • Journal of Electrochemical Science and Technology
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    • v.12 no.4
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    • pp.458-464
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    • 2021
  • Lithium ion batteries (LIBs) is a kind of rechargeable secondary battery, developed from lithium battery, lithium ions move between the positive and negative electrodes to realize the charging and discharging of external circuits. Zeolitic imidazolate frameworks (ZIFs) are porous crystalline materials in which organic imidazole esters are cross-linked to transition metals to form a framework structure. In this article, ZIF-67 is used as a sacrificial template to prepare nano porous carbon (NPC) coated cobalt nanoparticles. The final product Co/NPC composites with complete structure, regular morphology and uniform size were obtained by this method. The conductive network of cobalt and nitrogen doped carbon can shorten the lithium ion transport path and present high conductivity. In addition, amorphous carbon has more pores that can be fully in contact with the electrolyte during charging and discharging. At the same time, it also reduces the volume expansion during the cycle and slows down the rate of capacity attenuation caused by structure collapse. Co/NPC composites first discharge specific capacity up to 3115 mA h/g, under the current density of 200 mA/g, circular 200 reversible capacity as high as 751.1 mA h/g, and the excellent rate and resistance performance. The experimental results show that the Co/NPC composite material improves the electrical conductivity and electrochemical properties of the electrode. The cobalt based ZIF-67 as the precursor has opened the way for the design of highly performance electrodes for energy storage and electrochemical catalysis.