• Journal of Welding and Joining
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• v.19 no.4
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• pp.399-405
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• 2001

A dynamic force balance model is proposed in this work as an extension of the previous static force balance model to predict metal transfer in arc welding. Dynamics of a pendant drop is modeled as the second order system, which consists of the mass, spring and damper. The spring constant of a spherical drop at equilibrium is derived in the closed-form equation, and the inertia force caused by drop vibration is included in the drop detaching condition. While the inertia force is small in the low current range, it becomes larger than the gravitational force with current increase. The inertia force reaches half of the electromagnetic force at transition current, and has considerable effects on drop detachment. The proposed dynamic force balance model predicts the detaching drop size more accurately than the static force balance model.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.297-298
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• 2011

Metal/poly (4,4'-aminotriphen-ylene hexafluoroisopropylidenediphthalimide) (TP6F PI)/metal structure exhibited an electrically volatile phase transition with high (OFF) or low (ON) resistive states when voltage between electrodes swept. Here, we demonstrate a noble set-up in which holes are injected by photoelectron emission process during the voltage sweep instead of direct charge carrier injection via metal electrode, which enables direct investigation into changed electronic structures of TP6F PI both in ON and OFF states using photoemission spectroscopy methods. In the I-V measurement, TP6F PI shows a non-volatile behavior. In spectroscopic results, this non-volatile behavior is leaded from the structural modification of the O=C double bond in phthalimide of TP6F PI by hole injection.

• Analytical Science and Technology
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• v.31 no.1
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• pp.1-6
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• 2018

We used differential scanning calorimetry and a thermogravimetric analysis to investigate the effect of being confined in mesoporous MCM-41 on the decomposition of lithium borohydride and magnesium borohydride when heated. The confinement did not cause a phase transition of the metal borohydrides inside MCM-41, but did lower their decomposition temperature. With the exception of a lowering of the temperature, the decomposition reaction mechanism of the metal borohydrides was nearly the same for both the bulk and confined samples.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.68-68
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• 2018

Nanoporous or nanotubular metal oxide can be fabricated by anodization of metal substrate in fluoride contained electrolytes. The approach allows various transition metals such as Zr, Hf, Nb, Ta to form highly ordered oxide nanostructures. These oxide nanostructures have various advantages such as high surface area, fast electron transport rate and slow recombination in semiconductive materials. Recently, vanadium oxide nanostructures have been drawn attentions due to their superior electronic, catalytic and ion insertion properties. However, anodization of vanadium metal to form oxide layers is relatively difficult due to ease formation of highly soluble complex in water contained electrolyte during anodization. Yang et al. reported $[TiF_6]^{2-}$ or $[BF_4]^-$ in electrolyte helps to formation of stable oxide layer [1, 2]. However, the reported approaches are very sensitive in other parameters. In this presentation, we deal with the other important key parameters to form ordered anodic vanadium oxide such as pH, temperatures and applied potential.

• The Korean Journal of Ceramics
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• v.4 no.2
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• pp.103-113
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• 1998

By using a gas-tight electrochemical cell, we can perform high-temperature coulometric titration and measure electronic transport properties to determine the elecronic defect structure of metal oxides. This technique reduces the time and expense required for conventional thermogravimetric measurements. The components of the gas-tight coulometric titration cell are an oxygen sensor, Pt/yttria stabilitized zirconia(YSZ)/Pt, and an encapsulated metal oxide sample. Based on cell design, both transport and thermodynamic measurements can be performed over a wide range of oxygen partial pressure ($pO_2=10^{-35}$ to 1 atm). This paper describes the high-temperature gas-tight electrochemical cells used to determine electronic defect structures and transport properties for pure and doped-oxide systems, such as YSZ, doped and pure ceria $(Ca-CeO_2 \;and\; CeO_2)$, copper oxides and copper-oxide-based ceramic superconductors, transition metal oxides, $SrFeCo_{0.5}O_x,\; and \;BaTiO_2$.

• Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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• 2003.10a
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• pp.21-23
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• 2003

MOCVD method is one of promising techniques which can fabricate YBCO coated conductors in a low Price A continuous reel-to-reel MOCVD device using a dispersed solid source was designed and manufactured. YBCO films were deposited on various substrates of metallic silver, (100) MgO and SrTiO3 single crystals. The chemical composition of the metal organic sources was changed to optimize the processing condition associate to the deposition of the stoichiometric Y3a2Cu3O7-y. We report the superconducting transition temperature, surface morphology and chemical composition of the YBCO film surfaces.

• Journal of the Korean Chemical Society
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• v.57 no.3
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• pp.341-351
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• 2013

Zn(II), Cd(II) and Hg(II) complexes with a general composition[$M(L)_2(X)_2$], where L=4-aminopyridine (4AP) and $X=NO_2{^-}$ were prepared under microwave irradiation. The metal complexes were characterized by elemental analyses, molar conductance, IR, Far-IR, electronic, NMR ($^1H$, $^{13}C$), XPS spectral and thermal studies. The spectroscopic studies reveal the composition, different modes of bonding, electronic transition, different chemical environment of C and H atoms and the electronic state of the metal atoms. On the basis of the characterization data, tetrahedral geometry is suggested for all the complexes. The free ligand (4-aminopyridine) and their metal complexes were screened against phytopathogenic fungi and bacteria in vitro and the activities were compared.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.6
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• pp.678-682
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• 2004

Generally Bi-2223/Ag tapes have a broad S/N transition region and their sheath is a good electric conductor. In this study, the current distribution between superconductor and metal sheath in HTS tapes were investigated. AC with its peak value above 10 times $I_{c}$ was applied to HTS tapes for around 6 cycles and V-I characteristics were measured. Using the resistance of the sheath and V-I curves, the current distribution between superconductor and metal sheath was calculated. When 150 $A_{p}$ was applied, more than 2/3 of the current flows through superconductor. However, in the case of 304 $A_{p}$, most of the applied current came to flow through the metal sheath at the 6th cycle.e.e.e.

• Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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• 2000.11a
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• pp.3-8
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• 2000

Chemical nature of nascent metal surfaces which is one of the important active sources for tribochemical reactions was investigated using a newly developed method. Some enhanced activities were observed. For example, organic compounds chemisorbed on nascent gold surfaces and aromatic compounds decomposed on nascent nickel surfaces resulting in hydrogen evolution. Non-polar compounds such as organic sulfides had a higher chemisorption activity on nascent steel surfaces than polar compounds such as fatty acids and phosphates. Organic sulfides reacted directly with nascent steel surfaces and the surface was covered with metal sulfides. The activity for the chemisorption of organic compounds was closely dependent on the electronic structure of metals. Although benzene chemisorbed very easily on nascent surfaces of transition metals, it did not chemisorb ell nascent surfaces of simple metals. Boundary lubricating behaviors of extreme pressure additives were explained on the bases of the chemical activities of nascent surfaces obtained in this investigation. Under mild conditions, polar compounds such as fatty acids and phosphates were effective for boundary lubrication, because surfaces are covered with oxide layers. On the other hand, sulfides were more effective under severe conditions where the oxide layers were removed and the nascent surfaces were formed.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.15 no.2
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• pp.188-195
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• 1986

Condensation heat transfer can be classified in dropwise condensation and filmwise condensation, and for the industrial purpose, the former is more useful than the latter because of the higher heat transfer rate. But it is difficult to maintain the dropwise condensation continuously since most of the metal surfaces become wetted after exposure to a condensing vapor over an extended period of time. To maintain dropwise condensation continuously , various surface coatings and promoters have been used recently, but these methods must be reconsidered about the durability of condensing surface. Therefore, in this study, evaporating method of various pure metals on the condensing surface has been performed to maintain dropwise condensation. The results have showed that the heat transfer rate of silver evaporating surface is higher than any other metal evaporating in dropwise area. Transition temperature and filmwise condensation curves are uniform regardless of kinds of evaporating metals.