• Title/Summary/Keyword: transition element

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Effect of Transition Metal on the Thermal Stability and Mechanical Property of Fe-based Amorphous Alloys (Fe기 비정질합금의 열적안정성 및 기계적 성질에 미치는 천이금속의 영향)

  • Gook, Jin Seon;Yoon, Dong Joo
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.6
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    • pp.345-349
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    • 2001
  • This study has investigated the effect of thermal stability and mechanical property of $Fe_{80-X}P_{10}C_6B_4M_X$(X=2, 4, 6, M=transition metal) amorphous alloys fabricated by the melt-spun process. The glass transition temperature($T_g$), crystallization temperature($T_x$) and hardness increase with decreasing electron concentration (e/a) from about 7.38 to 7.18. The decrease of e/a implies the increase in the attractive bonding state between the M elements and other constituent element. The decrease in a/e leads to the enhancement of the attractive bonding state among the constituent elements which is favorable for the increase in $T_g$, $T_x$ and hardness.

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Periodic-Cell Simulations for the Microscopic Damage and Strength Properties of Discontinuous Carbon Fiber-Reinforced Plastic Composites

  • Nishikawa, M.;Okabe, T.;Takeda, N.
    • Advanced Composite Materials
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    • v.18 no.1
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    • pp.77-93
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    • 2009
  • This paper investigated the damage transition mechanism between the fiber-breaking mode and the fiber-avoiding crack mode when the fiber-length is reduced in the unidirectional discontinuous carbon fiber-reinforced-plastics (CFRP) composites. The critical fiber-length for the transition is a key parameter for the manufacturing of flexible and high-strength CFRP composites with thermoset resin, because below this limit, we cannot take full advantage of the superior strength properties of fibers. For this discussion, we presented a numerical model for the microscopic damage and fracture of unidirectional discontinuous fiber-reinforced plastics. The model addressed the microscopic damage generated in these composites; the matrix crack with continuum damage mechanics model and the fiber breakage with the Weibull model for fiber strengths. With this numerical model, the damage transition behavior was discussed when the fiber length was varied. The comparison revealed that the length of discontinuous fibers in composites influences the formation and growth of the cluster of fiber-end damage, which causes the damage mode transition. Since the composite strength is significantly reduced below the critical fiber-length for the transition to fiber-avoiding crack mode, we should understand the damage mode transition appropriately with the analysis on the cluster growth of fiber-end damage.

Far Infrared radiation characteristrics by temperature conversion of transition element oxjdes (전이원소 산화물의 온도변화에 따른 원적외선 방사특성)

  • 이종민;박종옥;최태섭
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 1991.10a
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    • pp.18-22
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    • 1991
  • Far Infrared radiators should have functionality to convert thermal energy into electron wave. In order to apply the Far Infrared to the substance, the absorption characteristics of the substance should be considered. In this paper, interrelation of emissivity with emission energy according to temperature in the range of 2.5$\mu$m to 25$\mu$m after the transition element oxides (MnO2, Fe2O3, CuO, Co3O4) of first grade reagent were molded in press, then they were calcinated in 1050˚C, and they were used as samples.

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Far Infrared Radiation Characteristics by Temperature Variation of Transition Element Oxides (전이원소 산화물의 온도변화에 따른 원적외선 복사특성)

  • 박종옥;최태섭
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.9 no.6
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    • pp.32-40
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    • 1995
  • Far Infrared radiators should have functionality to convert thermal energy into an electromagnetic wave. In order to apply the Far Infrared to the substance, the absorption characteristics of the substance should be considered. In this paper, interrelation of emissivity with emission energy according to temperature in the range of [$2.5\mu\textrm{m}$] to 25[$\mu\textrm{m}$] after the transition element oxides (MnO2, Fe2O3, CuO, Co3O4) of first grade reagent were molded in press, then they were sintered in [$1050^{\circ}C$], and they were used as samples.

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Buckling of insulated irregular transition flue gas ducts under axial loading

  • Ramadan, H.M.
    • Structural Engineering and Mechanics
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    • v.43 no.4
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    • pp.449-458
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    • 2012
  • Finite element buckling analysis of insulated transition flue ducts is carried out to determine the critical buckling load multipliers when subjected to axial compression for design process. Through this investigation, the results of numerical computations to examine the buckling strength for different possible duct shapes (cylinder, and circular-to-square) are presented. The load multipliers are determined through detailed buckling analysis taking into account the effects of geometrical construction and duct plate thickness which have great influence on the buckling load. Enhancement in the buckling capacity of such ducts by the addition of horizontal and vertical stiffeners is also investigated. Several models with varying dimensions and plate thicknesses are examined to obtain the linear buckling capacities against duct dimensions. The percentage improvement in the buckling capacity due to the addition of vertical stiffeners and horizontal Stiffeners is shown to be as high as three times for some cases. The study suggests that the best location of the horizontal stiffener is at 0.25 of duct depth from the bottom to achieve the maximum buckling capacity. A design equation estimating the buckling strength of geometrically perfect cylindrical-to-square shell is developed by using regression analysis accurately with approximately 4% errors.

Effect of Mechanical Damping and Electrical Conductivity on the Dynamic Performance of a Novel Electromagnetic Engine Valve Actuator

  • Park, Sang-Shin;Kim, Jin-Ho;Choi, Young;Chang, Jung-Hwan
    • International Journal of Precision Engineering and Manufacturing
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    • v.9 no.3
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    • pp.72-74
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    • 2008
  • We investigate the effect of mechanical damping and electrical conductivity on the dynamic performance of a new electromagnetic engine valve actuator that employs a permanent magnet. The key dynamic performance factors are the transition time and the landing velocity of the armature. Two-dimensional dynamic finite element analyses are performed to simulate a coupled system. The results show that mechanical damping and electrical conductivity have similar effects on the dynamic performance of the engine valve actuator. Subsequently, it is possible to replace the role of mechanical damping by controlling the electrical conductivity through the thickness and number of steel core laminations.

Structural Integrity Evaluation of the Integral Reactor SMART under Pressurized Thermal Shock (가압열충격에 대한 일체형원자로 SMART의 구조건전성 평가)

  • Kim, Jong-Wook;Lee, Gyu-Mahn;Choi, Suhn;Park, Keun-Bae
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.441-446
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    • 2001
  • In the integral type reactor, SMART, all the major components such as steam generators, pressurizer and pumps are located inside the single reactor pressure vessel. The objective of this study is to evaluate the structural integrity for RPV of SMART under the postulated pressurized thermal shock by applying the finite element analysis. Input data for the finite element analysis were generated using the commercial code I-DEAS, and the fracture mechanics analysis was performed using the ABAQUS. The crack configurations, the crack aspect ratio and the clad thickness were considered in the parametric study. The effects of these parameters on the reference nil-ductility transition temperature were also investigated.

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Thermal Ratchetting of the Conductive Adhesives Joints Subjected to the Thermal Cycles (전도성 접착제의 열경화 응력에 대한 해석)

  • 박주혁;서승호
    • Proceedings of the International Microelectronics And Packaging Society Conference
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    • 2002.05a
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    • pp.208-213
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    • 2002
  • When a thermoset conductive adhesive joints are subjected to the thermal cycles, the thermal stresses are developed around the joints. Most of in-plane, hi-axial components of these residual stresses induces large tensile peel stresses and weakens adhesive joints. Also these stresses vary with thermal cycles, and result in thermal fatigue loading and debonding propagation. In this study, the thermal ratchetting effect in conductive adhesive joints are evaluated by the finite element analysis with the viscoelastic material model. In order to Investigate the relationship between thermal ratchetting and glass transition temperature, the mathematical material model has been developed experimentally by dynamic mechanical analysis. These material models are implemented to the finite element analysis with thermal loading cycles. And the stress profiles around the conductive adhesive joints are calculated. It has been observed that the thermal ratchetting occurs when the maximum temperature of thermal cycles is above the glass transition temperature. The peel and shear stress components increase as the thermal loading time increases. This will contributes to thermal fatigue fracture of the joints.

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Studies of Element Substitution on Superconductivity in Bi-Sr-Ca-Cu-O Oxides (Bi계 치환 고온 초전도체)

  • 권오흥;박천제
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.124-128
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    • 2000
  • The high Tc phase disappeared and low Tc phase increased in the substitution of transition elements for Bi ions. The high Tc phase decreased in the substitution of Si and Sn for Bi ions. The high Tc phase increased in the substitution of Sb, As and P which were the same group of Bi for Bi ions. The substitution of P ions was the most effective and then the high Tc phase was formed in large quantity by replacing Bi ions with 30% of P ions.

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Content and Distribution of Transition Metals and Rare Earth Elements in Magnetically and Mechanically Separated Brown Coal Ash

  • Malikov, Sh.R.;Pikul, V.P.;Mukhamedshina, N.M.;Sandalov, V.N.;Kudiratov, S.;Ibragimova, E.M.
    • Journal of Magnetics
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    • v.18 no.3
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    • pp.365-369
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    • 2013
  • Coal ash is known to contain a noticeable amount of valuable elements, including transition metals and lanthanides. Therefore it is quite actual problem to extract them for metallurgy and other applications. This paper presents the results of high gradient magnetic and mechanical separation, microscopy, element analyses and optical spectroscopy of brown coal ash taken from the combustion camera and chimney-stalk of Angren thermal power station. The separated magnetic fraction was 3.4 wt.%, where the content of Fe in ferrospheres increased to 58 wt.%. The highest contents of Fe and rare earth elements were found in the fine fractions of $50-100{\mu}m$. Optical absorption spectroscopy of water solutions of the magnetic fractions revealed $Fe^{2+}$ and $Fe^{3+}$ ions in the ratio of ~1:1. The separated coal ash could be used for cleaning of technological liquid waste by means of the high gradient magnetic field.